• Title/Summary/Keyword: Mg-Zn

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Dependence of luminescence property of ZnMgS:Mn thin film phosphor on RTA temperature (ZnMgS:Mn 박막 형광체의 RTA 온도 변화에 따른 발광 특성 의존성)

  • Lee, Dong-Chin;Yun, Sun-Jin;Jeon, Duk-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05a
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    • pp.102-105
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    • 2004
  • With varying rapid thermal annealing (RTA) temperature, luminescent properties of ZnMgS:Mn thin film sputter-deposited with one target were measured. Although all samples have the same composition, $Zn_{1-x}Mg_xS:Mn$ (x=0.25) can emit luminescence between 580 and 614 nm, which is controlled by only RTA temperature. It is understood that the energy band gap shift of ZnMgS:Mn thin film phosphor occurs with varying RTA temperature.

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Effect of MgO Buffer Layer on the Structural Properties of Sputter-grown ZnO Thin Film (스퍼터링법으로 증착된 산화아연 박막의 구조적 성질에 대한 산화마그네슘 완충층의 효과 연구)

  • Lim, Young-Soo
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.673-678
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    • 2009
  • The effect of MgO buffer layer on the structural properties of sputter-grown ZnO thin film was investigated. Sapphire (0001) and Si (100) substrate were used for the growth and MgO buffer layer was inserted between ZnO thin film and the substrate. X-ray diffraction pattern indicated that enhanced crystallinity in the ZnO thin film grown was achieved by inserting very thin MgO buffer layer, regardless of the substrate type. The strain in the ZnO thin film could also be controlled by the insertion of the MgO buffer layer, and tendency of the strain was strongly dependent on the substrate type.

A study on corrosion resistance of Zn-Mg thin film by anodic polarization measurement (양극 분극 측정에 의한 Zn-Mg 합금 박막의 내식 특성 연구)

  • Kim, Yeon-Won;Gang, Jun;Ra, Hye-Na;Kim, Gi-Jun;Mun, Gyeong-Man;Lee, Myeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.05a
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    • pp.223-223
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    • 2009
  • PVD 법으로 제작한 Zn-Mg합금 박막의 내식성 평가를 위해 양극 분극 실험을 실시하였다. 강판상에 제작한 Zn 단일 박막은 활성적 거동을 나타내는 반면 Zn-Mg 합금 박막은 부동태 거동을 나타내었다. 여기서는 Mg 원소 첨가에 따른 Zn-Mg 합금박막의 조성이나 구조 변화가 내식성 향상에 어떤 영향이 있는지를 양극분극측정을 통해 고찰-검토했다.

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Microstructure and Properties of High Strength High Ductility Al-Mg-Zn Casting Alloy (고강도 고인성 Al-Mg-Zn 주조합금의 미세조직 및 특성)

  • Kim, Jeong-Min;Ha, Tae-Hyung
    • Journal of Korea Foundry Society
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    • v.36 no.6
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    • pp.181-186
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    • 2016
  • The typical microstructure of Al-5%Mg-2%Zn cast alloy mainly consists of an aluminum matrix with a small amount of AlMgZn 2nd phase. The secondary dendrite arm spacing and the grain size of the cast alloy tend to be inversely proportional to the section thickness of casting; however, the tensile properties cannot be said to be clearly related to the cast microstructure. After T6 heat treatment, the tensile strength of the alloy was enhanced significantly. TEM analysis results show that very fine AlMgZn precipitates were formed after the heat treatment. The corrosion resistance, measured according to the corrosion potential, was found to increase slightly after the conducting of heat treatment.

Microstructural and Mechanical Characteristics of Wrought Mg-Sn-Zn Alloy

  • Kim, J.M.;Park, J.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.22 no.2
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    • pp.75-79
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    • 2009
  • Precipitate formations and grain size variations in various Mg-Sn-Zn alloys have been investigated and their effects on the tensile properties and sheet metal formability were evaluated. MgSn and MgZn precipitates were observed in the alloy sheets, however any clear difference in morphology or size for the precipitates could not be found even though MgSn precipitates tend to be larger than MgZn. The highest formability in terms of conical cup value was found in the Mg-4 wt%Sn-2 wt%Zn where the high tensile elongation and the reduced grain coarsening at elevated temperatures were observed.

Effect of Sn Addition on Corrosion Behavior of Mg-4%Zn Casting Alloy (Mg-4%Zn 주조 합금의 부식 거동에 미치는 Sn 첨가의 영향)

  • Han, Jin-Gu;Jun, Joong-Hwan
    • Journal of Korea Foundry Society
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    • v.37 no.3
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    • pp.63-70
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    • 2017
  • In the present study, effects of an addition of Sn on the microstructure and corrosion behavior were investigated in Mg-4%Zn-(0-3)%Sn casting alloys. With an increase in the Sn content, the ${\alpha}-(Mg)$ dendritic cell size was reduced, whereas the total amount of precipitates increased due to the formation of the $Mg_2Sn$ phase. It was found in immersion and electrochemical corrosion tests that the addition of Sn has a detrimental effect on the corrosion resistance of the Mg-4%Zn alloy. Microstructural examinations of the corrosion product and the corroded surface indicated that an accelerated micro-galvanic effect by the $Mg_2Sn-phase$ particles and a less protective corrosion product on the surface were responsible for the increased corrosion rate at a higher Sn content.

