• Title/Summary/Keyword: Mg-reduction

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철과 양수성 물질을 이용한 PCE와 크롬 제거에 관한 연구

  • 조현희;천병식;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.68-71
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    • 2004
  • Effects of surfactants and natural organic matter (NOM) on the sorption and reduction of tetrachloroethylene (PCE) and chromate with iron were examined in this study. PCE and chromate reduction by iron depended on the ionic type of the surfactants in this study. The apparent reaction rate constants of PCE with Triton X-100 and hexadecyltrimethyl ammonium (HDTMA) at one half and two times of the critical micelle concentration (CMC) were relatively higher than without surfactants because of the enhanced PCE partitioning and surface concentration. In the presence of sodium dodecyl benzene sulfonate (SDDBS) at 2000 mg/L and NOM at 50 mg/L, the apparent reaction rate constants of PCE increased, but TCE production decreased. The enhanced removal rate of PCE was not due to the dechlorination, and the sorption was dominant iron with SDDBS and NOM. The apparent reaction rate constants of chromate by iron with Triton X-100 and NOM were 1.4-3.1 times lower than without surfactants while that with HDTMA was two times higher than without HDTMA, When the sorbed HDTMA molecules form admicelles, negatively-charged chromate has an affinity for the positively-charged HDTMA head group.

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The Effects of Bo-Jung-Chi-Seub-Tang Administration on Body Composition, Blood Biochemistrical Factors and Hormonal Changes during 2 weeks Weight Reduction in TaeKwonDo Athletes (태권도선수(跆拳道選手)의 체중감량시(體重減量時) 보중치습탕(補中治濕湯) 투여(投與)가 신체조성(身體組成), 혈약성분(血液成分) 및 호르몬 변화(變化)에 미치는 영향(影響))

  • Oh, Jae-Keun;Lee, Myeong-Jong
    • The Journal of Korean Medicine
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    • v.19 no.2
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    • pp.391-400
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    • 1998
  • This study was to investigate the effects of Bo-Jung-Chi-Seub-Tang administration on body composition, blood biochemistrical factors and hormonal changes during 2 weeks Weight Reduction in TaeKwonDo Athletes. 10 subjects were belong to be in elite athletes of KNUPE. They were divided two groups(administration group and non-administration) by 5 subjects in each group randomly. they were measured about body composition(% Fat, Fat Wt, LBM, TBW), Blood Biochemistrical Factors(glucose, TG, total protein, albumin, BUN, Uric acid, Ca, Pi, Mg) and Hormonal Changes(Renin, Aldosteron). As the results of the experiment, conclusions were made as follows: In terms of % Fat, Fat W.T., Mg, TG, Renin, it was shown significant differences between two groups. Although there were no significant differences, rate of weight reduction and levels of LBM, BUN in Bo-Jung-Chi-Seub-Tang administration group were changed more lower than non-administration group.

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Fabrication and Characterization of High-activity Pt/C Electrocatalysts for Oxygen Reduction

  • Lim, Bo-Rami;Kim, Joung-Woon;Hwang, Seung-Jun;Yoo, Sung-Jong;Cho, Eun-Ae;Lim, Tae-Hoon;Kim, Soo-Kil
    • Bulletin of the Korean Chemical Society
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    • v.31 no.6
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    • pp.1577-1582
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    • 2010
  • A 20 wt % Pt/C is fabricated and characterized for use as the cathode catalyst in a polymer electrolyte membrane fuel cell (PEMFC). By using the polyol method, the fabrication process is optimized by modifying the carbon addition sequence and precursor mixing conditions. The crystallographic structure, particle size, dispersion, and activity toward oxygen reduction of the as-prepared catalysts are compared with those of commercial Pt/C catalysts. The most effective catalyst is obtained by ultrasonic treatment of ethylene glycol-carbon mixture and immediate mixing of this mixture with a Pt precursor at the beginning of the synthesis. The catalyst exhibits very uniform particle size distribution without agglomeration. The mass activities of the as-prepared catalyst are 13.4 mA/$mg_{Pt}$ and 51.0 mA/$mg_{Pt}$ at 0.9 V and 0.85 V, respectively, which are about 1.7 times higher than those of commercial catalysts.

