• Bulletin of the Korean Chemical Society
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• v.31 no.10
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• pp.2835-2840
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• 2010

A series of $MoO_3/CeO_2-ZrO_2$ catalysts with different Mo content (8 - 20 wt %) were prepared by simple co-precipitation followed by impregnation method and were characterized by X-ray diffraction (XRD), infrared spectroscopy (IR), scanning electron microscopy (SEM), energy dispersive spectroscopic (EDS) techniques. The prepared materials were tested for catalytic activity by the synthesis of benzimidazole derivatives using condensation of aromatic aldehydes and o-phenylenediamine by conventional and microwave method. Obtained results reveal that the catalytic activity increases with increase in Mo wt % loading. The best catalytic activity was obtained with 20 wt % $MoO_3/CeO_2-ZrO_2$. The particle size or crystallite size was estimated using Debye-Scherrer equation. After completion of reaction, the catalyst can be recovered efficiently and reused with consistent activity.

• Journal of The Korean Society of Agricultural Engineers
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• v.64 no.4
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• pp.31-43
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• 2022

In this study, we estimated the monthly FDSI (Flash Drought Stress Index) for assessing flash drought on South Korea using AMSR2(Advanced Microwave Scanning Radiometer 2) satellite-based soil moisture footprints. We collected the AMSR2 soil moisture and climate-land surface data from April to November 2018 for analyzing the monthly FDSI values. We confirmed that the FDSI values were high at the regions with the high temperature/evapotranspiration while the precipitation is relatively low. Especially, the regions which satisfied an onset of flash drought (FDSI≧0.71) were increased from June. Then, the most of regions suffered by flash drought during the periods (July to August) with the high temperature and evapotranspiration. Additionally, the impacts of landuse and slope degree were evaluated on the monthly FDSI changes. The forest regions that have the steep slope degree showed the relatively higher FDSI values than the others. Thus, our results indicated that the the slope degree has the relatively higher impact on the onset and increasing of flash drought compared to the others.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.1
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• pp.60-68
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• 2015

The study of waste activated sludge (WAS) solubilization has been increased for sludge volume reduction and enhancing the efficiency of anaerobic digestion. Microwave (MW)-assisted solubilization is an effective method for the solubilization of WAS because this method can lead to thermal, nonthermal effect and ionic conduction by dielectric heating. In this study, the solubilization of WAS by MW heating and conductive heating (CH) was compared and to enhance the MW-assisted solubilization of WAS at low MW output power, chemical agents were applied such as $H_2SO_4$ as the strong acid and $CaCl_2$, NaCl as the ionic materials. Compared to the COD solubilization of WAS by CH, that by MW heating was approximately 1.4, 6.2 times higher at $50^{\circ}C$, $100^{\circ}C$, respectively and the highest COD solubilization of WAS was 10.0% in this study of low MW output power condition. At the same MW output power and reaction time in chemically agents assisted experiments, the COD solubilization of WAS were increased up to 18.1% and 12.7% with the addition of $H_2SO_4$ and NaCl, however, that with the addition of $CaCl_2$ was 10.7%. This result might be due to the fact that the precipitation reaction occurred by calcium ion ($Ca^{2+}$) and phosphate ion (${PO_4}^{3-}$) produced in WAS after MW-assisted solubilization. In this study, $H_2SO_4$ turned out to be the optimal agent for the enhancement of MW efficiency, the addition of 0.2 M $H_2SO_4$ was the most effective condition for MW-assisted WAS solubilization.

