• Title/Summary/Keyword: Microwave treatment

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Dissolution Conditions of Solid Radioactive Wastes Generated from NPP for the Analysis of Radionuclides Using a Closed-vessel Microwave Acid Digestion System (원전 발생 고체 방사성폐기물 내 핵종 분석을 위한 극초단파 산분해 장치를 이용한 용액화 조건)

  • 표형열;이정진;전종선;이창헌;지광용
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.158-166
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    • 2004
  • The optimal conditions are obtained for the decomposition of solid radioactive wastes, including ion exchange resin, zeolite, active charcoal, and sludge from nuclear power plant. In the process of decomposing the radioactive wastes were used the microwave acid digestion method with mixed acid. The solution after acid digestion by the following method was colorless and transparent. Each solution was analyzed with ICP-AES and AAS and the recovery yield for 5 different elements added the simulated radioactive wastes were over 94%. As an effective pre-treatment, the proposed microwave acid digestion conditions concerning the chemical trait of each radioactive waste are expected to be generally applied to above-mentioned radioactive wastes from nuclear power plant hereafter.

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A Study on BTEX Removal Efficiency for Variation of Moistures by Microwave Process (유류오염토의 마이크로파 처리 시 토양의 함수율 변화에 따른 BTEX 제거특성에 관한 연구)

  • Ha, Sang-An;Yeom, Hae-Kyong;Yu, Mi-Yong
    • Journal of Soil and Groundwater Environment
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    • v.12 no.2
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    • pp.65-71
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    • 2007
  • This study has been focused on an application of microwave pre-treatment of soil contaminated with volatile organic chemicals, and BTEX(benzene, toluene, ethylene, xylene). Microwave experiments were carried out under different power conditions (2 kW, 4 kW) using different moisture contents and BTEX concentration. According to these results of this study, the most BTEX removal efficiency was with 20% moisture contents regardless of electric power. The result show that 2kW was determined to the optimum electric power at $10{\sim}30%$ moisture contents, but the optimum power was 4 kW at 50% of moisture content.

Flame Resistance and Durability of Compressed Structural Wood through Microwave Heat Drying Method (마이크로파 가열건조법에 의한 압축 구조용 목재의 방염 및 내구성)

  • Lim, Nam-Gi
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.2
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    • pp.162-170
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    • 2011
  • As the result of implementing a treated material test and durability test after quickly drying S.P.F. species, a type of softwood structural material, within a short period time, soaking it in liquid phosphate flame proof agent for an hour, microwave heating it, and compressing it from 3.8cm to 1cm, when setting the appropriate heating time of microwave heating at 7 minutes at 5kW, it is observed that it satisfies the target water content (4~5%). It is shown that in a water content measurement of the wood that is compressed after being softened by soaking in the flame proof agent, drying and heating at 3kW for 9 minutes, all specimens satisfied 12~14%, the appropriate water content for exterior wood. Also, it is shown that in terms of the flame performance obtained through a flame resistance treatment of the compressed wood and a treated material test, the specimen soaked in flame proof agent for 30 minutes was the most excellent, and that the performance test result of the compressed wood in all areas, such as nail withdrawal resistance, compression, bending strength, and shearing strength, were all improved in their mechanical features to twice to three times better performances.

Determination of major and minor elements in low and medium level radioactive wastes using closed-vessel microwave acid digestion (밀폐형 극초단파 산분해법을 이용한 중${\cdot}$저준위 방사성폐기물의 성분 원소 분석)

  • Lee Jeong-Jin;Pyo Hyung-Yeal;Jeon Jong-Seon;Lee Chang-Heon;Jee Kwang-Yong;Ji Pyung-Kook
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.4
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    • pp.231-238
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    • 2004
  • The conditions are obtained for the decomposition of solid radioactive wastes, including ion exchange resin, zeolite, charcoal, and sludge from nuclear power plant. In the process of decomposing the radioactive wastes was used the microwave acid digestion method with mixed acid. The solution after acid digestion by the following method was colorless and transparent. Each solution was analyzed with ICP-AES and AAS and the recovery yield for 5 different elements added into the simulated radioactive wastes were over $94{\%}$. The elemental analysis of destructive low and medium level radioactive wastes by the proposed microwave acid digestion conditions concerning the chemical characteristics of each radioactive waste are expected to be useful basic data for development of optimal glass formulation.

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Effect of DC Bias on the Growth of Nanocrystalline Diamond Films by Microwave Plasma CVD (마이크로웨이브 플라즈마 CVD에 의한 나노결정질 다이아몬드 박막 성장 시 DC 바이어스 효과)

  • Kim, In-Sup;Kang, Chan Hyoung
    • Journal of the Korean institute of surface engineering
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    • v.46 no.1
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    • pp.29-35
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    • 2013
  • The effect of DC bias on the growth of nanocrystalline diamond films on silicon substrate by microwave plasma chemical vapor deposition has been studied varying the substrate temperature (400, 500, 600, and $700^{\circ}C$), deposition time (0.5, 1, and 2h), and bias voltage (-50, -100, -150, and -200 V) at the microwave power of 1.2 kW, working pressure of 110 torr, and gas ratio of Ar/1%$CH_4$. In the case of low negative bias voltages (-50 and -100 V), the diamond particles were observed to grow to thin film slower than the case without bias. Applying the moderate DC bias is believed to induce the bombardment of energetic carbon and argon ions on the substrate to result in etching the surfaces of growing diamond particles or film. In the case of higher negative voltages (-150 and -200 V), the growth rate of diamond film increased with the increasing DC bias. Applying the higher DC bias increased the number of nucleation sites, and, subsequently, enhanced the film growth rate. Under the -150 V bias, the height (h) of diamond films exhibited an $h=k{\sqrt{t}}$ relationship with deposition time (t), where the growth rate constant (k) showed an Arrhenius relationship with the activation energy of 7.19 kcal/mol. The rate determining step is believed to be the surface diffusion of activated carbon species, but the more subtle theoretical treatment is required for the more precise interpretation.

