• 한국연소학회:학술대회논문집
• /
• 2000.12a
• /
• pp.33-46
• /
• 2000

In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of NO-$NO_2$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $NO_2$ etc.) successively produced by hydrocarbon decomposition form the primary path of NO-$NO_2$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propene to have higher affinity with 0 radical under all conditions, thereby both of these hydrocarbons show very fast and efficient NO-$NO_2$ oxidation. It was also shown that propene is superior to ethylene in the aspect of NOx removal.

• 한국연소학회:학술대회논문집
• /
• 2002.06a
• /
• pp.185-191
• /
• 2002

The influence of N2 addition on soot formation, flame temperature and NOx emissions is investigated experimentally with methane fuel co-flow diffusion flames. The motivation of the present investigation is the differences in NOx reduction reported between fuel-side and oxidizer-side introduction of N2. To determine the influence of dilution alone, fuel was diluted with nitrogen while keeping the adiabatic flame temperature fixed by changing the temperature of the reactants. And to see the thermal effect only, air was supplied at different temperature without N2 addition. N2 addition into fuel side suppressed the soot formation than the case of oxidizer-side, while flame temperature enhanced the soot formation almost linearly. These results reveals the relative influences of the thermal, concentration effects of N2 additives on soot formation In accordance with experimental study, numerical simulation using CHEMKIN code was carried out to compare the temperature results with those acquired by CARS measurement, and we could find that there is good agreement between those results. Emission test revealed that NOx emissions were affected by not only flame temperature but also N2 addition.

• Journal of Korea Technology Innovation Society
• /
• v.2 no.2
• /
• pp.290-308
• /
• 1999

In this study a system for the treatment or recyling of organic wastes from both urban and rural area was recommended. It was developed based on the resource recovery system regarding human being by four tectnologies; forage, methane production, high-grade composting and complete decomposition. High quality compost can be produced by combining several kind of wastes produced from urban and agricultural areas. High quality compost must possess not only general characteristics of ordinary compost, but also a superior ability to improve the soil properties and must contain more nutrients for plant. Cedar chips were recommended as the main bulking agent to adjust moisture contents and air permeability. Charcoal and zeolite can be used not only as the second bulking agent but also as fertilizer for improve the soil amendment. Complete decomposition of organic wastes is defined by organic matter being completely converted to $CO_2$ and water. All the input water was evaporated by the heat produced through the oxidation of organic matter, In the present study, the complete treatments were successfully achieved for Shochu wastewater, swine wastes, thickened excess sewage sludge, wastes produced by Chinese restaurant and anaerobic digested sludge. First of all, recycling center of organic wastes should be established for the protect the environments and effective recovery of organic resources. This may means the way to derive the recovery of human value.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2006.05a
• /
• pp.279-282
• /
• 2006

Experiments in low strain rate methane-air counterflow diffusion flames diluted with $CO_2$ have been conducted to investigate the flame extinction behavior and edge flame oscillation The critical mole fraction at flame extinction is examined in terms of velocity ratio and global strain rate. Onset conditions of the edge flame oscillation and the relevant modes are also provided with global strain rate. It is observed that flame length is intimately relevant to lateral heat loss, and this affects flame extinction and edge flame oscillation considerably. Edge flame oscillations are categorized into three: a growing-, a decaying-, and a harmonic-oscillation mode.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2011.11a
• /
• pp.258-262
• /
• 2011

The laminar burning velocity in premixed Oxy-CH4 flames was studied in a lab-scale Bunsen burner. $CH^*$ chemiluminescence method and Schliren photography were used. Experimental results were compared with numerical prediction which was calculated with a CHEMKIN 3.7 package with a PREMIX code. Global equivalence ratio of oxy-CH4 mixture was varied from 0.5 to 2.0 in a laminar flow region. The laminar burning velocity was measured as 3.1 m/s for Schlieren photograph and 2.9 m/s for $CH^*$ chemiluminescence technique (angle method).

