• 제목/요약/키워드: Metallic elements

검색결과 252건 처리시간 0.025초

粒子狀 物質中 金屬成分의 密度分布 (Density Distributions of Metallic Compounds in Particulate Matters)

  • 허문영;김형춘;손동헌
    • 한국대기환경학회지
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    • 제2권2호
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    • pp.9-18
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    • 1986
  • For identification and apportionment of sources emitting particulate matters in environment, the multi-elemental characterization of size-density fractionated particulate matters was carried out. Eight types of samples were tested; soil, flyash released from burning of bunker-Coil, diesel oil, coal, and soft coal, urban road-way dust, urban dust fall, and airborne particulate matter. The fractions of particulate matters obtained by heavy liquid separation methos with a series of dichloromethane-bromoform were then analyzed using atomic absorption spectrophotometry for Ni, Cr, Cu, An, Fe, Al, and Mg. Each sample showed a different concentration profile as a function of density, and a number of useful conclusions concerning characterization of elemental distribution were obtained. From the density distributions of elements in soil, the maximum value was found for all elements in the density range of 2.2 $\sim 2.9g.cm^{-3}$, including the density of $SiO_2$. However, the distribution of metallic compounds with the density lower than $2.2g.cm^{-3}$ was prevalent in urban roadway dust, urban dust fall, and airborne particulate matter. And the density distribution curves of these urban dusts also have the higher distribution at the density of 2.2 - 2.9g.cm^{-3}$, including the density of wind-blown silica. This tendency generally was prevalent in the natural source elements, such as Al, Fe, Mn, and Mg. The maximum values were found in the density ranges of 1.3 $\sim 2.2g.cm^{-3}$ from the density distribution of elements in oil fired flyash. These distributions of anthropogenic source elements, such as Zn, Ni, Cu, and Cr were higher predominately than those of natural source elements. And the higher distribution was found in the density range of $2.2 \sim 2.9g.cm^{-3}$ from the density distribution of elements in coal and soft-coal fired flyash. These distributions showed similar patterns to soil. But anthropogenic source elements somewhat predominated at the density ranges of $1.3 \sim 2.2g.cm{-3} and 2.9g.cm^{-3}$ to soil. Therefore the higher distribution of anthropogenic source elements in the density ranges of $1.3 \sim 2.2g.cm^{-3} and 2.9g.cm^{-3}$ was considered as anthropogenic origin.

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Characterization of PM10 and Air-borne Metallic Elements Produced in Asan and Seoul

  • Son, Bu-Soon;Choi, Kyung-Ho;Yang, Won-Ho
    • 한국환경보건학회:학술대회논문집
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    • 한국환경보건학회 2004년도 International Conference Global Environmental Problems and their Health Consequences
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    • pp.142-145
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    • 2004
  • The purpose of this study was to characterize background mass concentration of fine particle PM10 and metallic composition from September 2001 to August 2002 in comparison with a medium-sized city, Asan and a metropolitan city, Seoul. Annual mean PM10 concentrations in Asan and Seoul were 47.98 and $75.33\;{\mu}g\;/\;m^3$, respectively. The concentrations of PM10 were highest in spring season in both cities. The concentrations of measured metals except As and Pb in Asan were higher than those in Seoul. Yellow dust could affect the mass and metals concentrations of measured PM10 in Asan and Seoul. Relationship between measured metals concentrations showed that Si and Fe were associated with natural sources such as soil. Pb, Cu and Zn were closely related to urban anthropogenic sources such as fuel combustion. Especially, relationship between metals showed different association during yellow dust. Proper management for fine particles is warranted in Asan, considering the concentrations of metallic elements in fine particles in Asan were relatively higher than those in Seoul.

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DV-Xα 분자궤도법으로 설계한 생체용 Ti-Ag-Zr 합금 특성 평가 (A Study on the Properties of Design for the Biomaterial Ti-Ag-Zr Alloys Using DV-Xα Molecular Orbital Method)

