• International Journal of Ocean System Engineering
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• v.2 no.3
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• pp.160-169
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• 2012

Flux Cored Arc Welding (FCAW) is a common practice to join thick plates such as the structural members of large scale offshore structures and very large container ships. The objective of this study was to investigate the mechanical properties and variability of the fatigue crack initiation life in the flux cored arc welded API 2W Gr.50 steel joints typically applied to offshore structures with a focus on the effect of the materials in fatigue crack growth life from the notch root of a compact tension specimen. Offshore structural steel (API 2W Gr.50) plates (60-mm thick) were used to fabricate multi-path flux core arc welded butt welded joints to clearly consider fatigue fractures at the weld zone from the notch. Fatigue tests were performed under a constant amplitude cyclic loading of R = 0.4. The mean fatigue crack initiation life of the HAZ specimen was the highest among the base metal (BM), weld metal (WM), and heat affected zone (HAZ). In addition, the coefficient of variation was the highest in the WMl specimen. The variability of the short fatigue crack growth rates from the notch tips in the WM and HAZ specimens was higher than in BM.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.9 no.4
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• pp.48-55
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• 2000

For the Tailor Welded Blank sheet used for automobile body panel, the characteristics of fatigue strength and crack propagation behavior were studied. The thickness of specimens was joined to be same (0.9mm+0.9mm) and different (0.9mm+2.0mm) .As a base test, mechanical properties around weld zone were examined . The results indicated that there were no significant decreases in mechanical properties , but hardness around weld bead was 2.3 times greater than base material . The fatigue strength was the highest when the loading direction was parallel to the welding direction, which was about 85% of tensile strength of base material. It was decreased by 8.5% when the thickness of specimens and base metal was different, and it was increased by 25% when pres-strain was applied. The crack propagation rate was noticeably decreased around weld line and rapidly increased as it passed through weld line. Reviewing the shape of the crack propagation , crack width around weld line was around the weld zone due to retardation of crack growth , but is became narrow passing weld line due to decreased toughness.

• Journal of the Korean Society for Precision Engineering
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• v.33 no.3
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• pp.199-205
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• 2016

A thin sheet of metal with corrugated structures has been utilized in various devices: heat exchangers, separators in fuel cells, and many others. However, it is not easy to fabricate thin corrugated structures using a single-step stamping process due to their geometrical complexity. To solve this problem, firstly, a plate type heat exchanger was redesigned to attain the optimal value of aspect ratio and the optimal shape of corrugated structures for the actual loading conditions. A forming analysis of the corrugated plate was then carried out to determine the process parameters. From this work, the optimal value of aspect ratio was found to be 4.6. In addition, the process parameters of heat exchanger forming were optimized using the optimal value of aspect ratio, and the analytical results were evaluated through experiments. The results obtained indicated good agreements between them.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.5
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• pp.529-537
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• 2000

Several Pt-based oxidation catalysts with different loading were prepared with various metal precursor solutions and characterized with H$_2$ chemisorption and TEM for Pt particle size. V was added to Pt-based catalyst for inhibiting SO$_2$oxidation reaction, as result, Pt-V/Ti-Si catalyst prepared by ERMS(Free Reduced Metal in Solution) method showed high enough activity and better inhibition on SO$_2$oxidation than Pt only catalyst. Optimum Pt particle size for diesel oxidation reaction turned out to be the size of around 20 nm. A prototype catalyst was prepared for light=duty diesel passenger car, and teated for the emission reduction performance with Korean regulation test mode(CVS-75 mode) on chassis dynamometer. The catalyst shows the performance reduction of 75~94% for CO, 53~67% for HC and 10~31% for PM. In the case of heavy-duty diesel catalyst, the domestic formal regulation teat mode D-13 was adopted for both Na engine and Turbo engine. The conversions of CO and THC are high enough(86% and 41%) while the reductions of NOx and PM are relatively low(3~11%).

• Resources Recycling
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• v.22 no.2
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• pp.3-10
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• 2013

Indium is one of the rare metals, and it has been used mainly for preparation of indium tin oxide (ITO). This review investigated the process parameters and the merits and demerits of several methods to recover indium from the leaching solution of secondary resources, such as solvent extraction, ion exchange, and precipitation. D2EHPA has been used mostly as a cationic extractant for indium extraction in moderate acid solutions, while amine extractants are used in strong hydrochloric acid solution. Since the loading capacity of resins for indium is generally small, ion exchange has some advantage over solvent extraction only when the concentration of indium is low.

