• 한국염색가공학회지
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• 제27권2호
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• pp.142-148
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• 2015

The aim of this study was to investigate the possibility utilizing Metasequoia(Metasequoia glyptostroboides) cone as a new natural dye resource. Dyeing onto cotton fiber was carried out to study the effect of dyeing conditions and mordanting effect on dye uptake, color change, and colorfastness. FT-IR analysis supported that hydrolyzable tannins were contained in the extracted colorant. Metasequoia cone colorant showed low affinity to cotton fiber and maximum dye uptake was obtained at pH 3.5 showing YR Munsell color. Mordanting improved dye uptake regardless of mordant type, especially Fe($C_5H_{10}FeO_6$) mordant was effective as much as 2 times higher dye uptake comparing with un-mordanted sample. The color of dyed fabric with mordanting showed YR Munsell color except of the Fe($FeSO_4{\cdot}7H_2O$) mordanted sample showing Y Munsell color. Colorfastness to rubbing and washing was relatively good, whereas lightfastness of the dyed fabrics was above grade 3/4 except that the dyed samples with Fe mordanting showed grade 2. It is necessary to apply Metasequoia cone colorant onto other fibers, especially protein fibers, for evaluating its efficacy as a new natural dye resource.

• 한국염색가공학회지
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• 제30권3호
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• pp.208-215
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• 2018

The objective was to investigate the efficacy of Metasequoia(Metasequoia glyptostroboides) cone colorants as a new functional dye for wool fiber. Effects of dyeing conditions and mordanting on dye uptake, color change, and colorfastness were investigated for wool fiber. Compared with cotton and silk fibers, wool fiber showed better affinity for the Metasequoia cone colorants. Fe and Cu mordants improved dye uptake, and mordanting did not change the color of dyed fabric with YR Munsell color. Colorfastness to rubbing and washing was as good as grade 4, whereas lightfastness of the dyed fabrics was above grade 3. Antimicrobial activity of the colorants was very high 99.3% of reduction rate toward S. aureus. It was confirmed that Metasequoia cone colorants can be utilized as a new functional natural dye for wool fiber. In addition, considering its high antimicrobial functionality it could be applied to cosmetics and food.

• 한국염색가공학회지
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• 제27권4호
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• pp.281-287
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• 2015

The aim of this study was to investigate the possibility utilizing Metasequoia(Metasequoia glyptostroboides) cone as a new natural dye resource. In previous study, dyeing onto cotton fiber was carried out and Metasequoia cone colorant showed low affinity to cotton fiber and maximum dye uptake was obtained at pH 3.5 showing YR Munsell color. For further evaluation of its efficacy as a new natural dye resource, effects of dyeing conditions and mordanting on dye uptake, color change, and colorfastness were investigated for silk fiber. Metasequoia cone colorant showed good affinity toward silk fiber showing YR Munsell color and maximum dye uptake was shown at pH 3.5. Post-mordanting with Cu and Fe improved dye uptake, especially Fe($C_5H_{10}FeO_6$) mordant was effective as much as 2 times higher dye uptake comparing with un-mordanted sample. The color of dyed fabrics with mordanting showed YR Munsell color. Fe mordanted fabrics appeared dark gray~black color. Colorfastness to washing was relatively good, whereas lightfastness of the dyed fabrics showed grade 2. It was confirmed that Metasequoia cone colorant can be used as a new dye resource for silk fiber getting brownish yellow to dark gray/black color depending on mordant type. In addition, it showed antimicrobial functionality.

• 한국지구과학회지
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• 제29권4호
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• pp.319-327
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• 2008

경상북도 포항분지에 분포하는 제3계 육성층인 장기층군의 금광동층에서 산출된 메타세콰이아 화석에 대하여 고식물학적인 연구가 수행되었다. 연구 결과 낙지성(落枝性) 단지(短枝)의 화석은 대부분 Metasequoia occidentalis의 단일종에 속한다. 이 종은 하연(下延)하는 대생(對生)의 잎과 잎자루의 기부에 인편(鱗片) 갖는 특징이 있다. 이 종은 우리나라의 제3기 마이오세 식물군의 전역에서 공통적으로 많이 산출되지만, 마이오세 이후부터는 우리나라에서 화석 기록이 나타나지 않는다. 현생종의 분포와 생태로부터 판단하면, 화석 메타세콰이아는 포항 분지 주변의 수분 조건이 충분한 하천의 범람원에서 습지림을 이루었을 것으로 추정된다.

• 생명과학회지
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• 제15권2호
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• pp.231-235
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• 2005

기질 금속단백분해효소(MMP)는 기저막이나 간질성 조직 등에 있는 세포외기질 성분을 분해하여 상처 치유, 태아의 발생, 종양세포의 침윤과 전이 등을 포함하여 조직이 재구성되는 과정에서 생리학적 및 병리학적인 과정 양쪽 모두에 매우 중요한 역할을 한다. 본 연구에서는 MMP-9 유전자의 발현을 억제하는 물질을 천연물에서 탐색하였고, 탐색된 시료 중에서 높은 역가를 가진 낙우송과의 Metasequoia glyptostroboides가 선택되었다. 여러 가지 flavonoid 성분을 가지고 있는 Metasequoia glyptostroboides를 이용하여 4개의 biflavonoid와 2개의 monoflavonoid 구조의 물질을 분리하였고, 이 flavonoid들은 sciadopitysin, isoginkgetin, bilobetin, 2, 3-dihydrohino-kiflavone, luteolin, apigenin으로 정제하여 구조를 밝히고 zymography, WST-1을 이용한 세포독성시험, northern blot 등의 실험을 통하여 각 화합물의 구조적인 특성과 함께 MMP-9 유전자 발현을 억제하는 효과가 있는 것을 확인하였다.