High glucose diets shorten lifespan of Caenorhabditis elegans via ectopic apoptosis induction

  • Choi, Shin-Sik
    • Nutrition Research and Practice
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    • v.5 no.3
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    • pp.214-218
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    • 2011
  • Diets based on carbohydrates increase rapidly the blood glucose level due to the fast conversion of carbohydrates to glucose. High glucose diets have been known to induce many lifestyle diseases. Here, we demonstrated that high glucose diet shortened the lifespan of Caenorhabditis elegans through apoptosis induction. Control adult groups without glucose diet lived for 30 days, whereas animals fed 10 mg/L of D-glucose lived only for 20 days. The reduction of lifespan by glucose diet showed a dose-dependent profile in the concentration range of glucose from 1 to 20 mg/L. Aging effect of high glucose diet was examined by measurement of response time for locomotion after stimulating movement of the animals by touching. Glucose diet decreased the locomotion capacity of the animals during mid-adulthood. High glucose diets also induced ectopic apoptosis in the body of C. elegans, which is a potent mechanism that can explain the shortened lifespan and aging. Apoptotic cell corpses stained with SYTO 12 were found in the worms fed 10 mg/L of glucose. Mutation of core apoptotic regulatory genes, CED-3 and CED-4, inhibited the reduction of viability induced by high glucose diet, which indicates that these regulators were required for glucose-induced apoptosis or lifespan shortening. Thus, we conclude that high glucose diets have potential for inducing ectopic apoptosis in the body, resulting in a shortened lifespan accompanied with loss of locomotion capacity.

A Study on Pain relief effects and Allergic responses for the Osteoarthritis of the knee joint Between Sweet Bee Venom and Bee Venom Pharmacopuncture (동일 농도0.1mg/ml)의 Sweet Bee Venom과 봉약침의 퇴행성 슬관절염에 대한 임상연구)

  • Kim, Sung-Chul;Na, Won-Min;Lee, Sung-Young;Jang, Eun-Ha;Lim, Seung-Il
    • Journal of Pharmacopuncture
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    • v.11 no.1
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    • pp.31-40
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    • 2008
  • Objectives : To verify pain relief effects and allergy inhibitory action for the osteoarthritis of the knee joint in Sweet Bee Venom in which allergy causing enzyme is removed. Methods : We randomly allocated 30 participants to treatment group Sweet Bee Venom and Bee Venom. Outcomes on pain reduction were measured by 100mm VAS(Visual Analog Scale). And we recorded into details allergic responses during Pharmacopuncture treatment. Results : Whole body condition and pain rate through VAS measurement were improved significantly in 2 weeks. We could get difference in pain score of two Pharmacopuncture groups significantly in 2 weeks. Sweet BV group($0.1{\beta}mg/m{\ell}$) showed superior reduction in pain compared to the BV group($0.1{\beta}mg/m{\ell}$) significantly. And other allergic responses such as edema, itchiness, pain were significantly lower in the Sweet BV group.

Improvement of Water Treatment Efficiency by Poly Aluminum Chloride Overdosing in High pH Raw Water (폴리염화알루미늄 과량주입에 의한 고(高) pH 원수의 수처리효율 개선)

  • Lim, Jaecheol;Kim, Jinkeun
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.1
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    • pp.39-46
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    • 2009
  • A method to improve water treatment efficiency by coagulant overdosing for high pH raw water at a drinking water treatment plant (WTP) which had no pH adjusting facilities was investigated. Poly aluminum chloride (PACl) was used for coagulant, and turbidity removal efficiency was evaluated as a function of PACl dosage increases. pH and turbidity of supernatant of jar-tester were 7.10 and 0.50 NTU respectively, when the turbidity, pH, alkalinity, water temperature, conductivity of raw water were 1.75 NTU, 9.38, 46.5 mg/L, $6.4^{\circ}C$, $400{\mu}s/cm$, respectively. Turbidity of settled water was reduced from 2.18 NTU to 0.28 NTU (87% reduction) when PACl dosage was increased from 16 mg/L to 45 mg/L at a full scale WTP. This can be attributed to the recovery of coagulant efficiency by pH reduction with the increase of coagulant dose, however coagulation efficiency was reduced with the formation of Al(OH)4- by PACl addition at higher pH. Coagulant overdosing was proven to be a rapid and effective method for high pH raw water, which can be applied at drinking WTP.

Laser Welding of AZ31B-H24 Mg Alloy with AZ61 Filler Wire (AZ61 필러 와이어를 첨가한 AZ31B-H24 마그네슘 합금의 레이저 용접)

  • Ryu, Chung-Sun;Bang, Kook-Soo;Lee, Mok-Young;Chang, Woong-Sung
    • Journal of Welding and Joining
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    • v.26 no.6
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    • pp.54-58
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    • 2008
  • Laser welding with AZ61 filler wire was carried out to improve formability though reduction of porosity and formation of under fill bead. Optimum welding condition and mechanical properties of butt joint for $400{\times}500{\times}1.3mm$ magnesium sheets were studied. Optimal welding conditions of laser power, welding speed, and defocusing length are 1000W, 3m/min, and 2mm, respectively. Results of tensile test indicated that both tensile strength and elongation of specimens welded with filler wire were improved at room temperature because of reduction of porosity and under-filled bead formation in addition to the precipitation hardening and microstructure refinement by Al-Mn and Mg-Al-Zn precipitates. At elevated temperature of $200{\sim}350^{\circ}C$, fracture location of tensile specimen was shifted from weld metal to base metal, indicating less softening of weld metal than base metal.

