• Title/Summary/Keyword: Microcellular polymer

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The Insulation Property of Microcellular Injection Molding Plastics (초미세 발포 사출 성형품의 단열 특성)

  • Lee, Jung-Hyun;Hong, Soon-Kug;Kim, Ji-Hyun;Yoon, Jae-Dong
    • Proceedings of the KSME Conference
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    • 2001.06c
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    • pp.263-268
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    • 2001
  • MCPs means Micro Cellular Plastics. The micro-cells are generated in the products by the difference of dissolution through the pressure drop after super critical fluid of CO2 or N2 dissolves into polymer. We have developed injection molding process adopting MCPs and applied it to a broad range of injection molded thermoplastic materials and applications. It can prevent the leakage of impact strength and increase the thermal conductivity, moreover regulate the thermal conductivity. Then we can develop the high strength foaming plastics. Also, it can be gained a competitive advantage by utilizing its processing benefits, e.g. the lightweight products and significant reductions in material consumption.

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Reinforced Polymer/Clay Nanocomposite Foams with Open Cell Prepared via High Internal Phase Emulsion Polymerization (고내상 에멀션 중합에 의해 제조된 열린 기공을 갖는 고장도 고분자/점토 나노복합 발포체)

  • Song, In-Hee;Kim, Byung-Chul;Lee, Seong-Jae
    • Polymer(Korea)
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    • v.32 no.2
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    • pp.183-188
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    • 2008
  • Reinforced open cell micro structured foams were prepared by the polymerization of high internal phase emulsions incorporating inorganic thickeners. Organoclays were used as oil phase thickener, and sodium montmorillonite was used as aqueous phase thickener. Rheological properties of emulsions increased as oil phase thickener concentration and agitation speed increased, due to the reduced drop size reflecting both competition between continuous and dispersed phase viscosities and increase of shear force. Drop size variation with thickener concentration could be explained by a dimensional analysis between capillary number and viscosity ratio. Upon the foams polymerized by the emulsions, compression properties, such as crush strength and Young's modulus were measured and compared. Among the microcellular foams, the foam incorporated with an organoclay having reactive group showed outstanding properties. It is speculated that the exfoliated silicate layers inside polystyrene matrix, resulting in nanocomposite foam, are the main reason why this foam has enhanced properties.

Characterization of Poly(lactic acid) Foams Prepared with Supercritical Carbon Dioxide (초임계 이산화탄소를 이용하여 제조한 Poly(lactic acid) 발포체의 특성 분석)

  • Shin, Ji Hee;Lee, Hyun Kyu;Song, Kwon Bin;Lee, Kwang Hee
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.685-693
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    • 2013
  • The foams of a poly(lactic acid) modified by the reactive compounding were produced with the batch foaming technique using supercritical $CO_2(scCO_2)$. Experiments were performed at $105{\sim}135^{\circ}C$ and 12~24 MPa. The blowing ratio and foam structure were significantly affected by changing the temperature and pressure conditions in the foaming process. The blowing ratio first increased with increasing foaming temperature and saturation pressure, reached a maximum and then decreased with a further increase in the foaming temperature and saturation pressure. Decreasing the rate of depressurization permitted a longer period of cell growth and therefore larger microcellular structures were obtained.

Electrohydrodynamic Jet Process for Pore-Structure-Controlled 3D Fibrous Architecture As a Tissue Regenerative Material: Fabrication and Cellular Activities

  • Kim, Minseong;Lee, Hyeongjin;Kim, GeunHyung
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.134.1-134.1
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    • 2017
  • In this study, we propose a new scaffold fabrication method, "direct electro-hydrodynamic jet process," using the initial jet of an electrospinning process and ethanol media as a target. The fabricated threedimensional (3D) fibrous structure was configured with multilayered microsized struts consisting of randomly entangled micro/nanofibrous architecture, similar to that of native extracellular matrixes. The fabrication of the structure was highly dependent on various processing parameters, such as the surface tension of the target media, and the flow rate and weight fraction of the polymer solution. As a tissue regenerative material, the 3D fibrous scaffold was cultured with preosteoblasts to observe the initial cellular activities in comparison with a solid-freeform fabricated 3D scaffold sharing a similar structural geometry. The cell-culture results showed that the newly developed scaffold provided outstanding microcellular environmental conditions to the seeded cells (about 3.5-fold better initial cell attachment and 2.1-fold better cell proliferation).

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Ultrasonic Processing of Polymer Foam (고분자 포움의 초음파 가공)

  • 변성광;윤재륜
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.4
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    • pp.618-624
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    • 1989
  • Ultrasonically induced bubble formation in thermoplastic matrix was investigated experimentally and theoretically. polystyrene was saturated with nitrogen under the pressure of 0.2 to 3.45 MPa in a pressure chamber, followed by pressure release and ultrasonic bubble nucleation. Zinc stearate was added to polystyrene as the nucleating agent to induce heterogeneous nucleation. Various mixture of low density polyethylene and polyethylene wax was also saturated with the gas. The foamed specimens with or without ultrasonically induced bubble nucleation was modeled by modifying the classical nucleation theory. The rate of ultrasonic nucleation was predicted for homogeneous and heterogeneous nucleation at a conical cavity. This study showed that the heterogeneous and heterogeneous nucleation at a conical cavity. This study showed that the heterogeneous nucleation must be employed for ultrasonic production of bubbles in a viscous fluid and the homogeneous nucleation for ultrasonic production of bubbles in a low viscosity fluid.

Study of Non Pressure and Pressure Foam of Bio-based Polymer Containing Blend (바이오 기반 폴리머가 포함된 블렌드의 상압 및 가압 발포 연구)

  • Dong-Hun Han;Young-Min Kim;Danbi Lee;Seongho Son;Geon-hee Seo;Hanseong Kim
    • Composites Research
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    • v.36 no.5
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    • pp.297-302
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    • 2023
  • There are several methods for shaping foams, but the most commonly used methods involve the use of resin mixed with a foaming agent, which is then foamed under high temperature and pressure in the case of compression foaming, or foamed under high temperature without applying pressure in the case of atmospheric foaming. The polymers used for foaming require design and analysis of optimal foaming conditions in order to achieve foaming under ambient pressure. Environmentally friendly bio-based polymers face challenges when it comes to foaming on their own, which has led to ongoing research in blending them with resins capable of traditional foam production. This study investigates changes in the characteristics of bio-based polymer-EVA blend foams based on variations in the content of bio-based polymers and explores the optimal foaming conditions according to crosslinking. The correlation between foaming characteristics and mechanical properties of the foams was examined. Through this research, we gained insights into how the content of bio-based polymers affects the properties of foams containing bio-based polymers and identified differences between ambient pressure and high-pressure foaming processes. Additionally, the feasibility of commercializing bio-based polymer-EVA composite foams was confirmed.