• Title/Summary/Keyword: Mg 입자

Search Result 715, Processing Time 0.029 seconds

Sputtering yield of the MgO thin film grown on the Cu substrate by using the focused ion beam (집속이온빔을 이용한 구리 기판위에 성장한 MgO 박막의 스퍼터링 수율)

  • 현정우;오현주;추동철;최은하;김태환;조광섭;강승언
    • Journal of the Korean Vacuum Society
    • /
    • v.10 no.4
    • /
    • pp.396-402
    • /
    • 2001
  • MgO thin films with 1000 $\AA$ thickness were deposited on Cu substrates by using an electron gun evaporator at room temperature. A 1000 $\AA$ thick Al layer was deposited on the MgO for removing the charging effect of the MgO thin film during the measurements of the sputtering yields. A Ga ion liquid metal was used as the focused ion beam(FIB) source. The ion beam was focused by using double einzel lenses, and a deflector was employed to scan the ion beams into the MgO layer. Both currents of the secondary particle and the probe ion beam were measured, and they dramatically changed with varying the applied acceleration voltage of the source. The sputtering yield of the MgO layer was determined using the values of the analyzed probe current, the secondary particle current, and the net current. When the acceleration voltage of the FIB system was 15 kV, the sputtering yield of the MgO thin film was 0.30. The sputtering yield of the MgO thin film linearly increases with the acceleration voltage. These results indicate that the FIB system is promising for the measurements of the sputtering yield of the MgO thin film.

  • PDF

Soil Washing Coupled with the Magnetic Separation to Remediate the Soil Contaminated with Metal Wastes and TPH (자력선별과 토양세척법을 연계하여 금속폐기물과 TPH로 복합 오염된 토양 동시 정화)

  • Han, Yikyeong;Lee, Minhee;Wang, Sookyun;Choi, Wonwoo
    • Economic and Environmental Geology
    • /
    • v.52 no.1
    • /
    • pp.1-12
    • /
    • 2019
  • Batch experiments for the soil washing coupled with the magnetic separation process were performed to remediate the soil contaminated with metal and oil wastes. The soil was seriously contaminated by Zn and TPH (total petroleum hydrocarbon), of which concentrations were 1743.3 mg/kg and 3558.9 mg/kg, respectively, and initial concentrations of Zn, Pb, Cu, and TPH were higher than the 2nd SPWL (soil pollution warning limit: remediation goal). The soil washing with acidic solution was performed to remove heavy metals from the soil, but Pb and Zn concentration of the soil maintained higher than the 2nd SWPL even after the soil washing with acidic solution. The 2nd soil washing was repeated to increase the Pb and Zn removal efficiency and the Zn and Pb removal efficiencies additionally increased by only 8 % and 5 %, respectively, by the 2nd soil washing (> 2nd SPWL). The small particle separation from the soil was conducted to decrease the initial concentration of heavy metals and to increase the washing effectiveness before the soil washing and 4.1 % of the soil were separated as small particles (< 0.075 mm in diameter). The small particle separation lowered down Zn and Pb concentrations of soil to 1256.3 mg/kg (27.9 % decrease) and 325.8 mg/kg (56.3 % decrease). However, the Zn concentration of soil without small particles still was higher than the 2nd SPWL even after the soil washing, suggesting that the additional process is necessary to lower Zn concentration to below the 2nd SPWL after the treatment process. As an alternative process, the magnetic separation process was performed for the soil and 16.4 % of soil mass were removed, because the soil contamination was originated from unreasonable dumping of metal wastes. The Zn and Pb concentrations of soil were lowered down to 637.2 mg/kg (63.4 % decrease) and 139.6 mg/kg (81.5 % decrease) by the magnetic separation, which were much higher than the removal efficiency of the soil washing and the particle separation. The 1st soil washing after the magnetic separation lowered concentration of both TPH and heavy metals to below 2nd SPWL, suggesting that the soil washing conjugated with the magnetic separation can be applied for the heavy metal and TPH contaminated soil including high content of metal wastes.

Fabrication of $Al_2O_{3p}/Al$ composites by in-situ Reaction Process of Molten Al (In-situ 반응에 의한 $Al_2O_{3p}/Al$기 복합재료의 제조)

  • 김재동;정해용;고성위
    • Composites Research
    • /
    • v.12 no.3
    • /
    • pp.36-44
    • /
    • 1999
  • The fabrication process of $Al_2O_{3p}/Al$ composite by in-situ process was investigated. The effects of processing variables such as addition type and content of Mg, processing temperature and time on the infiltration behavior of molten Al, microstructure and hardness were investigated. When the pure Al was infiltrated into mixtures of Mg and $Al_2O_3l$ powder, processing temperature required to spontaneous infiltration was decreased, and the content of Mg was the most powerful variable for infiltration of molten Al. But when the Al-Mg alloy was infiltrated into $Al_2O_3l$ particles, infiltration ratio indicated nearly same value regardless of Mg content in alloy and processing temperature, and critical processing temperature required to spontaneous infiltration was $800^{\circ}C$. The $Al_2O_{3p}/Al$ composites which were fabricated by mixtures of Mg and $Al_2O_3l$ powders resulted in high hardness value, but hardness values were scattered due to non uniform dispersion of $Al_2O_3l$ particles by excessive reaction of Mg.