• Journal of the Korean earth science society
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• v.33 no.2
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• pp.113-125
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• 2012

The estimations of the surface rain intensity and rain-related physical variables derived from two independent Tropical Rainfall Measuring Mission (TRMM) satellite sensors, TRMM Microwave Imager (TMI) and Precipitation Radar (PR), were compared over four different oceans. The precipitating clouds developed most frequently in the warmest sea surface temperature (SST) region of the west Pacific, which is 1.5 times more frequent than in the east Pacific and the tropical Atlantic oceans. However, the east Pacific exhibited the most intense rain intensity for the convective and mixed rain types while the tropical Atlantic showed the most intense rain intensity for all TMI rainy pixels. It was found that the deviation of TMI-derived rain rate yielded a big difference in region-to-region and rain type-to-type if the PR rain intensity value is assumed to be closer to the truth. Furthermore, the deviation by rain types showed opposite signs between convective and non-convective rain types. It was found that the region-to-region deviation differences reached more than 200% even though the selected tropical oceans have relatively similar geophysical environments. Therefore, the validation for the microwave rain estimation needs to be performed according to both rain types and climate regimes, and it also requires more sophisticated TMI algorithm which reflects the locality of rainfall characteristics.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.24 no.5
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• pp.646-654
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• 2020

This paper is to develop an electromagnetic wave-based sensor that can measure the spatial distribution of precipitation, and to a electromagnetic wave rain gauge (hereinafter, "EWRG") capable of simultaneously measuring rainfall, snowfall, and wind field, which are the core of heavy rain observation. Through this study, the LFM transmission and reception signals were theoretically analyzed. In addition, In order to develop a radar transceiver, LFM transceiver design and simulation were conducted. In this paper, we developed a K-BAND pulse-driven 6W SSPA(Solid State Power Amplifiers) transceiver using a small HMIC(Hybrid Microwave Integrated Circuit). It has more than 6W of output power and less than 5dB of receiving NF(Noise Figure) with short duty of 1% in high temperature environment of 65 degrees. The manufactured module emits LFM and Square Pulse waveform with the built-in waveform generator, and the receiver has more than 40dB of gain. The transceiver developed in this paper can be applied to the other small weather radar.

• Analytical Science and Technology
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• v.13 no.3
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• pp.297-303
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• 2000

Isotope-dilution inductively coupled plasma mass spectrometry was used to determine trace amounts of Cd, Cu, Pb, Ni and Zn in sediment. Sediment samples were dissolved by microwave digestion with addition of mixed acid ($HNO_3$, HF and $HClO_4$). Lead was determined after separation of alkaline and alkaline earth metals by an ammonium pyrrolidenedithiocarbarmate (APDC) solvent extraction. The other elements were determined after separation of iron, tin and titanium by hydroxide precipitation. Recovery efficiency of the analyte elements was not satisfactory, but most of matrix elements causing the isobaric interference could be effectively eliminated by the separation. Good agreement was achieved with the certified values in the analysis of the two sediment reference materials.

• Atmosphere
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• v.23 no.4
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• pp.453-470
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• 2013

As a part of the KIAPS Observation Processing System (KOPS), we have developed the modules of satellite radiance data pre-processing and quality control, which include observation operators to interpolate model state variables into radiances in observation space. AMSU-A (Advanced Microwave Sounding Unit-A) level-1d radiance data have been extracted using the BUFR (Binary Universal Form for the Representation of meteorological data) decoder and a first guess has been calculated with RTTOV (Radiative Transfer for TIROS Operational Vertical Sounder) version 10.2. For initial quality checks, the pixels contaminated by large amounts of cloud liquid water, heavy precipitation, and sea ice have been removed. Channels for assimilation, rejection, or monitoring have been respectively selected for different surface types since the errors from the skin temperature are caused by inaccurate surface emissivity. Correcting the bias caused by errors in the instruments and radiative transfer model is crucial in radiance data pre-processing. We have developed bias correction modules in two steps based on 30-day innovation statistics (observed radiance minus background; O-B). The scan bias correction has been calculated individually for each channel, satellite, and scan position. Then a multiple linear regression of the scan-bias-corrected innovations with several predictors has been employed to correct the airmass bias.