  • 백민숙;윤동주;김병일
    • 한국재료학회지
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    • 제24권4호
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    • pp.175-179
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    • 2014
  • Ti and Ti alloys have been extensively used in the medical and dental fields because of their good corrosion resistance, high strength to density ratio and especially, their low elastic modulus compared to other metallic materials. Recent trends in biomaterials research have focused on development of metallic alloys with elastic modulus similar to natural bone, however, many candidate materials also contain toxic elements that would be biologically harmful. In this study, new Ti based alloys which do not contain the toxic metallic components were developed using a theoretical method (DV-$X{\alpha}$). In addition, alloys were developed with improved mechanical properties and corrosion resistance. Ternary Ti-Ag-Zr alloys consisting of biocompatible alloying elements were produced to investigate the alloying effect on microstructure, corrosion resistance, mechanical properties and biocompatibility. The effects of various contents of Zr on the mechanical properties and biocompatibility were compared. The alloys exhibited higher strength and corrosion resistance than pure Ti, had antibacterial properties, and were not observed to be cytotoxic. Of the designed alloys' mechanical properties and biocompatibility, the Ti-3Ag-0.5Zr alloy had the best results.

탐진강 및 도암만 지역 퇴적물의 퇴적지구화학적 특성과 환경영향 (Sedimentary Geochemical Characteristics and Environmental Impact of Sediments in Tamjin River and Doam Bay)

  • 홍진택;나범수;김주용;고영구;윤석태;신상은;김해경;문병찬;오강호
    • 환경영향평가
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    • 제16권6호
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    • pp.393-405
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    • 2007
  • To examine the sedimentary geochemical characteristics of sediment in the Tamjin River and Doam bay, the analysis was conducted, using the sample obtained in February 2000, on the grain size and the contents of metallic elements and organic carbon. The factors that influence the geochemical behavior of metallic elements in the surface sediment are grain size, organism, surrounding soil and $CaCO_3$. To find out the pollution level of metallic elements, the enrichment factor (EF) and the index of geoaccumulation ($I_{geo}$) were researched. The majority of metallic elements sustain their values in natural state. The elements such as K, Ba, Zr, etc. appear to be rich in some places. The EF and $I_{geo}$ of P, Cu, Zn, and Pb, which belong to toxic heavy metals, are partly related with man-made pollution. P and Cu have a high EF, Pb has a high $I_{geo}$ and Zn is high in both EF and $I_{geo}$. The low contents of P and Cu are not likely to be related with the pollution of water environment. However, given the development of relative pollution, the research and the management regarding the pollutants are needed. Because Pb, naturally enriched by geological characteristics, has a large influence on water environment along with Zn, the adequate measures against man-made pollution should be worked out.

양.음이온교환 크로마토그래피와 유도결합플라스마 원자방출분광법을 이용한 모의 사용후핵연료 중 핵분열생성물 분석 (Determination of Fission Products in Simulated Nuclear Spent Fuels by Cation.Anion Exchange Chromatography and Inductively Coupled Plasma Atomic Emission Spectrometry)

  • 최광순;손세철;표형렬;서무열;김도양;박양순;지광용
    • 분석과학
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    • 제13권4호
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    • pp.446-452
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    • 2000
  • 질산에 잘 녹지 않는 백금족 원소를 포함하고 있는 모의 사용후핵연료(SIMfUEL)를 고압산분해 방법으로 녹였다. 핵분열생성물 원소들은 우라늄과 분리한 다음 유도결합플라스마 원자방출분광법 (ICP-AES)으로 분석하였다. 핵분열생성물 원소들의 피크가 우라늄 스펙트럼으로부터 분광학적 간섭을 받으므로 Mo, Pd, Rh 및 Ru은 양이온교환수지로 Ba, Ce, La, Nd, Rh, Sr, Y 및 Zr는 음이온교환수지로 우라늄과 원소들을 군분리하였다. 사용후핵연료의 조성과 비슷한 모의 핵연료용액을 만들어 양이온 교환수지로 분리한 다음 측정한 회수율은 99-103%이고, 음이온교환수지로 분리하고 측정한 회수율은 이트륨을 제외하고 96.5-107%이었다. 이 방법을 금속원소의 농도가 수백에서 수천 ppm 존재하는 SIMFUEL에 적용하여 측정한 상대표준편차는 1.3-6.7%이었다.

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알루미늄 합금의 성분원소가 절삭 특성에 미치는 영향 (Effect of Machining Characteristics Aluminium Alloy added Composition Elements)

  • 채왕석;김경우;최현민;김동현
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 1997년도 추계학술대회 논문집
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    • pp.857-860
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    • 1997
  • The purpose of this research was to study the influence of machining characteristics for aluminum alloys. The effect of metallic microstructural variables on the measures of machinability of aluminum alloys has no been adequately investigated. Machining Characteristics are influenced significantly by mechanical characteristics, composition and structure of material etcs. For improvement of machining characteristics, various studies are reported. In this paper, composition elements add to aluminum alloys within the limit of sustaining mechanical characteristics of metallic material. We have analyzed dynamic characteristics of cutting resistance, tensile strength value, hardness value etcs.