  • PDF

Physicochemical Properties of Black Rice Flours (BRFs) Affected by Milling Conditions (제분조건에 따른 흑미쌀가루 품질특성)

  • Choi, Bong-Kyu;Kum, Jun-Seok;Lee, Hyun-Yu;Park, Jong-Dae
    • Korean Journal of Food Science and Technology
    • /
    • v.38 no.6
    • /
    • pp.751-755
    • /
    • 2006
  • Physicochemical properties of black rice flours (BRFs) produced under different milling conditions were investigated to explore their applications for various processed rice products. Moisture contents of BRFs after roll milling and subsequent hot-air drying or microwave drying were 10.3% and 14.4%, respectively. The BRFs with jet milling and subsequent hot-air drying or microwave drying showed moisture contents of 7.9% and 7.5%. Mean particle sizes of the BRFs obtained from roll milling, jet milling, and following air-classification were 150, 41.5, and 9.4 ${\mu}m$, respectively. Hunter L value and water soluble index (WSI) of BRFs increased with decreasing particle size, while Hunter a value decreased. Total polyphenol contents of 91.4-115.8 mg/100 g and total amino acids of 75.0-96.4 mg/100 g in three types of BRFs were higher as compared to those (6.3 mg/100 g and 30.5 mg/100 g) of polished rice flour (PRF). Physicochemical properties such as moisture content, color parameter, and WSI have close relationship with the particle size of BRFs prepared under different milling conditions.

Evaluation of Dust Removal Efficiency on Roadway Structures Using Ultrafine Bubble Water Jet (초미세기포 water jet을 이용한 도로 시설물 분진 제거 효율 평가)

  • Kim, Hyun-Jin;Park, Il-gun
    • Clean Technology
    • /
    • v.27 no.1
    • /
    • pp.39-46
    • /
    • 2021
  • A road structure washing vehicle equipped with a 4 HP, 80 LPM ultrafine bubble generator was used to clean a tunnel wall and the surface of the surrounding structure, consisting of concrete and tiles, in a heavy traffic area around an apartment complex in the city. Ultrafine bubbles were generated by supplying air at 2 to 3 LPM and using a specially designed nozzle, whereas fine bubbles made by an impeller in a gas-liquid mixing self-priming pump were produced with an average diameter of 165.4 nm and 6.81 × 107 particles mL-1. Using a high pressure washer gun that can perform high-pressure cleaning at 150 bar and 30 LPM, ultrafine bubbles were used to wash dust adsorbed on the surface of the road structures. The experimental analysis was divided into before and after washing. The samples were analyzed by applying ISO 8502-3 to measure surface contamination of dust adsorbed on the surface. Using the transparent tape attached to the surface, the removal rate was calculated by measuring the weight of the dust, and the number of particles was calculated using the gravimetric method and the software, ImageJ. The results of the experiment showed that the number of dust particles adsorbed on the tile wall surface before and after washing were 3,063 ± 218 particles mL-1 and 20 ± 5 particles mL-1, respectively, with weights of 580 ± 82 mg and 13 ± 4 mg. Particles on the surface of the concrete structure before and after washing were 8,105 ± 1,738 particles mL-1 and 39 ± 6 particles mL-1, respectively, with weights of 1,448 ± 190 mg and 118 ± 32 mg.

Synthesis and Surface Modification of Magnesium Hydroxide by Hydrothermal Method (수열법에 의한 수산화 마그네슘의 합성과 표면개질)

  • Lee, Hae-Young;Kang, Kuk-Hyoun;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
    • /
    • v.29 no.1
    • /
    • pp.149-158
    • /
    • 2012
  • Magnesium hydroxide[$Mg(OH)_2$] was prepared by hydrothermal method using oleic acid as surface modifier. $Mg(OH)_2$ particles exhibit flake morphology with micrometer in size and the surface modification starts from the reaction of $C_{17}H_{33}COO^-$ group, derived from oleic acid molecule in alkaline environments. It is found that hydrothermal treatment conditions such as pH, temperature and reaction time are important for the control of the morphology and properties of surface modified magnesium hydroxide. The obtained magnesium hydroxide groups were characterized by FE-SEM, XRD, FT-IR, TGA. The dispersion in organic solution was determined by sedimentation test and compared with the result of raw $Mg(OH)_2$.

