• 제목/요약/키워드: Methyl alcohol

검색결과 366건 처리시간 0.031초

휴면기(休眠期) 딸기의 내생(內生) Cytokinin-like Substances의 활성(活性)에 관(關)한 연구(硏究) (The Activities of Cytokinin-like Substances In Dormant Strawberry Plants)

  • 이영복
    • 농업과학연구
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    • 제4권2호
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    • pp.121-125
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    • 1977
  • 딸기의 휴면기(休眠期)에 있어서의 내생(內生) Cytokinin-like 물질(物質)의 활성(活性)은 휴면(休眠)의 정도(程度)에 따라 변화(變化)를 보였고, 이 활성(活性)의 변화(變化)는 생육상(生育相)의 변화와 비슷한 결과(結果)를 나타냈다. 딸기의 Crown 부분(部分) 20g을 Methyl alcohol로 추출하여 Column chromatography로 분류, Soybean callus bioassay 한 결과 두 부분(部分)에서 활성(活性)을 보였고, 이 중 Ethyl acetate/methyl alcohol; 50/50 및 90/10에서 강한 활성(活性)을 보였다. 생육상과의 관계는 생육(生育)이 비교적 왕성한 시기에 강한 활성(活性)이 나타났으며, 휴면(休眠)이 깊은 시기에 활성(活性)이 낮았다. 그러나 일정(一定)한 저온기간(低溫期間)의 경과와 함께 다시 활성화(活性化)되었으며, 이 결과로 휴면(休眠)의 깊이의 정도(程度)와 내생(內生) Cytokinin의 양적증대(量的增大)와는 역비례적인 상관성을 보여주고 있다.

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한국산(韓國産) 식용(食用)버섯의 향기성분(香氣成分)에 관(關)한 연구(硏究) (I) -송이 버섯의 향기성분(香氣成分)- (Studies on the volatile aroma components of Edible mushroom (Tricholoma matsutake) of Korea)

  • 안장수;이규한
    • 한국식품영양과학회지
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    • 제15권3호
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    • pp.253-257
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    • 1986
  • 한국산 송이버섯의 생 것과 조리 중의 향기성분을 GC, GC-MS를 이용하여 분석한 결과는 다음과 같다. 1) 생 송이버섯의 향기성분 13종을 명확 동정하였다. 이들 중 1-octen-3-ol이 73.95% Methyl Cinnamate가 12.52% , 2-octanol 7.62% 및 octyl alcohol 2.78%로 전체의 향기성분 중에서 96.78%를 차지하였다. 2) 조리 중 송이버섯에서 향기성분 9종을 명확 동정하였으며 이들 중 1-octen-3-ol이 64.94%, Methyl cinnamate가 22.03%, 2-octenol 7.68% 및 Octyl alcohol이 22.03%로 전체의 향기성분 중에서 97.96%로 조성되었다. 3) 생 송이버섯과 조리 중의 송이버섯의 향기 성분은 대부분이 Alcohol류와 Carbonyl화합물이며 탄소수가 8개인 저급 화합물이었다.

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항암작용 가능성이 있는 10-Membered Enediyne의 선구물질인 14-Membered Phenylthio Enediyne Lactone의 합성 (Synthesis of 14-Membered Phenylthio Enediyne Lactone : A Precursor of the Potential Enediyne Antitumor Antibiotics)

  • 김기동
    • 대한화학회지
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    • 제39권2호
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    • pp.103-110
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    • 1995
  • 본 연구에서는 항암제로서의 가능성이 있는 10-membered enediyne(6)의 선구물질로 사용될 수 있는 14-membered phenylthio enediyne lactone을 성공적으로 합성할 수 있었다. 14-membered lactone은 Ireland-Clasisen rearrangement에 의해 10-membered enediyne(11)으로 변환되며 이물질(11)은 최종물질(8)로 전환될 수 있을 것으로 예상된다. 이 14-membered enediyned lactone(23)은 DCC/PTSA/Pyridine 하에 enediyne hydroxyl acid(22)의 락톤화 반응에 의해 합성되었다. Enediyne hydroxyl acid는 Pd(0) 촉매하에 methyl pentynoate(19)와 enyne alcohol(17)을 cis-1,2-dichloroethylene과 연속적으로 coupling 반응을 하여 좋은 수득율로 얻을 수 있었다. 그 때 필요한 enyne alcohol(17)은 vinyltin(12)을 출발물질로 하여 성공적으로 얻을 수 있었다.

