• Title/Summary/Keyword: Metallic Plate

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Electrochemical Properties of NiO-YSZ Thin Films on 316 Stainless Steel Bipolar Plates Under a Simulated PEMFC Environment

  • Lee, W.G.;Jang, H.
    • Bulletin of the Korean Chemical Society
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    • v.33 no.4
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    • pp.1177-1182
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    • 2012
  • The corrosion resistance of 316L stainless steel coated with NiO-YSZ (Ni added yttria stabilized zirconia) was examined in a proton exchange membrane fuel cell (PEMFC) environment. The NiO-YSZ coating was carried out using a sol-gel dip coating method, and the corrosion resistance and interfacial contact resistance (ICR) were determined by the composition and morphology of the NiO-YSZ film. The corrosion resistance increased with increasing Ni content in the NiO-YSZ film, but rapid corrosion was observed when the YSZ film contained more than 15 wt % Ni due to surface cracks. The polarization resistance was improved by several orders of magnitude when 316L stainless steel was coated with a 15 wt % NiO-YSZ film compared to bare 316L. The ICR of the NiO-YSZ film was decreased to that of bare 316L when the YSZ film contained 25 wt % NiO, suggesting the possible application of NiO-YSZ coated stainless steel for a bipolar plate.

Duplication of Koryo Tripitaka (Taejang′kyong) by Copper Electroforming (전주공정을 이용한 팔만대장경 동판제작)

  • 김인곤;강경봉;이재근;오명현
    • Journal of the Korean institute of surface engineering
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    • v.37 no.1
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    • pp.22-27
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    • 2004
  • Copper electroforming process has been applied to duplicate Koryo Tripitaka (Taejang'kyong), wooden printing block. Thin copper replica printing plates of 1 mm thickness was successfully manufactured from the printing face (54.5${\times}$25.5 cm) of wooden printing plate. Major processes are (1) silicon rubber replication of the master (2) silvering on silicon rubber (3) copper electroforming (4) separation of copper from the silicon mandrel (5) final coloring by brass plating and trimming. This process has various Potential applications in making thin metallic objects such as plaques, statues, bust and hollow metal objects for jewelry.

Effect of The Clearance on Core Deformation of Sandwich Plate during U-bending (U-bending 공정에서 틈새간격이 샌드위치판재의 내부구조 전단변형에 미치는 영향)

  • Seong, D.Y.;Jung, C.G.;Shim, D.S.;Yang, D.Y.;Chung, W.J.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.320-323
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    • 2008
  • In this study, a macroscopic approach was carried out to gain insight into the bending mechanism of metallic sandwich plates. Shear force-punch stroke curves for various clearances were analytically derived for mild steel (CSP 1N) sandwich plates with the total thickness of 3 mm and 0.5 mm face sheets. As the clearance increases, shear force of the inner structures and sensitivity of punch stroke decrease. These data are useful to derive a criterion of judgment for core shear failure and de-bonding failure during U-bending.

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Evaluation of Corrosion and Surface Resistance of Ni-Px/C Multi Layer (Ni-Px/C 다층 도금층의 내식성과 표면 전기저항 평가)

  • Park, Je-Sik;Jung, Eun-Kyung;Lee, Churl-Kyoung
    • Journal of the Korean institute of surface engineering
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    • v.45 no.4
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    • pp.162-167
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    • 2012
  • Ni-P/C multi-layer was synthesized by electroless plating and paste coating for better corrosion and surface conductance as a metallic bipolar plate. The Ni-P layer could be synthesized with the range of 2.6~22.4 at.% P contents and it's surface morphology and corrosion resistance depend on content of P. Corrosion resistance of the Ni-P layer in sulfuric acid by electrochemical test is similar with pure Ni. Surface resistance of pure Ni after corrosion was increased about 8% compared to pure Ni. On the other hand, that of the Ni-P/C composite with 20% carbon content was increased only 1%.

