• Title/Summary/Keyword: Mg 입자

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Textural and Geochemical Characteristics and their Relation of Spinel Peridotite Xenoliths from Jeju Island (제주도 첨정석 페리도타이트 포획암의 조직 및 지화학적 특성과 그 관련성)

  • Yu, Jae-Eun;Yang, Kyoung-Hee;Kim, Jin-Seop
    • The Journal of the Petrological Society of Korea
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    • v.19 no.3
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    • pp.227-244
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    • 2010
  • Abundant spinel lherzolite xenoliths showing distinctively different textural types such as protogranular, porphyroclastic, and mylonitic texture are trapped in the basaltic rocks from southeastern part of Jeju Island. These xenoliths show the textural spectrum from coarse-grained protogranular through porphyroclastic with bimodal grain size to fine-grained and foliated mylonitic texture. They tend to decrease in grain sizes and show more linear grain boundaries and more frequent triple junctions from protogranular through porphyroclastic to mylonitic. Spinel has different occurrence mode according the textural type. Spinel is always associated with orthopyroxene in protogranular texture, whereas it is scattered and independent of orthopyroxene in mylonitic texture. Additionally, porphyroblast from porphyroclastic and mylonitic textures has internal deformation features such as kink band, undulatory extinction and curved lamella, whereas neoblast is strain-free. These textural features indicate increasing degree of static/dynamic recrystallization from protogranular through porphyroclastic to mylonitic texture. The mg#[$=100{\times}Mg/(Mg+Fe_t)$] of olivine, orthopyroxene and clinopyroxene is relatively constant (ol: 88-91; opx: 89-92; cpx: 89-92) regardless of textural differences. The mg# of constituent minerals, NiO content (0.3~0.4 wt%) and MnO content (0.1~0.2 wt%) of olivine are similar to those of mantle xenoliths worldwide, also indicating that studied spinel lherzolite xenoliths were mantle residues having experienced 20~25% partial melting. The geochemical and textural characteristics have close relations showing that LREE and incompatible trace elements content of orthopyroxene and clinopyroxene increases from protogranular through porphyroclastic to mylonitic. These observations suggest that the studied mantle xenoliths experienced metasomatism by LREE enriched melt or fluid after partial melting, indicating a close relation between deformation and metasomatism. The metasomatism was possibly confined to narrow shear zones from where porphyroclastic and mylonitic textured xenoliths originated. These shear zones might favorably drive the percolation of LREE-enriched melts/fluids responsible for the metasomatism in the lithospheric mantle below the Jeju Island.

Preparation of Fabric Softener Product by using Amine-functionalized Magnesium-phyllosilicates (아민기로 관능화된 마그네슘-층상규산염을 이용한 섬유유연제 제조)

  • Kim, Seong Yeol;Choi, Yoo-Sung
    • Applied Chemistry for Engineering
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    • v.30 no.5
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    • pp.580-585
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    • 2019
  • In this study, we synthesized amine-functionalized magnesium-phyllosilicates (AF-MgP) with an octahedral and tetrahedral structure using (3-aminopropyl)triethoxysilane. The synthesis of AF-MgP, surface functionalization of amine and 1 : 2 ratio of the octahedral and tetrahedral structure were confirmed by FT-IR and XRD analysis. In addition, it was confirmed that AF-MgP was absorbed evenly on the surface of cotton fibers and coated on the cotton fibers from HR-SEM and EDX analysis. The antimicrobial activity test of cotton fibers according to KS confirmed that cotton fibers coated with AF-MgP particles show an enhanced antimicrobial activity against cutaneous microorganisms. Our results suggest that AF-MgP is not only applied as a functional nanomaterial that gives the cotton fiber antimicrobiality, but also can be used in the field of cosmetic and biomedical materials.

