• 제목/요약/키워드: Metallic elements

검색결과 252건 처리시간 0.026초

가막만 표층퇴적물 중 알칼리 및 알칼리 토금속 원소의 생지화학적 특성 (Biogeochemistry of Alkaline and Alkaline Earth Elements in the Surface Sediment of the Gamak Bay)

  • 김평중;박승윤;김상수;장수정;전상백;주재식
    • 해양환경안전학회지
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    • 제18권1호
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    • pp.1-13
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    • 2012
  • 2010년 4월 가막만 전역의 19개 정점에서 표층퇴적물을 채취하여 퇴적물의 입도 분포, 유기물의 기원, 알칼리 원소(Li, Na, K, Rb) 및 알칼리 토금속(Be, Mg, Ca, Sr, Ba)원소의 분포특성을 파악하였다. 조사해역의 퇴적물 유형은 대부분 Mud로 나타났다. Chlorophyll $a$, TOC, TN, TS 및 LOI의 경우 만의 북부해역과 어류양식장이 산재되어 있는 남측해역에서 높은 농도분포를 보였으며, 만의 중앙부에서 낮은 농도를 보였다. 이들 성분과는 반대로 산화환원전위의 경우 만의 중앙부에서 대체로 (+)값으로 산화상태를 나타내었으며, 만의 북부해역과 남측해역에서 (-)상태로 환원환경 특성을 보였다. 유기물의 기원은 대부분 자생기원 유기물질 이였으나, 일부 정점에서 육상 및 박테리아성 유기물 기원 특성을 보였다. 알칼리 및 알카리 토금속 원소 중 Li, Na, K, Rb, Be, Mg, Ca 및 Sr의 경우 대부분의 정점에서 석영희석 효과에 의해 일차적으로 농도 분포가 결정된다. Ba의 경우 본 조사해역에서 중정석(Barite)가 존재하는 것으로 생각되며, Sr 및 Ba의 경우 이차적으로 탄산염 희석과 산화환원전위에 의한 생지화학적 영향을 직간접적으로 받는 것으로 보인다.

한국에 분포하는 한약자원식물의 무기물 함량에 관한 연구 제 2 보 ( The Mineral Content of Medical Wild Plant Resources in Korea ( II ) )

  • 이상래
    • 한국자원식물학회지
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    • 제3권2호
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    • pp.115-121
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    • 1990
  • In view of the results to have measured metallic elements which is included in 40 sorts of herb medicines and surveyed their distribution, ninekinds of metals including Co, Ce, Ga, 71, Cd, As, Sbr Bu. Pb, are never orlittle included in almost herb medicines. Other twenty four sorts of ele-ments (Mo, Sc, Be, V, Ni, Su, Se, Ba, Cr, Su, Ti, B, Li, Mg, Ca, Sr, Mnl Fe,Cu, Zn. p, Al, Na, K) are metals that are included in large quentities incomparison with others. Selagirellae Radix contains is kinds of metallicelements more then other herb medicines does. The content of elements ofinorganic metal differs greatly according to the part of herb medicines .

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Organic Precipitate Flotation of Trace Metallic Elements with Ammonium Pyrrolidinedithiocarbamate (II). Application of Solvent Sublation for Determination of Trace Cd, Co, Cu and Ni in Water Samples

  • 김영상;정용준;최희선
    • Bulletin of the Korean Chemical Society
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    • 제19권1호
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    • pp.50-56
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    • 1998
  • A solvent sublation was studied for the determination of trace Cd, Co, Cu and Ni in water samples. Ammonium pyrrolidine dithiocarbamate (APDC) was used as a complexing agent. Experimental conditions such as pH of solution, amounts of APDC, the type and amount of surfactant, the type of solvent, etc. were optimized for the effective sublation of analytes. After metal-PDC complexes were formed in sample solutions of pH 2.5, the precipitate-type complexes were floated in a flotation cell with an aid of sodium lauryl sulfate as a surfactant and by bubbling with nitrogen gas. The precipitates were dissolved and separated into the surface layer of methyl iso-butyl ketone (MIBK). The analytes preconcentrated were determined by a graphite furnace atomic absorption spectrophotometry (GF-AAS). Extractability of each element was 88% for Cd(Ⅱ), 86% for Co(Ⅱ), 95% for Cu(Ⅱ) and 76% for Ni(Ⅱ), respectively. And this procedure was applied to the analysis of real samples. From the recoveries of more than 92%, it was concluded that this method could be simple and applicable for the determination of trace elements in various water samples of a large volume.