• Journal of Welding and Joining
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• v.15 no.1
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• pp.46-54
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• 1997

The object of this paper is to evaluate SCC(stress corrosion cracking) susceptibility for parent metal and bond line region of weld joints which have the various weld heat input condtions in TMCP(thermo-mechanical control process) steel by SP-SSRT(small punch-slow strain rate test) method. And the SCC test results of TMCP steel are compared with those of the conventional HT50 steel which has te almost same tensile strength level like TMCP steel. The loading rate used was $3\times10^{-4}$mm/min and the corrosive environment was synthetic sea water. According to the test results, in the case of parent metal, TMCP steel showed higher SCC susceptibility than HT50 steel because of the high plastic strain level of ferrite microstructure obtained by accelerated cooling. And in the case of bond line, the both TMCP steel and HT50 steel showed low load-displacement behaviors and higher SCC susceptibility above 0.6. These results may be caused by theembrittled martensite structure on HT50 steel and by the coarsened grain and the proeutectoid ferrite structure obtained by the impart of accelerated cooling effect on TMCP steel.

• Journal of Environmental Science International
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• v.22 no.8
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• pp.945-951
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• 2013

Alumina-supported catalysts containing different transition metals such as Cu, Cr, Mn, Zn, Co, W were investigated for their activity in the selective oxidation of toluene. Catalytic oxidation of toluene was investigated at atmospheric pressure in a fixed bed flow reactor system over transition metals with $Al_2O_3$ catalyst. The result showed the order of catalytic activities for the complete oxidation of toluene was Mn > Cu> Cr> Co> W> Zn for 5wt.% transition $metals/Al_2O_3$. $Mn/Al_2O_3$ catalysts containing different amount of Mn were characterized by X-ray diffraction spectroscopy for decision of loading amount of metal to alumina. 5 wt.%$Mn/Al_2O_3$ catalyst exhibits the highest catalytic activity, over which the toluene conversion was up to 90% at a temperature of $289^{\circ}C$.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2002.10a
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• pp.139-142
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• 2002

This study presents a mathematical model predicting the stress-strain behavior of fiber reinforced (FMMCs) and fiber/particle reinforced metal matrix composites (F/P MMCs). MMCs were fabricated by squeeze casting method using Al2O3 short fiber and particle as reinforcement, and A356 aluminum alloy as matrix. The fiber/particle ratios of F/P MMCs were 2:1, 1:1, 1:2 with the total reinforcement volume fraction of 20 vol.%, and the FMMCs were reinforced with 10 vol,%, 15 vol. %, 20 vol. % of fibers. Tensile tests were conducted and compared with predictions which were derived using laminate analogy theory and multi-failure model of reinforcements. Results show that the tensile strength of FMMCs with 10 vol.% of fiber was well matched with prediction, and as the fiber volume increases, predictions become larger than experimental results. The difference between the prediction and experiment is considered to be a result of matrix allowance of fiber damage in tensile loading. As the fiber volume fraction in FMMCs increases, the fiber damage increases and so that the tensile strength is reduced. The strength of F/P MMCs approaches more closely to the prediction than FMMCs reinforced with 20 vol.% of fibers because F/P MMCs contains small quantity of fibers and thus has a positive effect in fiber strengthening.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.29 no.6 s.237
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• pp.860-875
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• 2005

A new meshfree method for the analysis of elasto-plastic deformations is presented. The method is based on the proposed first-order least-squares formulation, to which the moving least-squares approximation is applied. The least-squares formulation for the classical elasto-plasticity and its extension to an incrementally objective formulation for finite deformations are proposed. In the formulation, the equilibrium equation and flow rule are enforced in least-squares sense, while the hardening law and loading/unloading condition are enforced exactly at each integration point. The closest point projection method for the integration of rate-form constitutive equation is inherently involved in the formulation, and thus the radial-return mapping algorithm is not performed explicitly. Also the penalty schemes for the enforcement of the boundary and frictional contact conditions are devised. The main benefit of the proposed method is that any structure of cells is not used during the whole process of analysis. Through some numerical examples of metal forming processes, the validity and effectiveness of the method are presented.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.160.1-160.1
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• 2014

Using a density functional theory calculation including van der Waals (vdW) corrections, we report that $H_2$ adsorption in a cubic-crystalline microporous metal-organic framework (MOF-5) leads to volume shrinkage, which is in contrast to the intuition that gas adsorption in a confined system (e.g., pores in a material) increases the internal pressure and then leads to volumetric expansion. This extraordinary phenomenon is closely related to the vdW interactions between MOF and $H_2$ along with the $H_2$-$H_2$ interaction, rather than the Madelung-type electrostatic interaction. At low temperatures, $H_2$ molecules adsorbed in the MOF-5 form highly symmetrical interlinked nanocages that change from a cube-like shape to a sphere-like shape with $H_2$ loading, helping to exert centrosymmetric forces and hydrostatic (volumetric) stresses from the collection of dispersive interactions. The generated internal negative stress is sufficient to overcome the stiffness of the MOF-5 which is a soft material with a low bulk modulus (15.54 GPa).