• Title/Summary/Keyword: Micro pore

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Preparation of Activated Carbon Fibers from Cost Effective Commercial Textile Grade Acrylic Fibers

  • Bikshapathi, Mekala;Verma, Nishith;Singh, Rohitashaw Kumar;Joshi, Harish Chandra;Srivastava, Anurag
    • Carbon letters
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    • v.12 no.1
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    • pp.44-47
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    • 2011
  • Activated carbon fibers (ACFs) were prepared from cost effective commercial textiles through stabilization, carbonization, and subsequently activation by carbon dioxide. ACFs were characterized for surface area and pore size distribution by physical adsorption of nitrogen at 77 K. ACFs were also examined for various surface characteristics by scanning electron microscopy, Fourier transform infrared spectroscopy, and CHNO elemental analyzer. The prepared ACFs exhibited good surface textural properties with well developed micro porous structure. With improvement in physical strength, the commercial textile grade acrylic precursor based ACFs developed in this study may have great utility as cost effective adsorbents in environmental remediation applications.

Water Treatment By VPMF (VPMF를 이용한 수처리방법)

  • 최충현;유승철
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.107-108
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    • 1997
  • 1. 서론 : 분리막 시설의 전처리방법에는 Sand Filter, 유니필터 그리고 케트리지(5$\mu$m) 필터가 상용되어 왔다. 그러나 Sand Filter와 유니필터 등은 설치비용은 저렴하지만 처리수질이 5$\mu$m 케트리지 필터보다 떨어지므로 분리막시설의 전처리로 미흡하다. 통상적인 분리막 시설의 설계시에 사용되는 5$\mu$m 케트리지 필터는 역세가 불가능하므로 교체하지만 대규모의 수처리설비나, SS의 농도가 높은 경우에 있어서 분리막의 전처리시설로 적합치 않다. 한편 5$\mu$m 케트리지 필터는 대체하기 위한 정밀여과장치가 많이 개발되고 있으며 Z필터, BMF, Cross Filter 등이 그러한 여과장치들이다. 본 글에서 소개할 VPMF(Variable Pore Micro Filter, 가변세공 정밀여과장치)도 그러한 여과장치와 유사한 기능과 성능을 가진 정밀여과장치이다. 본 연구에서는 Caolin을 이용하여 50~100ppm 사이의 SS농도하에서 VPMF의 처리수질, 역세효율, SS포집능력 등을 평가해 볼 것이다.

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An Experimental study on the effect that sampling position of cement matrix influences Quantitative Analysis result (시멘트 경화체 시료의 채취 위치가 정량분석 결과에 미치는 영향에 관한 실험적 연구)

  • Jin, Joo-Ho;Lee, Sang-Hyun;Lee, Han-Seung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.345-346
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    • 2009
  • This research focused on large variation of the result of Ca(OH)$_2$ quantity by TG/DTA test or micro-pore size by MIP test. Assume that sample postion has influenced on experimental result, therefore, relationship between sampling position and the experimental result was studied As a result of the research, it is obvious that samples from inside(P-3) shows more Ca(OH)$_2$ and less porosity than samples from outside(P-1).

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Fabrication of Macroporous Silicon Diaphragms (매크로기공을 갖는 다공질 실리콘 다이어프램의 제작)

  • Min, Nam-Ki;Ha, Dong-Sik;Jeong, Woo-Sik;Min, Suk-Ki
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1558-1560
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    • 1998
  • Macroporous silicon diaphragms 20 to $200{\mu}m$ thick have been formed on p-type silicon by anistropic etching in TMAH solution and then by electrochemical etching in HF-ethanol-water solution with an applied current. The pores have a pore diameter of $1.5{\sim}2{\mu}m$, with a depth of $20{\sim}30{\mu}m$ and are not interconnected, which are in sharp contrast to the porous silicon reported previouly for similarly doped p-Si. The fabrication of macroporous silicon and free-standing diaphragms is expected to offer new applications for microsensors, micro-machining, and separators.

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Effect of Sealing Process on the Tribological Behavior of the Plasma Spray Zirconia Based Coatings (지르코니아 충전이 지르코니아계 용사코팅층의 마모마찰에 미치는 영향)

  • 신종한;임대순;안효석
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1998.10a
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    • pp.265-271
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    • 1998
  • High temperature wear behavior of plasma sprayed zirconia based coating sealing with zirconia sol were investigated for high temperature wear resistance application. The zirconia powders containing 2.5, 5.0, 7.5, 10.0 mol% of MoS$_2$, $Fe_2O_3$ for plasma spray were made by spray drying method. As-sprayed coating was sealed by zirconia-sol to fill up the pore and crack in coating. wear test were performed at temperature ranges from room temperature to 600$\circ$C. The microstructural changes of before and after sealing process were examined by SEM, XRD and EPMA. After sealing process, the porosity was decreased and micro-hardness was increased. The wear properties of coating after sealing process were improved by sealing of pores and cracks. The behavior of wear amount and coefficient of friction were same tendency to before sealing process.

