• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2012년도 춘계학술대회 논문집
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• pp.803-804
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• 2012

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2012년도 추계학술대회 논문집
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• pp.583-584
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• 2012

• 한국기계기술학회지
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• 제13권2호
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• pp.123-128
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• 2011

It has been stand high in estimation to converse from Carbon dioxide to Dimethyl Ether in new alternative fuel energy division in 21C, especially Using of DME in point of view of transportation fuel has been discussed of a new clean energy which is very lower of exhaust gas than gasoline and diesel energy. In this paper it is used ZSM-5 and I developed new catalyst by addition of cerium to control acidity. The new catalyst was proved high conversion rate, when it was conversed from methanol to DME, there wasn't any additional material except DME and water, and I overlooked reaction temperature, reaction time, amount of catalyst, amount of added cerium, effect of water content in methanol, reaction temperature by making change of reaction time. I have conclude that conversion rate to DME was increased as increased of catalyst amounts. The best catalyst condition of without additional product was treated poisoning from ZSM-5 to 5% cerium and new catalyst was not effected in purity of fuel methanol.

• Journal of Electrochemical Science and Technology
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• 제8권4호
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• pp.331-337
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• 2017

A simple strategy is proposed herein for attaining uniform current distribution in direct methanol fuel cells by varying the catalyst loading over the electrode. In order to use the same total catalyst amount for a serpentine flow field, three spatial variation types of catalyst loading were selected: enhancing the cathode catalyst loading (i) near the cathode outlet, (ii) near the cathode inlet, and (iii) near the lateral areas. These variations in catalyst loading are shown to improve the homogeneity of the current distribution, particularly at lower currents and lower air-flow rates. Among these three variations, increased loading near the lateral areas was shown to contribute most to achieving a homogenous current distribution. The mechanism underlying each catalyst loading variation method is different; very high catalyst-loading is shown to decrease the homogeneity of the distribution, which may be caused by water management in the thick catalyst layer thereof.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제53권4호
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• pp.218-224
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• 2004

We present a miniature Direct Methanol Fuel Cell (micro-DMFC) using platinum sputtered microcolumn electrodes with a limited amount of fuel. We use the microcolumn electrode in order to improve the power density of the micro-DMFC that consists of two electrodes and polymer electrolyte. We also design the built-in fuel chamber in the anode for the portable electronics applications. We design and fabricate both microcolumn and planar electrodes, having an identical projective area of 5mm${\times}$5mm. The diffusion current density of the microcolumn electrode is 1.73 times higher than that of the planar electrode at electrode potential of 1.1V in the half-cell test. The micro-DMFC based on the microcolumn electrodes shows the maximum power of 10.8$\pm$7.54㎼(43.23$\pm$0.16㎼/$\textrm{cm}^2$) at the projective area of 5mm${\times}$5mm, while the planar electrode micro-DMFC shows the maximum power of 0.81$\pm$0.42㎼(3.24$\pm$1.68㎼/$\textrm{cm}^2$) at the same projective area. The micro-DMFC based on the microcolumn electrodes shows 13 times higher power density that the micro-DMFC based on the planar electrodes does.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 1997년도 International Symposium on Fire Science and Technology
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• pp.518-525
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• 1997

A series of measurements and visualization to investigate the interaction of water sprays with pool fires is presented. Fire source is a small-scale pool burner with methanol, ethanol and gasoline. Measurements of temperatures, $O_2$, $CO_2$, and CO concentrations along the plume centerline are carried out to observe pool fire structures without water sprays. Visualization by the Ar-ion laser sheet shows flow pattern of droplets of the sprays above the pool fires. It is observed that in the case of methanol and ethanol, water sprays continuously penetrate into the center of fuel surfaces. The gasoline pool fire allows intermittent penetration of water sprays because of pulsating characteristics of the gasoline flame. To evaluate the cooling effect of the fuel surface by the sprays, the temperature was measured at the fuel surface. As soon as the mists reach the fuel surface of methanol and ethanol, the temperatures of the fuel surface decrease rapidly below the boiling point, and then the fires are extinguished. Due to the application of mist upon the gasoline fire, though the fuel temperature decrease abruptly at the time of the injection, such a rapid decrease do not continue till the extinction point.