Formation of Mo(NAr)(PMe₃)₂Cl₃and Mo₂(PMe₃)₄Cl₄from Reduction of Mo(NAr)₂Cl₂(DME) with Mg in the Presence of PMe₃[Ar=2,6-diisopropylphenyl]

  • 정건수;박병규;Lee, Soon W.
    • Bulletin of the Korean Chemical Society
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    • v.18 no.2
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    • pp.213-217
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    • 1997
  • Magnesium reduction of Mo(N-C6H3-2,6-i-Pr2)2Cl2(DME) in the presence of trimethylphosphine led to a mixture of Mo(N-C6H3-2,6-i-Pr2)(PMe3)2Cl3, 1, and Mo2(PMe3)4Cl4, 2. In solution 1 is slowly air-oxidized to Mo(N-2,6-i-Pr2-C6H3)(OPMe3)(PMe3)Cl3, 3. 1 is chemically inert to carbon nucleophiles (ZnMe2, ZnEt2, AlMe3, AlEt3, LiCp, NaCp, TlCp, NaCp*, MeMgBr, EtMgBr), oxygen nucleophiles (LiOEt, LiO-i-Pr, LiOPh, LiOSPh), and hydrides (LiBEt3H, LiBEt3D). Crystal data for 1: orthorhombic space group P212121, a=11.312(3) Å, b=11.908(3) Å, c=19.381(6) Å, Z=4, R(wR2)=0.0463 (0.1067). Crystal data for 2: monoclinic space group Cc, a=18.384(3) Å, b=9.181(2) Å, c=19.118(3) Å, b=124.98(1)°, Z=4, R(wR2)=0.0228 (0.0568). Crystal data for 3: orthorhombic space group P212121, a=11.464(1) Å, b=14.081(2) Å, c=16.614(3) Å, Z=4, R(wR2)=0.0394 (0.0923).

Removal of sulfate ion from semiconductor wastewater by ettringite precipitation

  • Chung, Chong-Min
    • Membrane and Water Treatment
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    • v.13 no.4
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    • pp.183-189
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    • 2022
  • This study seeks towards an optimal way to control sulfate ions in semiconductor wastewater effluent with potential eco-toxicity. We developed a system based on ettringite (Ca6Al2(SO4)3(OH)12·26H2O). The basic idea is that the pH of the water is raised to approximately 12 with Ca(OH)2. After, aluminium salt is added, leading to the precipitation of ettringite. Lab-scale batch and continuous experiment results with real semiconductor wastewater demonstrated that 1.5 and 1 of stoichiometric quantities for Ca2+ and A3+ with pH above 12.7 could be considered as the optimal operation condition with 15% of sludge recycle to the influent. A mixed AlCl3 + Fe reagent was selected as the beneficial Al3+ source in ettringite process, which resulted in 80% of sludge volume reduction and improved sludge dewaterability. The results of continuous experiment showed that with precipitation as ettringite, sulfate concentration can be stably reduced to less than 50 mg/L in effluent from the influent 2,050 ± 175 mg/L on average (1,705 ~ 2,633 mg/L).

Effects of Alloying Elements on the Properties of High Strength and High Thermal Conductivity Al-Zn-Mg-Fe Alloy for Die Casting (다이캐스팅용 Al-Zn-Mg-Fe 합금의 특성에 미치는 Zn 및 Mg 첨가의 영향)

  • Kim, Ki-Tae;Lim, Young-Suk;Shin, Je-Sik;Ko, Se-Hyun;Kim, Jeong-Min
    • Journal of Korea Foundry Society
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    • v.33 no.4
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    • pp.171-180
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    • 2013
  • The effects of alloying elements on the solidification characteristics, microstructure, thermal conductivity, and tensile strength of Al-Zn-Mg-Fe alloys were investigated for the development of high strength and high thermal conductivity aluminium alloy for die casting. The amounts of Zn and Mg in Al-Zn-Mg-Fe alloys had little effect on the liquidus/solidus temperature, the latent heat for solidification, the energy release for solidification and the fluidity of Al-Zn-Mg-Fe alloys. Thermo-physical modelling of Al-Zn-Mg-Fe alloys by the JMatPro program showed $MgZn_2$, AlCuMgZn and $Al_3Fe$ phases in the microstructure of the alloys. Increased amounts of Mg in Al-Zn-Mg-Fe alloys resulted in phase transformation, such as $MgZn_2{\Rightarrow}MgZn_2+AlCuMgZn{\Rightarrow}AlCuMgZn$ in the microstructure of the alloys. Increased amounts of Zn and Mg in Al-Zn-Mg-Fe alloys resulted in a gradual reduction of the thermal conductivity of the alloys. Increased amounts of Zn and Mg in Al-Zn-Mg-Fe alloys had little effect on the tensile strength of the alloys.