Fe가 첨가된 과공정 Al-Si-Fe합금 압출재의 기계적특성 및 미세조직에 관한 연구 (Effect of Fe Addition on Mechanical Properties and Microstructure of As-Extruded Hypereutectic Al-Si-Fe Alloy)

  • 이세동;김덕현;백아름;임수근
    • 소성∙가공
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    • 제28권3호
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    • pp.123-129
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    • 2019
  • Hypereutectic Al-Si alloys have been widely utilized for wear-resistant components in the automotive industry. In order to expand the application of Hypereutectic Al-Si alloys, the addition of alloying elements forming a stable precipitate at high temperature is required. Thermally stable inter metallic compounds can be formed through the addition of transition elements such as Fe, Ni to Al alloys. However, the amount of transition element to be added to Al alloys is limited due to their low solid solubility. Also, hypereutectic Al-Si-Fe alloys form coarse primary Si phases and needle-shaped intermetallic compounds during solidification in the general casting processes. In this study, the effects of the destruction of Intermetallic compound and Si phase are investigated via hot extrusion. Both the microstructure and mechanical properties are discussed under different extrusion conditions.

부산지역의 미세먼지 중 중금속 및 이온성분과 선박배출가스의 영향에 관한 연구 (A Study on the Metallic and Ion Elements by Fine Particle and Effects of Vessels Exhaust Emission in Busan City)

  • 이승원;손이슬;김정권
    • 한국환경과학회지
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    • 제20권1호
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    • pp.147-153
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    • 2011
  • The objectives of this study were to investigate the seasonal characteristics of metallic and ion elements of $PM_{10}$(Particulate matter with aerodynamic diameter ${\leq}10\;{\mu}m$) and the effects of vessels exhaust emission from ships harboring in Busan City. The $PM_{10}$ samples were collected from January 2010 to October 2010 at Dongsam-dong(coastal area), in Busan City. The particulate matters were analyzed for major water soluble ionic components and metals. The ranges of the $PM_{10}$ mass concentrations were from 29.8 ${\mu}g/m^3$ to 47.0 ${\mu}g/m^3$ in Dongsam-dong. The $PM_{10}$ mass concentrations in Dongsam-dong are very similar to Gwangbok-dong during same sampling periods. These results were understood by the effects of the shipping source emitted from ships anchoraging and running. The concentrations of water-soluble ions and metals in the $PM_{10}$ had a level of as high as the order of $SO_4^{2-}$>$NO_3^-$>$Cl^-$ and $NH_4^+$>$Na^+$>$Ca^{2+}$>$K^+$>$Mg^{2+}$, respectively. The correlation coefficients($R^2$) for $SO_4^{2-}/PM_{10}$ and $NH_4^+/PM_{10}$ of were 0.7446 and 0.7784, respectively, and it showed the high correlation with each other.

지화학적 평가기법을 이용한 전남 서해 도서갯벌 퇴적물내 중금속 오염도 평가 (Evaluation of Heavy Metal Contamination in Intertidal Surface Sediments of Coastal Islands in the Western Part of Jeollanam Province Using Geochemical Assessment Techniques)

  • 황동운;김성길
    • 한국수산과학회지
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    • 제44권6호
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    • pp.772-784
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    • 2011
  • We measured grain size, organic matter, and metallic elements (Fe, Cu, Pb, Zn, Cd, Cr, Mn, Hg, and As) in intertidal sediments collected from six islands in the western part of Jellanam Province in order to evaluate heavy metal contamination in the tidal flat sediments of coastal islands. The evaluation of metal contamination was carried out using geochemical assessment techniques such as sediment quality guidelines (SQGs), enrichment factor (EF), and geoaccumulation index ($I_{geo}$). Surface sediments were classified into four sedimentary facies: sand, gravelly muddy sand, slightly gravelly mud, and silt. The concentrations of heavy metals in intertidal sediments from Jaeun, Amtae, Biguem, and Docho islands showed good positive correlations with mean grain size and ignition loss, indicating that the concentrations of metallic elements in these sediments were dependent on grain size and the organic matter content. The concentrations of heavy metals in sediments from almost all of the stations were lower than two criterion values proposed by the National Oceanic and Atmospheric Administration (NOAA) in the United States. Based on the EF and $I_{geo}$ results, surface sediments were a little polluted for Cr and were moderately polluted for As. Our results suggest that more intensive studies are necessary in the future in order to determine the major source of As in intertidal sediment and to evaluate the As pollution level in macrobenthos.