• 한국연소학회:학술대회논문집
• /
• 2000.05a
• /
• pp.178-188
• /
• 2000

In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of $NO-NO_{2}$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $HO_{2}$ etc.) successively produced by hydrocarbon decomposition form the primary path of $NO-NO_{2}$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propene to have higher affinity with 0 radical under all conditions, thereby both of these hydrocarbons show very fast and efficient $NO-NO_{2}$ oxidation. It was also shown that propene is superior to ethylene in the aspect of NOx removal.

• 한국연소학회:학술대회논문집
• /
• 2005.10a
• /
• pp.320-327
• /
• 2005

An experimental study was performed to investigate the effects of partially premixing, varying the equivalence ratios from $1.36{\sim}{\infty}$, and swirlers with swirl numbers of 0, 0.28, 0.64, and 1.32, on the characteristic of radical ($OH^{\ast}$, $CH^{\ast}$, and $C_2^{\ast}$) and pollutant emission in partially premixed swirling flames. The signal from the electronically excited state of $OH^{\ast}$, $CH^{\ast}$, and $C_2^{\ast}$ was detected through a band pass filter with a photo multiplier tube, and flow fields images were detected through a schlieren system. The results demonstrated that the flame height decreases and jet spreading angle increase with increasing a swirl number. The more momentum ratio and swirl number increase, the more decrease flame height, and the generation of sooting flame is promoted.

• Proceedings of the KSME Conference
• /
• 2002.08a
• /
• pp.255-258
• /
• 2002

Liquid rocket engines using liquefied natural gas (LNG) or methane as a fuel is known to have several good characteristics, such as high specific impulse compared to other hydrocarbon fuels, environment-friendly exhaust gas, low production cost, and re-usability with low soot generation in the cooling channel. In this study, experimental combustion chambers capable of using LNC and $CH_{4}$ are being researched through experimental firing tests, and within easy range of eyes' inspection, there are the periodical existence of soot or discoloration in the chamber wall surface. This result means that mixture ratio of oxidizer and fuel fluctuates periodically between outer-row injectors in the mixing head in the circumferential direction. Therefore, based on this phenomenon, the variation of mixture ratio near the chamber wall caused by the spill pattern of a shear coaxial injector was analyzed quantitatively and the thermal heat flux Into the cooling channel is modified. Then, the calculated and modified results are compared with the measured ones.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2003.05a
• /
• pp.270-273
• /
• 2003

The characteristic of constant volume micro combustor was investigated experimentally. The shape of micro combustor was cylindrical and has row aspect ratio or has relatively large diameter compared with chamber height. Diameter and chamber height was varied to investigate the geometric effect of combustor on the flame propagation. Diameter of 15 mm and 7.5 mm was designed while chamber height was designed to be 1mm, 2mm, and 3mm. The effect of initial pressure was also investigated parametrically from 1bar to 3bar. The gas used in this study was stoichiometric mixture of methane and air. The maximum pressure achieved in down scaled combustors was lower than that of conventional combustor because heat loss to wall was dominant as expected. The maximum pressure responded favorably with the change of height of combustor and the initial pressure, the maximum pressure was also increased. The flame propagation was possible when the specific condition was satisfied. Although the quenching distance of stoichiometric mixture of CH4 and Air is 2.5 mm, the flame could propagate even under quenching distance as the initial pressure increased.

• Journal of Hydrogen and New Energy
• /
• v.20 no.1
• /
• pp.45-54
• /
• 2009

Reduction reactivity and carbon deposition characteristics of three oxygen carrier particles(OCN01, OCN02, OCN03) have been investigated by using hydrogen, methane, syngas, and natural gas as fuels. For all particles, the maximum conversion, the oxygen transfer capacity, and the degree of carbon deposition increased as the reactive carbon contents increased. The reduction rate and the oxygen transfer rate increased as the moles of required oxygen per input gas increased. The change of maximum conversion, reduction rate, oxygen transfer capacity, oxygen transfer rate and degree of carbon deposition for different fuels can be explained consistently by using parameters such as the reactive carbon contents and the moles of require oxygen per input gas.