Consolidation Behavior of Gas Atomized Mg-Zn-Y Alloy Powders by Spark Plasma Sintering (Spark Plasma Sintering에 의한 가스분무 Mg-Zn-Y 합금분말의 성형특성)

  • Lee, Jin-Kyu;Kim, Taek-Soo;Bae, Jung-Chan
    • Journal of Powder Materials
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    • v.14 no.2 s.61
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    • pp.140-144
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    • 2007
  • Using Spark Plasma Sintering process (SPS), consolidation behavior of gas atomized $Mg_{97}Zn_1Y_2$ alloys were investigated via examining the microstructure and evaluating the mechanical properties. In the atomized ahoy powders, fine $Mg_{12}YZn$ particles were homogeneously distributed in the ${\alpha}-Mg$ matrix. The phase distribution was maintained even after SPS at 723 K, although $Mg_{24}Y_5$ particles were newly precipitated by consolidating at 748 K. The density of the consolidated bulk Mg-Zn-Y alloy was $1.86g/cm^3$. The ultimate tensile strength (UTS) and elongation were varied with the consolidation temperature.

Microstructures and Mechanical Properties of Consolidated Mg-Zn-Y Alloy

  • Lee, Jin-Kyu;Kim, Taek-Soo;Jeong, Ha-Guk;Bae, Jung-Chan
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1035-1036
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    • 2006
  • The microstructure and mechanical properties of the $Mg_{97}Zn_Y_2$ alloy prepared by spark plasma sintering of gas atomized powders have been investigated. After consolidation, precipitates were observed to form in the ${\alpha}-Mg$ solid solution matrix of the $Mg_{97}Zn_1Y_2$ alloy. These precipitates consisted of $Mg_{12}YZn$ and $Mg_{24}Y_5$ phases. The density of the consolidated bulk Mg-Zn-Y alloy was $1.86g/cm^3$. The ultimate tensile strength and elongation were dependent on the consolidation temperature, which were in the ranges of 280 to 293 MPa and 8.5 to 20.8 %, respectively.

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The Effect of Mg Precursors on Optical and Structural Characteristics of Sol-Gel Processed Mg0.3Zn0.7O Thin Films (졸-겔법으로 성장시킨 Mg0.3Zn0.7O 박막의 Mg 전구체의 종류에 따른 광학적·구조적 특성에 관한 연구)

  • Yeom, Ahram;Kim, Hong Seung;Jang, Nak Won;Yun, Young;Ahn, Hyung Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.3
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    • pp.214-218
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    • 2020
  • In this study, MgxZn1-xO thin films, which can be applied not only to active layers of light-emitting devices (LEDs), such as UV-LEDs, but also to solar cells, high mobility field-effect transistors, and power semiconductor devices, are fabricated using the sol-gel method. ZnO and Mg0.3Zn0.7O solution synthesized by the sol-gel method and the thin film were grown by spin coating on a Si (100) substrate and sapphire substrate. The solutions are synthesized by dissolving precursor materials in 2-methoxyethanol (2-ME) solvent, and then monoethanolamine (MEA) was added to the mixed solution as a sol stabilizer. Zinc acetate dihydrate is used as a ZnO precursor, while Mg nitrate hexahydrate and Mg acetate tetrahydrate are used as an MgO precursor. Then, the optical and structural characteristics of the fabricated thin films are compared. The molar concentration of the Zn precursor in the solvent is fixed at 0.3 M, and the amount of the Mg precursor is 30% of Mg2+/Zn2+. The optical characteristics are measured using an UV-vis spectrophotometer, and the transmittance of each wavelength is measured. Structural characteristics are measured using X-ray diffraction (XRD) and transmission electron microscopy (TEM). Composition analyses are performed using energy dispersive X-ray spectroscopy (EDS). The Mg0.3Zn0.7O thin film was well formed at the ratio of the Mg precursor added regardless of the type of Mg precursor, and the c-axis of the thin film was decreased, while the band gap was increased to 3.56 eV.

Gas Absorption and Release Properties of Zn(BH4)2 and MgH2-Zn(BH4)2-Ni-Ti-Fe Alloy

  • Kwak, Young Jun;Kwon, Sung Nam;Song, Myoung Youp
    • Korean Journal of Materials Research
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    • v.25 no.1
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    • pp.43-47
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    • 2015
  • $Zn(BH_4)_2$ was prepared by milling $ZnCl_2$ and $NaBH_4$ in a planetary ball mill in an Ar atmosphere, and XRD analysis, SEM observation, FT-IR analysis, DTA, and TGA were performed for synthesized $Zn(BH_4)_2$ samples. 90 wt% $MgH_2$+1.67 wt% $Zn(BH_4)_2(+NaCl)$+5 wt% Ni+1.67 wt% Ti+1.67 wt% Fe (named $90MgH_2+1.67Zn(BH_4)_2(+NaCl)$+5Ni+1.67Ti+1.67Fe) samples were also prepared by milling in a planetary ball mill in an $H_2$ atmosphere. The gas absorption and release properties of the $Zn(BH_4)_2(+NaCl)$ and $90MgH_2+1.67Zn(BH_4)_2(+NaCl)_2(+NaCl)$+5Ni+1.67Ti+1.67Fe samples were investigated. An FT-IR analysis showed that $Zn(BH_4)_2$ formed in the $Zn(BH_4)_2(+NaCl)$ samples prepared by milling $ZnCl_2$ and $NaBH_4$. At the first cycle at $320^{\circ}C$, $90MgH_2+1.67Zn(BH_4)_2(+NaCl)$+5Ni+1.67Ti+1.67Fe absorbed 2.95 wt% H for 2.5 min and 4.93 wt% H for 60 min under 12 bar $H_2$, and released 1.46 wt% H for 10 min and 4.57 wt% H for 60 min under 1.0 bar $H_2$.