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Evaluation on Sulfate Attack Resistance of Cement Matrix (시멘트 경화체의 황산염침식 저항성 평가)

  • 문한영;김홍삼;이승태
    • Journal of the Korea Concrete Institute
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    • v.12 no.5
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    • pp.141-151
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    • 2000
  • Compressive strength, sulfate deterioration factor(SDF) and length change of 5 types of mortars immersed in sodium sulfate solution were observed. As the results of tests, it was found that the sulfate resistance of blended cement mortars were superior to that of portland cement mortars. Pore volume with diameter larger than 0.1 $\mu\textrm{m}$ of 5 types of pastes indicated that the micro-structures of blended cement pastes were denser, due to pozzolan reaction and latent hydraulic properties, than those of portland cement pastes. The XRD, ESEM, EDS and TG analyses demonstrated that the reactants such as ettringite and gypsum were significantly formed in portland cement pastes. Besides, compared with the $Ca(OH)_2$ content of ordinary portland cement pastes immersed in water and sodium sulfate solution, the $Ca(OH)_2$ contents of fly ash blended cement and ground granulated blast-furnace slag cement paste were about 58% and 28% in water, and 55% and 20% in sodium sulfate solution, respectively.

Structure and EDLC Characteristics of Pitch-based Activated Carbons

  • Kim, Young-Ha;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.627-627
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    • 2009
  • In this work, the activated carbons (ACs) with high porosity were synthesized from pitch by KOH chemical activation. The structure and surface properties of ACs were characterized by means of elemental analysis, X-ray diffraction (XRD), and X-ray photoelectron spectroscopy(XPS). And, the influence of the KOH-to-pitch ratio on the porosity of the ACs was investigated using the nitrogen adsorption isotherms at 77 K and a scanning electron microscopy (SEM). As a result, pitch could be successfully converted into ACs with well-developed micro and mesopores. The specific surface areas and pore volumes were increased with an increase of the KOH-to-pitch ratio. Furthermore, it was found that the addition of KOH led to the transformation of the micropores to the meso- and macropores. In the application to electric double layer capacitors (EDLC), the pitch-based ACs showed a higher capacitance per weight and per volume, and an excellent electrochemical stability in the high voltage region.

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Fabrication of a Superhydrophobic Water-Repellent Mesh for Underwater Sensors

  • An, Taechang
    • Journal of Sensor Science and Technology
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    • v.22 no.2
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    • pp.100-104
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    • 2013
  • A superhydrophobic mesh is a unique structure that blocks water, while allowing gases, sound waves, and energy to pass through the holes in the mesh. This mesh is used in various devices, such as gas- and energy-permeable waterproof membranes for underwater sensors and electronic devices. However, it is difficult to fabricate micro- and nano-structures on three-dimensional surfaces, such as the cylindrical surface of a wire mesh. In this research, we successfully produced a superhydrophobic water-repellent mesh with a high contact angle (> $150^{\circ}$) for nanofibrous structures. Conducting polymer (CP) composite nanofibers were evenly coated on a stainless steel mesh surface, to create a superhydrophobic mesh with a pore size of $100{\mu}m$. The nanofiber structure could be controlled by the deposition time. As the deposition time increased, a high-density, hierarchical nanofiber structure was deposited on the mesh. The mesh surface was then coated with Teflon, to reduce the surface energy. The fabricated mesh had a static water contact angle of $163^{\circ}$, and a water-pressure resistance of 1.92 kPa.

Superitical fluid (SCF) technology application to the regeneration of industrial catalyst contaminated with toxic materials (독성폐기물로 오염된 산업촉매 재생공정에 초임계유체기술의 적용)

  • 이재동;윤용수;홍인권;정일현
    • Journal of the Korean Society of Safety
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    • v.7 no.1
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    • pp.13-19
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    • 1992
  • Supercritical fluid technology was applied to the regeneration of industrial catalyst contaminated with toxic materials. The regeneration process of activated loaded with phenol was proposed, then the adsorphon tower was packed with the activated carbon-bed. Phenol diffuses into supercritical carbon dioxide(SCC) through the micro-pore and voldge of the activated carbon. The saturated solubility of phenol in SCC depended on the density of SCC varing with temperature and pressure conditions. Therefore, the fasile phase equilibrium calculation model of dxpanded liquid One was proposed, and equilibrium solubility of phenol in SCC was calculated using the model theoretically. The regeneration mechanism of activated carbon was analysed by degree of saturation of phenol and diffusion in SCC. The solubility prediction was more satisfactory for the wide range of SCC density than the dense gas model and the desorption of phenol depended on the degree of saturation of phenol in SCC.

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Modeling of the Time-Dependent Changes of Micro Pore Structures in Concrete for Nuclear Power Plants (원전콘크리트의 미세공극구조 경시변화 예측 모델 개발)

  • Kim, Joo-Hyung;Jung, Sang-Hwa;Moon, Jae-Heum
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2010.04a
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    • pp.762-765
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    • 2010
  • 본 연구에서는 원전격납구조물과 같이 고품질을 요하는 콘크리트의 내구성설계 및 관리에 필요한 구조물 건전성 평가시스템 구축의 일환으로 콘크리트 미세공극구조 형성 예측 프로그램을 개발하였다. 개발된 미세공극구조 형성 예측 프로그램은 콘크리트의 강도 등과 같은 역학적 특성 및 유해이온 확산거동 예측에 활용되는 부분으로서 기존의 연구결과로부터 개발된 모델식들을 바탕으로 개발되었다. 개발된 프로그램은 콘크리트 시험체로부터 구하여진 MIP 실험결과와 비교해 보았으며, 상관성을 검토하였다.

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