• 한국잡초학회지
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• 제31권2호
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• pp.146-151
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• 2011

메타세콰이아(Metasequoia glyptostroboides)의 구과로부터 수증기증류법을 이용하여 정유를 추출하였고, 정유의 향취를 분석하였으며 이에 함유되어 있는 휘발성 화학성분을 solid-phase microextraction 장치가 장착된 gas chromatography-mass spectrometry를 이용하여 분석하였다. 메타세콰이아의 구과에 함유된 정유는 0.4%이었다. 정유의 주향취는 woody, coniferous, herbal이었으며, 부향취는 minty, spicy, oily이었다. 정유에는 총 9종의 휘발성 유기화합물이 함유되어 있었는데 이들을 화학성분별로 구분하면 탄화수소가 8종 그리고 옥사이드가 1종이었다. 정유에 함유된 휘발성 유기화합물은 limonene(66.18%), ${\delta}$-3-carene(11.11%), ${\beta}$-caryophyllene(6.66%), ${\beta}$-myrcene(5.92%), ${\beta}$-pinene(4.14%), caryophyllene oxide (2.39%), camphene(2.32%), ${\alpha}$-caryophyllene(0.85%), tricyclene(0.43%)이었다. 메타세콰이아 구과로부터얻은 정유의 herbal과 minty 향취는 limonene과 ${\delta}$-3-carene, spicy 향취는 caryophyllene, coniferous 향취는 ${\alpha}$-pinene과 ${\beta}$-pinene, oily 향취는 camphene에 의해 발현된 것이라 판단된다.

• 한국가구학회지
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• 제29권1호
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• pp.1-7
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• 2018

A study was carried out to observe the 1% aqueous safranine solution flow speed in longitudinal and radial directions of softwood Metasequoia glyptostroboides, diffuse-porous wood Anthocephalus cadamba and ring-porouswood Fraxinus rhynchophylla. In radial direction, ray cells and in longitudinal direction, tracheids, vessel and wood fiber were considered for the measurement of liquid penetration speed at less than 12% moisture contents (MC). The length, lumen diameter, pit diameter, end wall pit diameter and the numbers of end wall pits determined for the flow rate. The liquid flow in the those cells was captured via video and the capillary flow rate in the ones were measured. Vessel in hardwood species and tracheids in softwood was found to facilitate prime role in longitudinal penetration. Anatomical features like the length and diameter, end-wall pit numbers of ray parenchyma were found also responsible fluid flow differences. On the other hand, vessel and fiber structure affected the longitudinal flow of liquids. Therefore, the average liquid penetration depth in longitudinal tracheids of Metasequoia glyptostroboides was found the highest among all cells considered in Anthocephalus cadamba and Fraxinus rhynchophylla In radial direction, ray parenchyma of Metasequoia glyptostroboides was found the highest depth and the one of Fraxinus rhynchophylla was the lowest. The solution was penetrated lowest depth in the wood fiber of Fraxinus rhynchophylla. The large vessel of Fraxinus rhynchophylla was found the lowest depth among the vessels. The solutin was penetrated to the wood fiber of Anthocephalus cadamba higher than the one of Fraxinus rhynchophylla.

• Natural Product Sciences
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• 제15권1호
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• pp.12-16
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• 2009

Phytochemical investigation of Metasequoia glyptostroboids leaves resulted in the isolation of ten compounds. The structures were determined to be isoquercitrin (1), quercitrin (2), myricitrin (3), amentoflavone (4), sciadopitysin (5), isoginkgetin (6), 2,3-dihydrosciadopitysin (7), 2,3-dihydroisoginkgetin (8), $3{\beta}$-acetoxy-8(17),13E-labdadien-15-oic acid (9) and $\beta$-sitosterol (10) by spectroscopic analyses. Isoquercitrin (1) was isolated from this plant for the first time.

• Environmental Analysis Health and Toxicology
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• 제29권
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• pp.3.1-3.7
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• 2014

Objectives This study was conducted to determine the depositional characteristics of several tree barks, including Ginkgo (Ginkgo biloba), Pine (Pinus densiflora), Platanus (Platanus), and Metasequoia (Metasequoia glyptostroboides). These were used as passive air sampler (PAS) of atmospheric polybrominated diphenyl ethers (PBDEs). Methods Tree barks were sampled from the same site. PBDEs were analyzed by high-resolution gas chromatography/high-resolution mass spectrometer, and the lipid content was measured using the gravimetric method by n-hexane extraction. Results Gingko contained the highest lipid content (7.82 mg/g dry), whereas pine (4.85 mg/g dry), Platanus (3.61 mg/g dry), and Metasequoia (0.97 mg/g dry) had relatively lower content. The highest total PBDEs concentration was observed in Metasequoia (83,159.0 pg/g dry), followed by Ginkgo (53,538.4 pg/g dry), Pine (20,266.4 pg/g dry), and Platanus (12,572.0 pg/g dry). There were poor correlations between lipid content and total PBDE concentrations in tree barks ($R^2$=0.1011, p =0.682). Among the PBDE congeners, BDE 206, 207 and 209 were highly brominated PBDEs that are sorbed to particulates in ambient air, which accounted for 90.5% (84.3-95.6%) of the concentration and were therefore identified as the main PBDE congener. The concentrations of particulate PBDEs deposited on tree barks were dependent on morphological characteristics such as surface area or roughness of barks. Conclusions Therefore, when using the tree barks as the PAS of the atmospheric PBDEs, samples belonging to same tree species should be collected to reduce errors and to obtain reliable data.

• 한국작물학회:학술대회논문집
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• 한국작물학회 2006년도 한국약용작물학회 공동춘계학술발표회
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• pp.464-465
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• 2006