• 전기화학회지
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• 제5권1호
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• pp.27-29
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• 2002

본 연구는 메탄올과 공기를 이용하여 상온, 상압에서 전기를 발생시키는 휴대폰용 전원공급 장치의 개발에 관한 것이다. 이 장치는 직접 메탄을 연료전지(DMFC)와 Back-up전지가 병렬로 연결되어 있어, 통화시 소요 전력의 최대 $50\%$ DMFC가 공급하고 나머지 부분은 Back-up 전지가 공급한다. 또한 통화 대기시에는 DMFC가 $100\%$ 필요 전력을 공급하고, 잉여 전력으로 Back-up전지를 충전한다. 상기 DMFC는 유효면적이 $9cm^2$인 8개의 단위전지가 직렬로 연결되어 있으며, 휴대폰의 작동 전압 범위인 2.5-3.9V의 전압을 출력한다.

• Bulletin of the Korean Chemical Society
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• 제34권9호
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• pp.2657-2662
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• 2013

Multiwalled carbon nanotube (MWCNT)-g-poly (aniline-co-2,5-diaminobenzenesulfonic acid) (DABSA) reinforced Nafion$^{(R)}$ nanocomposite membranes were prepared and characterized for direct methanol fuel cells (DMFCs). The nanocomposite membranes with approximately $90{\mu}m$ thickness were prepared by the water assisted solution casting method. To evaluate the properties of nanocomposite membranes for DMFC applications, the nanocomposite membranes were characterized by methanol and water uptake, thermal stability, and ion exchange capacity (IEC). Furthermore, oxidative stability measurements in terms of the hydrogen peroxide decomposition rate that represent the oxidative stability of the membranes were examined. The methanol uptake values of the nanocomposite membranes were dramatically decreased compared to the cast Nafion$^{(R)}$ membranes. The IEC values of the nanocomposite membranes were increased about 30% compared to the cast Nafion$^{(R)}$ membrane.

• 한국산학기술학회논문지
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• 제10권5호
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• pp.955-961
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• 2009

현재 소형 휴대용 배터리의 용량 증가에 따라 배터리 부피가 커지는 문제를 가지고 있다. 이러한 문제를 해결하기 위해 직접 메탄올 연료전지가 대안으로 떠오르고 있다. 본 논문에서는 직접 메탄올 연료전지를 상온 상태에서 자연 대류 방식으로 공기를 공급하고, 메탄올의 농도와 유량의 변화에 대한 특성을 분석하였다. 분석 결과 저 농도의 메탄올에서는 수소 이온의 확산 속도 지연에 따른 분극현상이 발생하였고, 메탄올의 공급량이 높을수록 전지 Cell의 냉각 효과가 발생하여 출력이 감소한다.

• 대한기계학회논문집
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• 제18권2호
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• pp.389-396
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• 1994

It is very important to clarify the ignition and flame propagation processes of methanol fuel in the Spark-ignition engine. High speed Schlieren photography and pressure trace analyses were used to study on combustion characteristics of methanol fuel in a constant volume chamber. Methanol-air mixtures equivalence rations from lean limit to 1.4 were ignited at initial pressure (0.1, 0.3, 0.5 MPa), temperature (313 343, 373 K) and ignition energy (40, 180 mJ). As the result of this study, we verified the characteristics such as ignition delay, effective thermal efficiency, flame propagation velocity, lean limit, ignitability and combustion duration. Obatained results are as follows. (1) The time to 10% reach of maximum pressure was 40-50% of the total combustion duration for this experimental condition hardly affected by equivalence ratio. (2) The Effective thermal efficiency, as calculated from maximum pressure was the highest when the mixture was slightly lean $({\phi} 0.8-0.9)$ and maximum pressure was the highest when the mixiture was slightly rich $({\phi} 1.2-1.2).$