Mg-Al합금의 석출상 예측을 위한 수치해석

  • Lee, Byeong-Deok;Baek, Ui-Hyeon;Jang, Gyeong-Su;Han, Jeong-Hwan
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2010.05a
    • /
    • pp.46.1-46.1
    • /
    • 2010
  • 일반적으로 석출물의 석출은 핵생성(Nucleation)-성장(Growth)-조대화(Coarsening)의 단계를 거친다. 핵생성에 의해 생성된 개개의 핵들은 아직 열역학적으로 평형 상태가 아니다. 석출물의 부피 분율은 아직 상태도에서 예측할 수 있는 값까지 도달하지 못했다. 과포화된 기지에서 생성된 핵은 계속적으로 기지로부터 용질 원자를 공급받아 성장하게 된다. 석출물의 성장은 그 부피 분율이 상태도에서 예상되는 값에 도달할 때까지 계속된다. 시간에 따른 석출 분율 계산과 분산된 석출물들이 matrix내에서 어느 정도 용해도를 갖는다면, 보다 작은 크기의 입자들은 용해되어 보다 큰 입자로 석출(성장)하려는 경향이 있다. 이러한 현상의 구동력은 전체 시스템의 계면 에너지 감소에 의해 주어지며, 결국 하나의 큰 입자만이 존재하게 될 것이다. 본 연구에서는 석출분율을 계산하기 위해 상용프로그램인 Pandat을 통해 Mg-Al 2원계합금의 상태도 및 석출분율 계산을 위한 열역학 데이터를 계산하였다. 계산된 열역학 데이터는 C언어로 함수화 하여 입력하고 Excell을 통해 석출분율을 계산하였다. 계산된 석출분율과 실험값의 비교를 통해 fitting parameters를 대입하여 계산값 및 실험값의 오차율을 줄였다. 본 연구에서 계산된 석출분율은 미래의 석출상 크기 및 분포 등을 개발하는 기초데이터로 활용할 수 있을 것이다.

  • PDF

A Study on the Fabrication of Al/TiCp Composites by Liquid Mixing method(I) (액상교반법에 의한 AI/TiCp 복합재료의 제조에 관한 연구(I))

  • Im, Jong-Guk;Kim, Myeong-Han;Choe, Jae-Ha
    • Korean Journal of Materials Research
    • /
    • v.3 no.5
    • /
    • pp.529-537
    • /
    • 1993
  • The mecllanical properties of AI/TiCp composite fabrication by liquid mixing was investigat ed. The composites, containing 10 wt% Tic. were producwi using induction furnace with mechanical stirring. The amounts of' 1.5wt% Mg were, added to wetting agents. Thr presence of aluminum in TiC composites showed rnhanced strengrh without loss of ductility at room and clrvated temperatures. Espe cially, wear resistance was found to dramatically irnprovc. I3ul excess stirring d~terrninrd the mect~ani~ cal properties. Approximate values at present work were 500 rpm. There was no inrerfacial reaction of any kind and the interface remains clearly deineated.

  • PDF

Effects of P2O5-doped on the Surface of MgO Particles for Hydrolysis, Water Repellency, and Insulation Behavior (MgO입자 표면에 도핑된 P2O5가 가수분해, 발수성, 그리고 절연거동에 미치는 영향)

  • Choi, Jin Sam
    • Applied Chemistry for Engineering
    • /
    • v.33 no.6
    • /
    • pp.588-593
    • /
    • 2022
  • The effects of P2O5-doped on the surface of MgO particles on hydrolysis, water repellency, and insulation behavior were investigated. P2O5-doped MgO has exhibited a unique electrical property, which is significant insulation behavior due to both the suppression of the hydrolysis reaction by P2O5 and water repellency. Therefore, the insulation behavior was inversely proportional to the hydrophilicity and the Mg(OH)2 and OH-charge transfer ratio by the surface hydration reaction of MgO. The insulation of MgO according to aging was strongly influenced by the surface hydration reaction, the band gap of the added dopant species, and the hydrophilicity and hydrophobicity of the dopant. Finally, it was to show electrical insulation by inhibiting the surface hydration reaction of the hydrophilic MgO, which has a great potential for use in heat transfer medium applications.

Evaluation of Dose Enhancement by Gold Nanoparticles using Mathematical Head Phantom (금 나노입자를 활용한 두부 모의피폭체에서의 선량증가 효과 평가)

  • Hwang, Chulhwan;Park, Eun-Tae;Kim, Jung-Hoon
    • The Journal of the Korea Contents Association
    • /
    • v.16 no.8
    • /
    • pp.477-483
    • /
    • 2016
  • The effect of dose enhancement was evaluated using Snyder head phantom, dependence on size of gold nanoparticle and material concentration in megavoltage X, ${\gamma}$-ray. Monte Carlo simulation using MCNPX was used for 4, 6, 10, 15 MV and Co-60 ${\gamma}$-ray. Described the tumor in Snyder head phantom, gold nanoparticle of 25, 75, 125nm diameter was inserted inside tumor. Concentration of dose enhancement material was used for 5, 15, 25 mg/g and dose enhancement factor was calculated on the basis of the no dose enhancement material. The lower incident energy and the higher concentration of material were that high dose enhancement factor is indicated. The size of gold nanoparticle had relatively high dependence on lower incident energy and higher concentration of material. It will increase dose inside the tumor, and be additional effect of use of gold nanoparticles in radiation therapy.