FE simulation of S-N curves for a riveted connection using two-stage fatigue models

  • Correia, Jose A.F.O.;de Jesus, Abilio M.P.;Silva, Antonio L.L.;Pedrosa, Bruno;Rebelo, Carlos;Calcada, Rui A.B.
    • Advances in Computational Design
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    • 제2권4호
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    • pp.333-348
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    • 2017
  • Inspections of ancient metallic bridges have illustrated fatigue cracking in riveted connections. This paper presents a comparison between two alternative finite element (FE) models proposed to predict the fatigue strength of a single shear and single rivet connection. The first model is based on solid finite elements as well as on contact elements, to simulate contact between the components of the connection. The second model is built using shell finite elements in order to model the plates of the riveted connection. Fatigue life predictions are carried out for the shear splice, integrating both crack initiation and crack propagation lives, resulting from the two alternative FE models. Global fatigue results, taking into account several clamping stresses on rivet, are compared with available experimental results. Proposed comparisons between predictions and experimental data illustrated that the proposed two-stage model yields consistent results.

교차 다이폴 소자 여기에 의한 다층 원형 도체 배열 구조의 구형 빔 패턴 형성에 관한 실험적 연구 (An Experimental Study on Shaping Flat-Topped Element Patterns of a Multi-layered Disk Array Structure Excited by Cross-Dipole Elements)

  • 엄순영;박한규
    • 한국전자파학회논문지
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    • 제14권7호
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    • pp.712-720
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    • 2003
  • 본 논문에서는 원형 편파의 구형 빔 패턴을 효율적으로 형성하기 위하여 교차 다이폴 소자로 여기되는 다층 원형 도체 배열 구조(MDAS)를 제안하였다. 다이폴 방사 소자 여기에 의한 MDAS는 전체 배열 안테나의 부피 및 무게를 줄일 수 있는 장점이 있으므로 비교적 낮은 주파수 대역 응용에 적합하다. 이러한 구조의 유효성을 검증하기 위하여 X 대역(7.9~8.4 GHz)에서 동작하는 MDAS 시제품을 제작하였으며, 설계 변수들은 설계 경험을 바탕으로 실험적으로 최적화하였다. 실험 결과는 교차 다이폴 소자에 의한 MDAS가 최소한 6.1 % 대역폭내에서 $\pm$20$^{\circ}$의 양호한 구형 빔 패턴을 형성함을 보여주었다.

급냉응고와 원소첨가에 의한 Mg-Zn합금의 미세조직 제어 (Microstructural Control of Mg-Zn Alloys by Rapid Solidification and Elemental Addition)

  • 김연욱;허보영
    • 한국주조공학회지
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    • 제18권3호
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    • pp.283-288
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    • 1998
  • Interest in rapid solidification of magnesium alloys stems from the fact that conventional ingot metallurgy alloys exhibit poor strength, ductility, and corrosion resistance. Such properties can be improved by microstructural refinement via rapid solidification processing. In this study, Mg-Zn alloys have been produced as continuous strips by melt overflow technique. In order to evaluate the influence of additional elements on the grain refinement and mechanical properties, Th and Zr were added in rapidly solidified Mg-5wt%Zn alloy. Then the microstructual observations were undertaken with the objective of evaluating the grain refinement as function of the cooling rate and the additional elements. The tremendous increase in hardness of Mg-Zn base alloys was mainly due to the refinement of the grain structure by the effect of rapid solidification and alloying elements. The formation of intermetallic phases on the grain boundaries may have a positive effect on the corroion resistance. Therefore, despite competition from many other developments, the rapid solidification processing of magnesium alloys emerges as a valuable method to develop superior and commercially acceptable magnesium alloys.

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A SMA-based morphing flap: conceptual and advanced design

  • Ameduri, Salvatore;Concilio, Antonio;Pecora, Rosario
    • Smart Structures and Systems
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    • 제16권3호
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    • pp.555-577
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    • 2015
  • In the work at hand, the development of a morphing flap, actuated through shape memory alloy load bearing elements, is described. Moving from aerodynamic specifications, prescribing the morphed shape enhancing the aerodynamic efficiency of the flap, a suitable actuation architecture was identified, able to affect the curvature. Each rib of the flap was split into three elastic elements, namely "cells", connected each others in serial way and providing the bending stiffness to the structure. The edges of each cell are linked to SMA elements, whose contraction induces rotation onto the cell itself with an increase of the local curvature of the flap airfoil. The cells are made of two metallic plates crossing each others to form a characteristic "X" configuration; a good flexibility and an acceptable stress concentration level was obtained non connecting the plates onto the crossing zone. After identifying the main design parameters of the structure (i.e. plates relative angle, thickness and depth, SMA length, cross section and connections to the cell) an optimization was performed, with the scope of enhancing the achievable rotation of the cell, its ability in absorbing the external aerodynamic loads and, at the same time, containing the stress level and the weight. The conceptual scheme of the architecture was then reinterpreted in view of a practical realization of the prototype. Implementation issues (SMA - cells connection and cells relative rotation to compensate the impressed inflection assuring the SMA pre-load) were considered. Through a detailed FE model the prototype morphing performance were investigated in presence of the most severe load conditions.