Micro-pattern Fabrication of Amorphous Alloy by Laser Beam Machining (비정질 합금의 마이크로 패턴 레이저 가공)

  • Kim, Haan;Park, Jong Wuk
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.4
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    • pp.77-83
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    • 2022
  • Amorphous alloys exhibit excellent mechanical properties; therefore, application technology development is being attempted in various fields. However, industrial use of application technology is limited owing to the limitations in fabrication. In this study, micropattern fabrication of an amorphous alloy was conducted using laser beam machining. Although microhole fabrication is possible without the deformation of the amorphous phase through nanosecond pulsed laser beam machining, there are limitations in the generation of recast layers and spatters. In cover plate laser beam machining (c-LBM), a cover plate is used to reduce the thermal deformation and processing area. Therefore, it is possible to fabricate holes at the level of several micrometers. In this study, it was confirmed that recast layers are hardly generated in c-LBM. Furthermore, square-shaped micropatterns were successfully fabricated using c-LBM.

The Effect of Coloring Condition on the Surface Characteristic of 304 Stainless Steel (304 스테인리스강의 착색 처리 조건이 표면 특성에 미치는 영향)

  • Kim, Ki-Ho
    • Journal of the Korean institute of surface engineering
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    • v.44 no.5
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    • pp.220-225
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    • 2011
  • 304 stainless steel plate was colored by hot dip and electrochemical treatment in a solution containing sulphuric and chromic acids. In the process, treatment variables such as operating time and methode were changed. The surface characteristics that changed by the treatment of the samples such as surface composition, oxide film thickness, color, surface roughness and reflectivity were studied. Surface composition was varied as follows. Fe was decreased, but Cr and O were increased. Ni was increased until 20 min, but reveals decreasing tendency as time passed after that. These means the surface film becomes chrome rich oxide phase as the treatment times increase. The thickness of film was about 220 nm at 30 min by dip treatment and it reduced as the treatment times increased. On the other hand, the thickness was about 150 nm at 10 min by electrochemical method and it doesn't increased with time. Surface color changed from metallic white of the base plate to gray, black, red, and green-blue, gradually, as the treating time increased. The reflectivity of colored surface measured by UVVIS-NIR spectrophotometer was reduced from max 38% of basis metal to min 3.5%.

Corrosion and Surface Resistance of Ni-C Composite by Electrodeposition (전해도금에 의한 Ni-C 복합층의 내식성 및 표면 전기저항)

  • Park, Je-Sik;Lee, Sung-Hyung;Jeong, Goo-Jin;Lee, Churl-Kyoung
    • Korean Journal of Materials Research
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    • v.21 no.5
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    • pp.288-294
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    • 2011
  • Simultaneous Ni and C codeposition by electrolysis was investigated with the aim of obtaining better corrosion resistivity and surface conductivity of a metallic bipolar plate for application in fuel cells and redox flow batteries. The carbon content in the Ni-C composite plate fell in a range of 9.2~26.2 at.% as the amount of carbon in the Ni Watt bath and the roughness of the composite were increased. The Ni-C composite with more than 21.6 at.% C content did not show uniformly dispersed carbon. It also displayed micro-sized defects such as cracks and crevices, which result in pitting or crevice corrosion. The corrosion resistance of the Ni-C composite in sulfuric acid is similar with that of pure Ni. Electrochemical test results such as passivation were not satisfactory; however, the Ni-C composite still displayed less than $10^{-4}$ $A/cm^2$ passivation current density. Passivation by an anodizing technique could yield better corrosion resistance in the Ni-C composite, approaching that of pure Ni plating. Surface resistivity of pure Ni after passivation was increased by about 8% compared to pure Ni. On the other hand, the surface resistivity of the Ni-C composite with 13 at.% C content was increased by only 1%. It can be confirmed that the metal plate electrodeposited Ni-C composite can be applied as a bipolar plate for fuel cells and redox flow batteries.

