• Title/Summary/Keyword: Methanol fuel

Search Result 481, Processing Time 0.023 seconds

Preparation of pore-filling membranes for polymer electrolyte fuel cells and their cell performances (고분자 연료전지용 세공충진막의 제조 및 연료전지 특성)

  • Choi, Young-Woo;Park, Jin-Soo;Lee, Mi-Soon;Park, Seok-Hee;Yang, Tae-Hyun;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2009.06a
    • /
    • pp.278-281
    • /
    • 2009
  • Proton exchange membrane is the key material for proton exchange membrane fuel cells (PEMFC). Currently widely-used perfluorosulfonic acid membranes have some disadvantages, such as low thermal stability, easy swelling, excessive crossover of methanol and high price etc. Other membranes, including sulfonated polymer, radiation grafted membranes, organic-inorganic hybrids and acid-base blends, do not satisfy the criteria for PEMFC, which set a barrier to the development and commercialization of PEMFC. Pore-filling type proton exchange membrane is a new proton exchange membrane, which is formed by filling porous substrate with electrolytes. Compared with traditional perfluorosulfonic acid membranes, pore-filling type proton exchange membranes have many advantages, such as non- swelling, low methanol permeation, high proton conductivity, low cost and a wide range of materials to choose. In this research, preparation methodology of pore-filling membranes by particularly using all hydrocarbon polymers and fuel cell performances with the membranes are evaluated.

  • PDF

Direct Synthesis of Dimethyl Ether From Syngas in Slurry Phase Reactor (액상 슬러리 반응기에서 합성가스로부터 DME 직접 제조)

  • Hwang, Gap-Jin;Kim, Jung-Min;Lee, Sang-Ho;Park, Chu-Sik;Kim, Young-Ho;Kim, Jong-Won
    • Journal of Hydrogen and New Energy
    • /
    • v.15 no.2
    • /
    • pp.119-128
    • /
    • 2004
  • DME(Dimethyl Ether) was directly produced from the synthesis gas using the slurry phase reactor. The catalyst for DME production prepared two types (A type; Cu:Zn:Al=57:33:10, B type; Cu:Zn:Al=40:45:15, molar ratio). It was evaluated for the effect of the reaction medium oil using the small size slurry phase reactor. DME production yield and the methanol selectivity decreased in the order: n-hexadecane oil> mineral oil> therminol oil. The long-term test of DME production was carried out using A and B type catalyst, and n-hexadecane oil and mineral oil, respectively. It was confirmed that the use of A type for the catalyst and n-hexadecane for the reaction medium oil was very useful for the viewpoint of the DME production form the synthesis gas.

Conceptual Design of the Fuel Injection Valve Tester for ME-LGI Marine Engine by Using System Engineering (ME-LGI 선박엔진용 연료분사밸브 테스터 개발을 위한 시스템 엔지니어링 기반 개념 설계)

  • Noh, Hyonjeong;Kang, Kwangu;Bae, Jaeil
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.19 no.5
    • /
    • pp.681-688
    • /
    • 2018
  • As environmental regulations have been strengthened and high fuel efficiency has been in demand in recent years, the number of ships using natural gas as a fuel is increasing. The demand for ships using LPG or methanol, which are emerging as eco-friendly vessel fuels, is also increasing. In this perspective, ME-LGI engines using LPG or methanol as a fuel have attracted considerable attention. Ships equipped with an ME-LGI engine are required to check the reliability of the fuel injection valve during shipping. This means that the development of a fuel injection valve tester is essential for the commercialization of ME-LGI engine. This study conducted the conceptual design of a fuel injection valve tester for ME-LGI engines using a system engineering process in the order of requirements analysis, functional analysis, and design synthesis. In the requirement analysis stage, the operating process of fuel injection valve was analyzed, and the necessity of checking the sealing oil leakage was then derived. In the functional analysis stage, the functions and flow of them were defined at each functional level. In the design synthesis stage, the equipment for each function was set and the process block diagram based on it was derived. In addition, preliminary risk analysis was performed as a part of system analysis and control, and safety measures were added to the conceptual design. This study is expected to be a good reference material for the concept design of other systems in the future because it shows the application process of a system engineering process to the conceptual design in detail.

Planar fuel cell design integrated with methanol reformer by using a high temperature membrane (고온형 멤브레인을 사용한 메탄올 개질 연료전지의 개질기 일체형 평판 설계)

  • Kim, Sung-Han;Jang, Jae-Hyuk;Gil, Jae-Hyoung;Lee, Hong-Ryul;Cha, Hye-Yeon;Ku, Bo-Sung;Jung, Chang-Ryul;Kundu, Arunaha;Miesse, Craig;Oh, Yong-Soo
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2006.11a
    • /
    • pp.467-470
    • /
    • 2006
  • For a mobile application such as cellular phone, micro fuel cells should be extremely compact and thin. RHFC can be an alternative solution because RHFC gives higher power density than DMFC and does not need ahydrogen storage vessel In this paper, RHFC using methanol fuel is made as a novel planar design without a PROX. Both reformer and cell are made closely in a same plate to share the heater of reformer with the cell. The PBI membrane is used in the cell. The reason is that high temperature of reformer can cause a performance drop when perfluorosulfonic acid membrane such as Nafion is used such a high temperature operation also guarantees the higher CO tolerance to MEA catalyst. The cell is designed as an air-breathing type which the cathode of the cell is opened to the air. The commercial Cu/ZnO/Al2O3 steam reformer catalyst is packed in reformer channel. The active area of MEA is $11.9cm^2$ and the peak power density was $27.5mW/cm^2$.

  • PDF

Synthesis of Biodiesel Using Supercritical Fluid (초임계유체를 이용한 바이오디젤연료의 제조기술)

  • Lee, Youn-Woo;Song, Eun-Seok;Kim, Hwayong
    • Clean Technology
    • /
    • v.11 no.4
    • /
    • pp.171-179
    • /
    • 2005
  • Biodiesel is synthesized by transesterification of vegetable or animal oils with alcohols. Since it has similar characteristic with diesel fuel, it can be used as a fuel by mixing with diesel fuel. Moreover, it is advantageous that biodiesel can reduce air pollution emitted from fuel combustion and is produced from sustainable energy, biomass. Recently, many researchers have investigated biodiesel synthesis using supercritical methanol since it is economical due to shorter reaction time and simple separation/purification process, compared with conventional alkali- or acid-catalyzed process. By the development of biodiesel production process from waste edible oil using supercritical methanol, it can be expected to utilize potential energy resources, reduce carbon dioxide emission, and improve environmental conditions.

  • PDF