Composition comparison of PM10 and PM2.5 fine particulate matter for Asian dust and haze events of 2010-2011 at Gosan site in Jeju Island (황사와 연무 시 PM10 및 PM2.5 미세먼지 조성 비교: 2010-2011년 고산지역 측정)

  • Kim, Ki-Ju;Lee, Seung-Hoon;Hyeon, Dong-Rim;Ko, Hee-Jung;Kim, Won-Hyung;Kang, Chang-Hee
    • Analytical Science and Technology
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    • v.27 no.1
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    • pp.1-10
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    • 2014
  • The $PM_{10}$ and $PM_{2.5}$ samples were collected at Gosan Site of Jeju Island, and analyzed, in order to investigate the size distribution and pollution characteristics of their components. $NH{_4}{^+}$, nss-$SO{_4}^{2-}$, $K^+$, and $CH_3COO^-$ were mostly existed in fine particles. Meanwhile, $NO{_3}{^-}$ was distributed in both fine and coarse particles, and $Na^+$, $Cl^-$, $Mg^{2+}$, nss-$Ca^{2+}$ were rich in coarse particle mode. The concentrations of nss-$Ca^{2+}$ and $NO{_3}{^-}$ were increased 36.7 and 3.2 times in coarse particles, and 15.0 and 3.1 times in fine particles during the Asian Dust periods. Especially, the concentrations of crustal elemental species such as Al, Fe, Ca, K, Mg, Ti, Mn, Sr, Ba were highly increased for those periods. In the haze events, the concentrations of secondary air pollutants were increased 1.3~2.6 and 1.5~4.2 times in coarse and fine particles, respectively. Moreover, the remarkable increase of $NO{_3}{^-}$ concentration was also observed in fine particle mode. The factor analysis showed that the composition of coarse particles was influenced mainly by marine sources, followed by soil and anthropogenic sources. On the other hand, the fine particles were influenced by anthropogenic sources, followed by marine and soil sources.

Analysis of Physicochemical Properties of Red Ginseng Powder Based on Particle Size (홍삼분말 입자크기에 따른 이화학적 특성 분석)

  • Choi, Hee Jeong;Lee, Sang Yoon;Lee, Jung Gyu;Park, Dong Hyeon;Bai, Jing Jing;Lee, Byung-Joo;Kim, Yoon-Sun;Cho, Youngjae;Choi, Mi-Jung
    • Food Engineering Progress
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    • v.21 no.3
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    • pp.225-232
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    • 2017
  • Most of the red ginseng (RG) products contain active substances derived from hot water or alcohol extraction. Since active substances of RG are divided into two types - water-soluble and liposoluble - water or alcohol is needed as an extraction solvent and this leads the different extraction yields and components of the active substances. To overcome the limit, whole red ginseng powder can be used and consumed by consumers. In this study, the physicochemical properties and extractable active substance contents of variable-sized RG powder ($158.00{\mu}m$, $8.45{\mu}m$, and $6.33{\mu}m$) were analyzed, and dispersion stability was measured to investigate the suitable size of RG powder for industrial processing. In the results, no significant difference was found from the changes in color intensity and thiobarbutric acid tests at $4^{\circ}C$, $25^{\circ}C$, and $40^{\circ}C$ for 4 weeks. There was no significant difference on the production of antioxidants and ginsenoside among the samples (p>0.05). In dispersion stability, $RG-158.00{\mu}m$ was precipitated immediately, and the dispersion stabilities between $RG-8.45{\mu}m$ and $RG-6.33{\mu}m$ showed no significant difference. It implies that fine RG is suitable for the production process. With further study, it seemed that the physicochemical effects of RG particle sizes can be clearly revealed.

Protective effects of red ginseng treated with gold nanoparticles against H2O2-induced oxidative stress in neuronal PC-12 cells (금 나노입자를 처리한 홍삼의 산화스트레스 완화 및 PC-12 신경세포 보호)