• Atmosphere
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• v.24 no.4
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• pp.523-532
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• 2014

In this study, thermal tropopause height defined from WMO (World Meteorological Organization) using temperature profile derived from Advance Microwave Sounding Unit-A (AMSU-A; hereafter named AMSU) onboard EOS (Earth Observing System) Aqua satellite is retrieved. The temperature profile of AMSU was validated by comparison with the radiosonde data observed at Osan weather station. The validation in the upper atmosphere from 500 to 100 hPa pressure level showed that correlation coefficients were in the range of 0.85~0.97 and the bias was less than 1 K with Root Mean Square Error (RMSE) of ~3 K. Thermal tropopause height was retrieved by using AMSU temperature profile. The bias and RMSE were found to be -5~ -37 hPa and 45~67 hPa, respectively. Correlation coefficients were in the range of 0.5 to 0.7. We also analyzed the change of tropopause height and temperature in middle troposphere in the extreme heavy rain event (23 October, 2003) associated with tropopause folding. As a result, the distinct descent of tropopause height and temperature decrease of ~8 K at 500 hPa altitude were observed at the hour that maximum precipitation and maximum wind speed occurred. These results were consistent with ERA (ECMWF Reanalysis)-Interim data (potential vorticity, temperature) in time and space.

• Korean Journal of Agricultural and Forest Meteorology
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• v.12 no.1
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• pp.63-73
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• 2010

A comprehensive mapping project for agroclimatic zoning in South Korea will end by April 2010, which has required 4 years, a billion won (ca. 0.9 million US dollars) and 22 experts from 7 institutions to complete it. The map database from this project may be categorized into primary, secondary and analytical products. The primary products are called "high definition" digital climate maps (HD-DCMs) and available through the state of the art techniques in geospatial climatology. For example, daily minimum temperature surfaces were prepared by combining the climatic normals (1971-2000 and 1981-2008) of synoptic observations with the simulated thermodynamic nature of cold air by using the raster GIS and microwave temperature profiling which can quantify effects of cold air drainage on local temperature. The spatial resolution of the gridded climate data is 30m for temperature and solar irradiance, and 270m for precipitation. The secondary products are climatic indices produced by statistical analysis of the primary products and includes extremes, sums, and probabilities of climatic events relevant to farming activities at a given grid cell. The analytical products were prepared by driving agronomic models with the HD-DCMs and dates of full bloom, the risk of freezing damage, and the fruit quality are among the examples. Because the spatial resolution of local climate information for agronomic practices exceeds the current weather service scale, HD-DCMs and the value-added products are expected to supplement the insufficient spatial resolution of official climatology. In this lecture, state of the art techniques embedded in the products, how to combine the techniques with the existing geospatial information, and agroclimatic zoning for major crops and fruits in South Korea will be provided.

• Atmosphere
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• v.31 no.4
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• pp.461-472
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• 2021

Yeongdong has frequently suffered from severe snowstorms, which generally give rise to societal and economic damages to the region in winter. In order to understand its mechanism, there has been a long-term measurement campaign, based on the rawinsonde measurements for every snowfall event at Gangneung since 2014. The previous observations showed that a typical heavy snowfall is generally accompanied with northerly or northeasterly flow below the snow clouds, generated by cold air outbreak over the relatively warmer East Sea. An intensive and multi-institutional measurement campaign has been launched in 2019 mainly in collaboration with Gangwon Regional Office of Meteorology and National Institute of Meteorological Studies of Korean Meteorological Administration, with a special emphasis on winter snowfall and spring windstorm altogether. The experiment spanned largely from February to April with comprehensive measurements of frequent rawinsonde measurements at a super site (Gangneung) with continuous remote sensings of wind profiler, microwave radiometers and weather radar etc. Additional measurements were added to the campaign, such as aircraft dropsonde measurements and shipboard rawinsonde soundings. One of the fruitful outcomes is, so far, to identify a couple of cold air damming occurrences, featuring lowest temperature below 1 km, which hamper the convergence zone and snow clouds from penetrating inland, and eventually make it harder to forecast snowfall in terms of its location and timing. This kind of comprehensive observation campaign with continuous remote sensings and intensive additional measurement platforms should be conducted to understand various orographic precipitation in the complex terrain like Yeongdong.