A Study on the Li5Fe5O8 Species Affecting the Microwave Heating Performance on the Ternary Li-Fe-Zn Material (3원계 금속산화물로 제조한 마이크로웨이브 발열소재상 Li5Fe5O8 종이 발열성능에 미치는 영향 연구)

  • Jang, Young Hee;Lee, Sang Moon;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.703-709
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    • 2018
  • Dielectric heating materials were prepared through the thermal treatment for composites of Li and Zn type precursors that are major materials being responded to microwave under diversified conditions. The prepared heating material samples were analyzed by SEM and it was confirmed that $Li_5Fe_5O_8$ materials being formed on the surface was a major influencing factor for the heating performance. Heating materials improved the moisture removal in a sludge drying facility, for example, the moisture content of 25 v/v% sludge decreased to 15.22 v/v%. Accordingly, heating materials were confirmed to directly affect the performance and efficiency of the microwave drying process.

Cation Ordering and Microwave Dielectric Properties of $Ba(Mg_{1/3}Nb_{2/3})O_3$Ceramics: I. Long-Range Order Parameter ($Ba(Mg_{1/3}Nb_{2/3})O_3$ 세라믹스의 양이온 규칙구조와 유전특성: I. 장거리 규칙도)

  • 김영웅;박재환;김윤호;박재관
    • Korean Journal of Crystallography
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    • v.12 no.2
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    • pp.76-80
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    • 2001
  • We have studied the effect of sintering conditions on the long-range order parameter of the 1 : 2 cation ordering in Ba(Mg/sub 1/3/Nb/sub 2/3/)O₃microwave dielectrics prepared through a columbite precursor method. It is found that the order parameter depends strongly on the sintering conditions. As the heat-treatment time increases at 1350℃, the long-range order parameter decreases. When sintered at 1500℃ for 4 hours, BMN shows a high long-range order parameter of 0.94.

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Microstructural Characterization of $CaTiO_3-NdAlO_3$-Based Ceramics

  • Suvorov, Danilo;Drazic, Goran;Valant, Matjaz;Jancar, Bostjan
    • Korean Journal of Crystallography
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    • v.11 no.4
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    • pp.195-199
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    • 2000
  • Ceramics based on CaTiO₃-NdAlO₃ solid solutions were synthesized in order to study their dielectric microwave properties. Microstructural analysis was performed with scanning electron microscopy (SEM) and transmission electron microscopy (TEM) using different analytical methods such as energy-dispersive X-ray spectroscopy (EDXS). It was observed that the heating conditions during sintering and cooling strongly affect the microstructural development of CaTiO₃-NdAlO₃-based ceramics. Various types and concentrations of structural defects were identified, for example, dislocations, twins and/or antiphase boundaries. all such defects resulted in a degradation of the dielectric microwave properties, in particular the quality factor Q. Dielectric properties of CaTiO₃-NdAlO₃-based ceramics can be improved by an appropriate thermal treatment of ceramics which results in a decrease in the concentrations of the identified microstructural defects.

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A study on the improvement of crystallinity and surface roughness of polycrystalline diamond films deposited by MPCVD method (MPCVD 방법에 의해 증착된 다결정 다이아몬드 박막의 결정성 및 표면 거칠기 향상에 관한 연구)

  • Shin, Wan-Chul;Seo, Soo-Hyung;Park, Jin-Seok
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1349-1351
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    • 2001
  • Polycrystalline diamond films are deposited by using a microwave plama CVC system, where the bias-enhanced nucleation (BEN) method is employed. Effects of the varying microwave power, the surface treatment by hydrogen plasma, and the cyclic hydrogen etching during deposition on the crystallinity as well as on the surface roughness of deposited films are examined by Raman spectroscopy, SEM, and AFM. A novel method for achieving a smoother diamond surface is also suggested through the indirect wafer bonding and back-side polishing.

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SYNERGISTIC INTERACTION OF ENVIRONMENTAL TEMPERATURE AND MICROWAVES: PREDICTION AND OPTIMIZATION

  • Petin, Vladislav G.;Kim, Jin-Kyu;Kolganova, Olga I.;Zhavoronkov, Leonid P.
    • Journal of Radiation Protection and Research
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    • v.36 no.1
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    • pp.1-7
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    • 2011
  • A simple mathematical model of simultaneous combined action of environmental agents has been proposed to describe the synergistic interaction of microwave and high ambient temperature treatment on animal heating. The model suggests that the synergism is caused by the additional effective damage arising from an interaction of sublesions induced by each agent. These sublesions are considered to be ineffective if each agent is taken individually. The additional damage results in a higher body temperature increment when compared with that expected for an independent action of each agent. The model was adjusted to describe the synergistic interaction, to determine its greatest value and the condition under which it can be achieved. The prediction of the model was shown to be consistent with experimental data on rabbit heating. The model appears to be appropriate and the conclusions are valid.