  • Kim, Ji Won;Cho, Chi Heung;Hwang, Yun-Gu;Park, Woo Jung;Kang, Hee;Kim, Dae-Ok
    • Korean Journal of Food Science and Technology
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    • v.49 no.2
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    • pp.222-227
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    • 2017
  • Red ginseng prepared from fresh 6-year-old ginseng treated with colloidal gold nanoparticles was extracted using hot water to evaluate its total phenolic and flavonoid contents, antioxidant capacity, and neuroprotective effects. Water extract of red ginseng treated with gold nanoparticles (WERGGN) had total phenolic and total flavonoid contents of 212.2 mg gallic acid equivalents/$^{\circ}Bx$ and 3.5 mg catechin equivalents/$^{\circ}Bx$, respectively. The antioxidant capacities of WERGGN measured using ABTS, DPPH, and ORAC assays were 272.3, 141.2, and 868.4 mg vitamin C equivalents/$^{\circ}Bx$, respectively. The WERGGN showed protective effects on the viability of neuron-like PC-12 cells against oxidative stress induced by hydrogen peroxide in a dose-dependent manner, partly because of a reduction in intracellular oxidative stress. Acetylcholinesterase and butyrylcholinesterase, which degrade the neurotransmitter acetylcholine to terminate neurotransmission, were inhibited by treatment with WERGGN. These results suggest that WERGGN is useful as a functional material to decrease oxidative stress and neuronal damage.

Soil Physical and Chemical Characteristics of River-Bed Sediments in River Basins (하천 퇴적토양의 이화학적 특성)

  • Zhang, Yong-Seon;Sonn, Yeon-Gye;Park, Chan-Won;Hyun, Byung-Keun;Moon, Yong-Hee;Song, Kwan-Cheol
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.963-969
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    • 2011
  • The river-bed sediments from the major river basins were analysed for the chemical and physical properties to evaluate environmental safety for the agricultural uses. The samples were taken from 16 sites of Han river, 36 of Geumgang river, 27 of Yeongsan river, and 140 of Nakdong river. The total of 219 samples from the 28 counties were taken from the surface of the sediments at the depth of 50 cm. The particle density of the sediments was greater than $2.63Mg\;m^{-3}$ and the whole range of the density was $2.60{\sim}2.69Mg\;m^{-3}$, the average particle size was 0.7 mm whereas the size range was 0.075~0.85 mm. The analyses of the particle sizes by basins showed that Han and Geumgang river had particle sizes of 0.075~0.85 mm, while Geumgang and Yeongsan river had particle sizes of 0.25~0.85 mm. Geumgang and Yeongsan river tended to have greater particle sizes. The average values of the chemical properties were 6.3 for pH, $0.16dS\;m^{-1}$ for EC, $8g\;kg^{-1}$ for organic matter, $101mg\;kg^{-1}$ for available phosphate, 0.39, 3.47, and $0.93cmol_c\;kg^{-1}$ for exchangeable potassium, calcium, and magnesium respectively. The greatest property at each basin was pH for Han river, Ec, available phosphate and exchangeable sodium for Geumgang river, organic matter, exchangeable calcium and magnesium for Yeongsan river, and exchangeable potassium for Nakdong river.

Changes of Compost Quality by the Formation of Struvite Crystal During the Composting of Swine Manure (돈분뇨 부숙과정에서 Struvite 결정체 형성에 따른 퇴비특성 변화)

  • Lee, Jin-Eui;Ra, Chang-Six
    • Journal of Animal Science and Technology
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    • v.51 no.3
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    • pp.249-254
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    • 2009
  • The effect of Mg supplement on the composting of swine manure and the formation of $MgNH_4PO_46H_2O$ (MAP) crystal during composting were examined. Mg source was added at a rate of 1.2 molar ratios to soluble phosphate ($PO_4$) level in swine manure. The temperature profiles and final compost qualities revealed that the Mg source addition didn't retard the decomposition of organic matters. As the added Mg reacted with $NH_4$ and $PO_4$ in manure, creating MAP crystal, the $NH_4$ level was reduced, and this was resulted in low nitrogen lose during the composting. The phosphate level was also decreased with the addition of Mg source, and hence the ratio of orthophosphate to total phosphate (OP/TP) in the final compost was lowered. Therefore, it was assured that supplement of Mg source into the composting materials could enhance the quality of compost by preserving nourishment and converting it into a slowly releasing fertilizer. X-Ray diffraction examination of the final compost showed that a distinct MAP crystal was formed during the composting, and the crystal mainly existed with the compost particle size less than 2.8 mm and over 2/3 of nourishment of the final compost was found in those particles.