Strength Assessment of LNG CCS using Strength Analysis Method for Composite Materials (직교이방성 복합재료의 극저온 재료 물성치를 고려한 LNG CCS의 강도 평가에 관한 연구)

  • Jeong, Han Koo;Yang, Young Soon
    • Journal of the Society of Naval Architects of Korea
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    • v.51 no.2
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    • pp.114-121
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    • 2014
  • Liquefied natural gas(LNG) cargo containment system(CCS) has the primary function of ensuring both adequate structural safety with respect to sloshing load which is defined as a violent behaviour of the liquid contents in CCS due to external forced motions and thermal insulation keeping natural gas below its boiling point. Among different LNG CCS types such as independent B-type and membrane ones, Mark III CCS is considered in this paper to perform its strength assessment. Mark III CCS plate is designed and constructed by stacking various non-metallic engineering materials such as plywood, triplex, reinforced PU foam that are supported by series of mastic upon inner steel hull structure. From the viewpoint of structural analysis, this plated structure is treated as a laminated composite structure showing complex structural behaviour under external load. Advanced finite element models of Mark III CCS plate is generated and used in conjunction with ultimate strength based failure criteria from laminated composite mechanics for the strength assessment. The strength assessment is performed within the initial failure state of Mark III CCS plate. Results provide failure details such as failure locations and loads. Finally obtained results are reviewed using the loads from acceptance criteria suggested by classification.

A Study of Lamella Tearing being Produced by Corner Joint Welding in Box Column of Ultra Thick Plate (극후판 Box Column의 Corner Joint 용접시 발생하는 Lamella Tearing에 관한 연구)

  • Han-Sur Bang;Seong-Joo Kim;Jong-Myung Kim;Woong-Sung Jang;Young-Seob Kwon
    • Journal of the Society of Naval Architects of Korea
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    • v.36 no.4
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    • pp.95-104
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    • 1999
  • Use of the ultra thick plate is being continuously increased in large off-shore structures, ships, bridges and skyscraper construction, due to increasingly large-sized steel structures and it seems that this trend will be maintained. But, occurrence of the lamella tearing has been reported in ultra thick plate used for construction. It is reportedly caused by impurities such S(sulfur), P(phosphorus) and others accumulated in the ultra thick plate's centerline in the thickness direction with strip shape or by restraint residual stress caused by the welding. In the ultra thick plate made by continuous casting method, occurrence of lamination is difficult to avoid because of the properties of production procedure. Therefore, with a view to reducing the lamella properties, this report tries tearing in the steel structure in the view of welding strength rather than metallic properties, this report tries to seek the optimum groove and welding procedure by using the computer simulation based on FEM(Finite Element Method).

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Vibroacoustic response of thin power law indexed functionally graded plates

  • Baij Nath Singh;Vinayak Ranjan;R.N. Hota
    • Steel and Composite Structures
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    • v.50 no.3
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    • pp.299-318
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    • 2024
  • The main objective of this paper is to compute the far-field acoustic radiation (sound radiation) of functionally graded plates (FGM) loaded by sinusoidally varying point load subjected to the arbitrary boundary condition is carried out. The governing differential equations for thin functionally graded plates (FGM) are derived using classical plate theory (CPT) and Rayleigh integral using the elemental radiator approach. Four cases, segregated on power-law index k=0,1,5,10, are studied. A novel approach is illustrated to compute sound fields of vibrating FGM plates using the physical neutral surface with an elemental radiator approach. The material properties of the FGM plate for all cases are calculated considering the power law indexes. An in-house MATLAB code is written to compute the natural frequencies, normal surface velocities, and sound radiation fields are analytically calculated using semi-analytical formulation. Ansys is used to validate the computed sound power level. The parametric effects of the power law index, modulus ratios, different constituent of FGM plates, boundary conditions, damping loss factor on the sound power level, and radiation efficiency is illustrated. This work is the benchmark approach that clearly explains how to calculate acoustic fields using a solid layered FGM model in ANSYS ACT. It shows that it is possible to asymptotically stabilize the structure by controlling the intermittent layers' stiffness. It is found that sound fields radiated by the elemental radiators approach in MATLAB, ANSYS and literatures are in good agreement. The main novelty of this research is that the FGM plate is analyzed in the low-frequency range, where the stiffness-controlled region governs the whole analysis. It is concluded that a clamped mono-ceramic FGM plate radiates a lesser sound power level and higher radiation efficiency than a mono-metallic or metal-rich FGM plate due to higher stiffness. It is found that change in damping loss factor does not affect the same constituents of FGM plates but has significant effects on the different constituents of FGM plates.