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순환골재와 천연제올라이트 피복에 의한 연안퇴적물 오염물질 용출 차단 효과 (Effects of Capping with Recycled Aggregates and Natural Zeolite on Inhibition of Contaminants Release from Marine Sediment)

  • 김영기;신우석
    • 한국물환경학회지
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    • 제32권6호
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    • pp.546-551
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    • 2016
  • In this study, capping with recycled aggregate and natural zeolite in marine sediment was performed to investigate its inhibitory effect on pollutants released from sediment to seawater. An experiment was performed by capping with amendments for 60 days, and concentrations of organic matter (COD), nitrate, phosphate and metallic elements (Ni, Zn, Cu, Pb, Cd, As, and Cr) were measured. Two capping materials effectively suppressed pollutant release. Recycled aggregate showed better effectiveness for organic pollutant, nitrate and phosphate release. Meanwhile, natural zeolite was effective for metallic elements. As a result, recycled aggregate and natural zeolite can be considered as cost-effective/inexpensive capping material candidates. Also, the capping material can be selected according to the target pollutant.

Theoretical and Numerical Study of Cylindrical-vector-mode Radiation Characteristics in Periodic Metallic Annular Slits and Their Applications

  • Kim, Hyuntai;Jeong, Yoonchan
    • Current Optics and Photonics
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    • 제2권5호
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    • pp.482-487
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    • 2018
  • We investigate the radiation characteristics of radially polarized light and azimuthally polarized light through plasmonic subwavelength-scale annular slit (PSAS) structures, by means of both theoretical and numerical methods. Effective-medium theory was utilized to analyze the characteristics of PSAS structures, and the corresponding results showed that PSAS structures can function as a metallic medium for azimuthally polarized light, or as a low-loss dielectric medium for radially polarized light. Numerical calculations based on the finite-element method were also performed, to verify the theoretical analyses. It turned out that the numerical results supported the theoretical results. Moreover, we exploited the PSAS structures in novel nanophotonic elements with dual functionalities that could selectively focus or pass/block incident light, depending on its polarization state. For example, if PSAS structures were implemented in the dielectric region of a metallic Fresnel zone plate, the modified zone plate could function as a blocking element to azimuthally polarized light, yet as a focusing element to radially polarized light. On the contrary, if PSAS structures were implemented in the metallic region of a metallic Fresnel zone plate (i.e. the inverted form of the former), it could function as a focusing element to azimuthally polarized light, yet as a simple transparent element to radially polarized light.

황해 남동해역 표층퇴적물 중 수종 금속원소의 분포 특성에 관한 연구 (Distribution of Some Metallic Elements in Surface Sediments of the Southeastern Yellow Sea.)

  • 이창복;정회수
    • 한국해양학회지
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    • 제27권1호
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    • pp.55-65
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    • 1992
  • 황해 남동해역에서 채취한 97개 표층퇴적물을 대상으로 그 지화학적 특성을 규명 하기 위하여 철, 망간, 니켈, 구리 및 납의 5가지 금속원소 함량과 아울러 퇴적물의 입도와 탄산염 함량 등이 분석되었다. 분석된 금속원소 중 니켈과 구리는 퇴적물 입도 와 밀접한 상관관계를 나타내어 그 공간적 분포는 입도분포와 유사하게 나타났다. 이 와는 대조적으로 망간과 납의 경우는 입도와의 관련성이 미약하였으며, 전반적으로 한 국 연안에 인접한 시료에서 높은 함량이 나타났다. 한편, R-mode 요인분석 결과도 니 겔과 구리의 함량을 조절하는 요인이 망간이나 납의 함량을 조절하는 요인들과 구별됨 을 보여주었으며, 금속원소의 행동과 분포에 있어 이렇게 상반된 결과가 나타나는 현 상은 퇴적후 속성작용 및 환경오염물질 유입의 영향에 기인한 것으로 해석되었다. 이 에 근거하여 이들 금속원소들의 비가 서로 다른 기원의 세립물질들을 구분하는 특징으 로 이용될 수 있는 가능성이 제시되었다.

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