• Title/Summary/Keyword: Methane reduction

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Analysis of Diesel Combustion Flames with Highly Oxygenated Fuels

  • Kim Bong-Seock;Ogawa Hideyuki
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.6
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    • pp.662-670
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    • 2005
  • With highly oxygenated fuels the smoke emissions decreased sharply and linearly with increases in the fuel oxygen content and entirely disappeared at an oxygen content of $38wt-\%$ even at stoichiometric mixture conditions The NOx also decreased monotonically with increases in oxygen content. and thermal efficiency slightly improved because of a reduction in cooling loss and improvement in the degree of constant volume combustion. The mechanisms of the significant reductions in emissions and improvement in engine performance were analyzed with a bottom view type DI diesel engine. Together with direct flame images, flame images were taken through an optical fetter passing only two wavelengths for use in 2-D two-color analysis. The results showed that luminous flame decreased significantly with increases in oxygen content and was not detected for neat dimethoxy methane(DMM). The decrease in flame luminosity with highly oxygenated fuels corresponds with decreases in soot and cooling losses, including those due to heat radiation. The 2-D two-color flame analysis indicated that the high temperature flame and high KL factor areas apparently decreased with increasing fuel oxygen content. These results correspond strongly with decreases in NOx. smoke. and cooling loss with increases in oxygen content.

Characteristics of Preheated Air Combustion in a Laminar Premixed Flame (층류 예혼합 화염의 예열공기 연소특성)

  • Lee, Jong-Ho;Lee, Seung-Young;Hahn, Jae-Won;Chang, Young-June;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.7
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    • pp.1039-1046
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    • 2002
  • Co-flow axisymmetric laminar premixed flame of methane was used to study the influence of air temperature and $N_2$ addition on the flame structure, temperature field and emission characteristics. OH 2-D images and temperatures along the centerline were measured experimentally by PLIF and CARS techniques respectively to observe the influences of dilution and thermal effects of $N_2$ in the gas mixture. Also, the concentration of NOx was measured at each condition by gas analyser to see the suppression effect of N2 addition on NOx emissions. It was found that OH concentrations distribute widely as air temperature goes higher, while the effect of $N_2$ addition is not significant. But $N_2$ addition highly contributes to the flame front and NOx emissions which was argued to be due to the reduction of flame temperature. In accordance with experimental study, numerical simulation using CHEMKlN code was carried out to compare the temperature results with those acquired by CARS measurement, and we could find that there is good agreement between those results.

Anaerobic Treatment of Food Waste Leachate for Biogas Production Using a Novel Digestion System

  • Lim, Bong-Su;Kim, Byung-Chul;Chung, In
    • Environmental Engineering Research
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    • v.17 no.1
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    • pp.41-46
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    • 2012
  • In this study, the performance of new digestion system (NDS) for the treatment of food waste leachate was evaluated. The food waste leachate was fed intermittently to an anaerobic reactor at increasing steps of 3.3 L/day (hydraulic retention time [HRT] = 30 day), 5 L/day (HRT = 20 day), and finally 10 L/day (HRT = 10 day). In the anaerobic reactor, the pH and alkalinity were maintained at 7.6 to 8.2 and 8,940-14,400 mg/L, respectively. Maximum methane yield determined to be 0.686L $CH_4$/g volatile solids (VS) containing HRT over 20 day. In the digester, 102,328 mg chemical oxygen demand (COD)/L was removed to produce 350 L/day (70% of the total) of biogas, but in the digested sludge reduction (DSR) unit, only 3,471 mg COD/L was removed with a biogas production of 158 L/day. Without adding any chemicals, 25% of total nitrogen (TN) and 31% of total phosphorus (TP) were removed after the DSR, while only 48% of TN and 32% of TP were removed in the nitrogen, phosphorus, and heavy metals (NPHM) removal unit. Total removal of TN was 73% and total removal of TP was 63%.

Effects of Ultrasonic Pretreatment on Sludge Biodegradability (초음파 전처리에 의한 슬러지 생분해성 영향 평가)

  • Kim, Ju-Hyun;Lee, Kang-Hoon;Nguyen, Hai;Yeom, Ick-Tae
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.4
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    • pp.611-616
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    • 2011
  • The impacts of ultrasonic pretreatment on the biodegradability of domestic sewage sludge were evaluated through a series of anaerobic digestion experiments in batch system. The gas and methane production from the sludge samples pretreated by an ultrasonic tool with different durations were measured with time. Although the biogas production increased with the extent of sludge solubilization and the period of ultrasonic pretreatment, the enhancement of sludge biodegradability was much more sensitive to the pretreatment for the relatively short periods. Most of the enhanced biodegradability by the pretreatment was appeared in the early stage of anaerobic digestion, less than 6 days. The maximum biogas production per day was observed between 4 to 6 days when the sludge was pretreated less than 10 minutes while it was obtained in the beginning for the sludge pretreated longer periods. The results suggest that the repeated alternation of low strength ultrasonic pretreatment and anaerobic digestion may be more effective than the combination of one time pretreatment for a relatively long period and following anaerobic digestion.

Numerical Study of the Effects of Hydrocarbon Addition and Corresponding Chemical Kinetics on the Promotion of NO Oxidation in Nonthermal Plasma DeNOx Treatment (비열 플라즈마에 의한 NO의 산화에서의 탄화수소 첨가 효과와 그 반응역학에 대한 수치적 연구)

  • Shin, Hyun-Ho;Yoon, Woong-Sup
    • Journal of the Korean Society of Combustion
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    • v.5 no.2
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    • pp.37-50
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    • 2000
  • In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of $NO-NO_2$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propylene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $HO_2$ etc.) successively are produced by hydrocarbon decomposition form the primary path of $NO-NO_2$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propylene to have higher affinity with O radical under all conditions, thereby both of these hydrocarbons show very fast and efficient $NO-NO_2$ oxidation. It was also shown that propylene is superior to ethylene in the aspect of NOx removal.