A Research on Superparamagnetic Iron Oxide Nanoparticles' Toxicity to U373MG Cell and its Effect on the Radiation Survival Curve (산화철 나노입자의 U373MG 세포 독성평가 및 방사선 세포생존 곡선에 미치는 영향에 대한 연구)

  • Kang, Seonghee;Kim, Jeonghwan;Kim, Dokyung;Kang, Bosun
    • Journal of the Korean Society of Radiology
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    • v.6 no.6
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    • pp.507-513
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    • 2012
  • This research was performed to evaluate the superparamagnetic iron oxide nanoparticles'(SPIONs) cell toxicity and to measure the radiation cell survival curve changes of SPIONs-uptake glioblastoma multiforme cells. The results could be practically used as the fundamental data to ameliorate proton beam cancer therapy, for example, providing necessary GBM treatment dose in the proton beam therapy when the therapy takes advantage of SPIONs. The assessment of the toxicological evaluation of synthesized SPIONs was accomplished by MTT assay as an in vitro experiment. The results showed no meaningful differences in the cell survival rate at the $1-100{\mu}g/ml$ SPIONs concentrations, but the cell toxicity was shown as the cell survival rate decreased up to 74.2% at the $200{\mu}g/ml$ SPIONs concentration. Then, we measured each radiation cell survival curve for U373MG cells and SPIONs-uptake U373MG cells with 0~5 Gy of proton beam irradiations. It is learned from the analysis of the experimental results that the SPION-uptake cells' radiation survival rate was more rapidly decreased as the irradiation dose increased. In conclusion we confirmed that SPIONs-uptake in U373MG cells induces cell death at the much less dose than the lethal dose of SPION-non-uptake cell. This research shows that the therapeutic efficacy of glioblastoma multiforme treatment in proton beam therapy can be improved by SPIONs targeting to the GBM cells.

Development of Standard Analysis Methods for Physical Properties on Korean bedsoil 1. Particle density and Bulk density (우리나라 상토의 물리적 표준분석법 설정 연구 1. 입자밀도 및 용적밀도)

  • Kim, Lee-Yul;Cho, Hee-Kee
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.6
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    • pp.327-334
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    • 2002
  • Method of besoil analysis were difficult to be applied universally since the use and the source material of bedsoils are diverse from country to country. Korean Standard Methods for Bedsoil Analysis was developed to measure the particle and bulk density. Fifty-three samples for horticultural bedsoil and nine samples for paddy rice bedsoil in the current market were collected. Particle density was measured by electrical pyconometer with He gas, and bulk density by the sandbox method, free fall method, plunger compaction method, free fall and plunger method, and sample weight compaction method. While the use of glass pycnometer which measures particle density to fill blank space with water was inappropriate due to floating organic and calcined inorganic materials in the water, the electrical pycnometer with gas type was suitable considering speed and accuracy. For bulk density, the sandbox method recommended as European Standard Method was more reasonable in principle than other methods. However, this method requires expensive apparatus and intricate process. Plunger compaction method was proposed as standard method, since it had higher consistence with the sandbox method than other methods, as well as an advantage of easy and prompt measurement. Particle density of bedsoil ranged $1.48{\sim}2.67Mg\;m^{-3}$(mean $1.93Mg\;m^{-3}$) for horticultural bedsoil and $2.33{\sim}2.67Mg\;m^{-3}$ (mean $2.43Mg\;m^{-3}$) for paddy rice bedsoil by the electrical pycnometer with He gas. Bulk density of bedsoil ranged $0.11{\sim}0.40Mg\;m^{-3}$ (mean $0.22Mg\;m^{-3}$) for horticultural bedsoil and $0.84{\sim}1.26Mg\;m^{-3}$(mean $1.01Mg\;m^{-3}$) for paddy rice bedsoil by plunger compaction method.