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목이 및 석이 메탄올 추출물의 유전독성 억제효과 (Antigenotoxic Effects of Methyl Alcohol Extracts from Auricularia mesenterica and Gyrophora esculenta)

  • 함승시;김득하;최근표;이득식
    • 한국식품영양과학회지
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    • 제27권1호
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    • pp.57-62
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    • 1998
  • This study was designed to demonstrate the antigenotoxic potential of methyl alcohol extracts from Auricularia mesenterica and Gyrophora esculenta against the frequency of micronucleate polychromatic erythrocyte(MNPCE) produced by benzo($\alpha$) pyrene in vivo. We used the mouse bone marrow test system to measure the effect of single and multiple treatments of each sample. Genotoxicity of benzo ($\alpha$) pyrene(150mg/kg, i.p.) as positive control was the highest at 36 hours. However, each sample per dose was not genotoxic, showing MNPCE values in the range of the control level. Treatments of methyl alcohol extracts both of Auricularia mesenterica and Gyrophora esculenta showed significant decreased frequencies of NMPCE induced by benzo($\alpha$) pyrene within 12 hours by single treatment(100mg/kg, oral). And also, the MNPCE level produced benzo($\alpha$) pyrene was decreased by the treatment of benzo($\alpha$) pyrene(5 to 200mg/kg, oral) of each sample, but significantly different redults were obtained with 100mg/kg. In the multiple treatment, the highest antigentoxic effects were demonstrated with 20mg/kg in the each sample, a range which induced inhibition indices of 54.2 and 56.3%, respectively.

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Transesterification for FAME production of Rapeseed Oil

  • 정귀택;윤대현;강춘형;최병철;이운택;박돈희
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2003년도 생물공학의 동향(XII)
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    • pp.164-168
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    • 2003
  • 유채유를 사용하여 바이오디젤 생산을 위한 1단 전이에스테르화 공정에 있어서 반응온도 $60^{\circ}C$, 유지에 대한 메탄올 몰비 1:10 이상, 1.0 % (w/w) 포타슘 하이드록시드의 조건에서 98.5% 이상의 전화율을 얻을 수 있었다.

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감식초 제조를 위한 감펄프의 알콜발효시 펙틴분해효소 처리의 효과 (Effect of Pectin Degradation Enzyme during Alcohol Fermentation of Persimmon Pulp for Persimmon Vinegar Preparation)

  • 정석태;김지강
    • 한국식품저장유통학회지
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    • 제3권2호
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    • pp.179-185
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    • 1996
  • This study was carried out for the purpose of improving the persimmon vinegar. Crushed persimmon(persimmon pulp) was used at alcohol fermentation using Saccharomyces bayanus for persimmon alcohol medium preparation. Glucose(8.39%) and fructose(7.96%) were the dominant free sugar in persimmon pulp before the at cohol fermentation. They decreased abruptly during alcohol fermentation and glucose was consumed more rapidly than fructose. Final alcohol concentration was finally reached to 8%(v/v) in 5 days for mentation of persimmon pulp. Pectinase pre-treatment of persimmon pulp resulted in tusker contents of galacturonic acid, galactose, methyl alcohol and isoamyl alcohol in main mash for alcohol fermentation than those in main mash prepared without pectinase pre-treatment. After alcohol fermentation tannin concentration was 350ppm and astringency was not perceived.

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전통 이화주 양조 중의 주요성분(유기산, 알코올, Fusel Oil) 및 관능적 품질 특성 (Major Components(Organic acids, Alcohols, Fusel Oil) and Sensory Properties of Traditional Ewhaju during Brewing)

  • 김정옥;김종군
    • 한국식품조리과학회지
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    • 제10권1호
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    • pp.1-7
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    • 1994
  • Major quality parameters(organic acids, alcohols, fusel oil and sensory characteristics) of traditional Ewhaju were investigated during brewing. In organic acid contents at immediately after brewing, lactic acid was 155.1mg%, malonic acid was 5.4mg%, succinic acid was 8.9mg%, acetic acid was 7.6mg%, oxalic arid was 1.3mg%, citric and tartaric acid was 27.8mg% and pyruvic acid was 4.8mg% but in 100 days after brewing and one year aged, lactic acid was 1763.3 and 3059.3mg%, malonic acid was 12.3 and 19.3mg%, succinic acid was 11.5 and 23.1mg%, acetic acid was 29.2 and 73.1mg%, oxalic acid was 0.6 and 0.2mg%, citric and tartaric acid was 298.3 and 639.6mg%, and pyruvic acid were 1.1 and 0.3mg%, respectively. All the alcohol contents increased as the fermentation period increased ; the ethyl alcohol was only 0.05fe at immediately after brewing. In the alcohols content of Ewhaju at 100 days after brewing, the ethyl alcohol, methyl alcohol n-propyl alcohol and iso-butyl alcohol were 5.13ft, 47.56 ppm, 37.25 ppm and 19.51 ppm, respectively, Also in the one year aged Ewhaju, the ethyl alcohol was 9.39f), methyl alcohol was 36.34 ppm, Fusel oil was not detected in the first stage of brewing, but it was detected 1.12mg% at 100 days after brewing and 1.18mg% at one year stored sample. A general trend in change of color was almost white immediatly after brewing but a increase in Hunter "b" value and "a" value were observed depending on brewing time prolonged. Taste and overall palatability of Ewhaju after 100 days of brewing were significantly superior(p<0.05, p<0.01).

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