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Evaluation of Mixing Effects on Solid-state Anaerobic Digestion Performance of Dairy Manure and Sawdust Bedding Mixtures

  • Jo, Hyeonsoo;Lee, Seunghun;Lee, Jaehee;Kim, Eunjong;Ahn, Heekwon
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.3
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    • pp.227-234
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    • 2016
  • The influence of mixing on biogas production and organic material removal performance of solid state anaerobic digestion of dairy manure and sawdust bedding mixtures was evaluated using 22 L volume lab-scale digesters. After 45 days of anaerobic digestion at $37^{\circ}C$, cumulative methane yield of unmixed test unit ($73.1N{\cdot}mL/g-VS$) was almost 1.3 times of that of mixed one ($56.3N{\cdot}mL/g-VS$). The biodegradable volatile solids removal rate of unmixed test unit was 67%, which was almost 28% greater than mixed one. Our results reveal that unmixed condition is better than mixed one in terms of biogas production and organic material reduction.

The Effects of Secondary Fuel Injection on Combustion Oscillation

  • Shigeru Tachibana;Laurent Zimmer;Park, Gyung-Min;Takeshi Yamamoto;Ufosawa, Yoji-K;Seiji Yoshida;Kazuo Suzuki
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.376-379
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    • 2004
  • The purpose of this work is to develop an effective active control system for combustion instabilities of premixed combustors. For the first step, the natural modes of combustion oscillation were investigated for a methane-air premixed combustor and the controls by secondary fuel injection were examined. The main premixed flame is stabilized by a swirler with orifices for secondary injection installed on the central hub. For sensing purposes, a pressure transducer and a chemiluminescence sensor were placed on the appropriate positions. The acoustic characteristics and the source of the oscillation were analyzed by those signals. To test the controllability, two methods of actuations by secondary fuel injection were examined. One is the open loop control and the other is the closed loop control. The comparison of the reduction levels of p $_{rms}$ shows that the closed loop control with a phase-shift injection performs best in this condition.ition.n.

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Computer Simulation of Methanation Reactor with Monolith Catalyst (전산 모델링을 통한 모노리스 촉매형 메탄화 반응기의 성능 특성 연구)

  • Chi, Junhwa;Kim, Sungchul;Hong, Jinpyo
    • Journal of Hydrogen and New Energy
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    • v.25 no.4
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    • pp.425-435
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    • 2014
  • Simulation studies on catalytic methanation reaction in externally cooled tubular reactor filled with monolithic catalysts were carried out using a general purpose modelling tool $gPROMS^{(R)}$. We investigated the effects of operating parameters such as gas space velocity, temperature and pressure of feeding gas on temperature distribution inside the reactor, overall CO conversion, and chemical composition of product gas. In general, performance of methanation reaction is favored under low temperature and high pressure for a wide range of their values. However, methane production becomes negligible at temperatures below 573K when the reactor temperature is not high enough to ignite methanation reaction. Capacity enhancement of the reactor by increasing gas space velocity and/or gas inlet pressure resulted no significant reduction in reactor performance and heat transfer property of catalyst.

A Study on PSA Controll Strategy for Part Load Operation of a Hydrogen Generator (수소추출기의 부분부하 운전을 위한 PSA 제어전략에 대한 연구)

  • SANGHO LEE;SEONYEOB KIM;YOUNG CHOI
    • Journal of Hydrogen and New Energy
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    • v.33 no.6
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    • pp.819-826
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    • 2022
  • Fuel cell systems are being supplied to households and buildings to reduce greenhouse gases. The fuel cell systems have problems of high cost and slow startup due to fuel processors. Greenhouse gas reduction of the fuel cell systems is also limited by using natural gas. The problems can be solved by using a hydrogen generator consisting of a reformer and pressure swing adsorption (PSA). However, part load operation of the hydrogen generator is required depending on the hydrogen consumption. In this paper, PSA operation strategies are investigated for part load of the hydrogen generator. Adsorption and purge time were changed in the range of part load ratio between from 0.5 to 1.0. As adsorption time increased, hydrogen recovery increased from 29.09% to 48.34% at 0.5 of part load ratio. Hydrogen recovery and hydrogen purity were also improved by increasing adsorption and purge time. However, hydrogen recovery dramatically decreased to 35.01% at 0.5 of part load ratio.

Preliminary Thermodynamic Evaluation of a Very High Temperature Reactor (VHTR) Integrated Blue Hydrogen Production Process (초고온가스로 연계 블루수소 생산 공정의 열역학적 분석)

  • SEONGMIN SON
    • Journal of Hydrogen and New Energy
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    • v.34 no.3
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    • pp.267-273
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    • 2023
  • As the impacts of global climate change become increasingly apparent, the reduction of carbon emissions has emerged as a critical subject of discussion. Nuclear power has garnered attention as a potential carbon-free energy source; however, the rapidity of load following in nuclear power generation poses challenges in comparison to fossil-fueled methods. Consequently, power-to-gas systems, which integrate nuclear power and hydrogen, have attracted growing interest. This study presents a preliminary design of a very high temperature reactor (VHTR) integrated blue hydrogen production process utilizing DWSIM, an open-source process simulator. The blue hydrogen production process is estimated to supply the necessary calorific value for carbon capture through tail gas combustion heat. Moreover, a thermodynamic assessment of the main recuperator is performed as a function of the helium flow rate from the VHTR system to the blue hydrogen production system.