• 한국응용과학기술학회지
• /
• 제26권1호
• /
• pp.80-86
• /
• 2009

This research was performed to evaluate heavy metal leaching characteristics of the sludge from paper mill process with sintering temperature. Heavy metal leaching of the sludge was characterized with Korean Leaching Test and Toxicity Characteristic Leaching Procedure. The test sludge was composed of 70.72% of moisture, 9.5% of volatile solids and 9.76% of fixed solids. As a result of XRF analysis, Fe was the highest inorganic element in approximately 83%, which implies the recycling possibility of the sludge in reuse of Fenton chemicals and artificial lightweight aggregate. Leaching of heavy metals from sintered sludge was lower than the dry ones. However, there was no significant difference in leaching characteristics between the sludges sintered at $350^{\circ}C$ and $650^{\circ}C$. Zn and Fe were leached more greatly in TCLP and KLT methods respectively.

• 대한기계학회논문집A
• /
• 제22권2호
• /
• pp.343-351
• /
• 1998

This paper was investigated degradation of the fracture toughness caused by sensitizing heat-treatment of the cryogenic structural material JN1 base metal using unloading compliance method reported as useful a method in evaluating the elastic-plastic fracture toughness at cryogenic temperature. The specimens used in this paper were 20% side-grooved 0.5T-CT specimens which were machined in the JN1 base metal. Also, to investigate cryogenic fracture toughness of the fusion line region in the JN1 GTA weldments, it was also used 20% side-grooved 0.5T-CT specimens that was machined fusion line to located in the middle of the specimen. The cryogenic fracture toughness values of the JN1 base metal were significantly decreased with increasing the time and temperature of the heat treatment. The fracture toughness value obtained from the fusion line specimen was invalid, but it was lower value than that of the JN1 base metal. Especially, this value was approximately equal with that obtained from the JN1 650.deg. C-5h heat-treated material.

• 전기학회논문지
• /
• 제65권10호
• /
• pp.1761-1766
• /
• 2016

In this paper, we investigated the fusing current of carbon fiber and thermal properties of carbon fiber and metal shielded cable due to over-current. The fusing current value for the metal-coated carbon fiber was 5.3A in 3K, 7.4K and 13.05A in 12K. And if it exceeds 50% of the fusing current was broken with a rapid voltage rise. In the case of carbon fiber shielded cable, the temperature of the PVC sheath increased somewhat in the allowable current range. However, the temperature of PVC sheath rapidly increased to $128.1^{\circ}C$ in the 2 time allowable current range. This value is $10^{\circ}C$ higher than the temperature of PVC sheath on the metal screen cable, because the resistance of the carbon fiber is high and heat transfer rate is slow.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
• /
• pp.727-730
• /
• 2009

Highly active and stable nano-sized Ni catalysts supported on MgO-$Al_2O_3$ calcined from hydrotalcite-like materials have been successfully developed with a strong metal to support interaction (SMSI) to enhance the coke resistance in combined $H_2O$ and $CO_2$ reforming of $CH_4$ (CSCRM) for syngas ($H_2$/CO=2) production. The change of the surface area and NiO crystallite size with varying the pre-calcination temperature of support and Mgo content was investigated in relation to the coke resistance. As increasing the pre-calcination temperature, the surface area decreases and the metal to support interaction becomes weak. As a consequence, the coke deposition was more severe on catalysts pre-calcined at high temperature. It was concluded that highly dispersed Ni metal in the surface of Ni/MgO-$Al_2O_3$ catalyst (MgO=30 wt%) pre-calcined at $800^{\circ}C$ had a strong metal to support interaction (SMSI) resulting in an increase of coke resistance and high activity.

• 공업화학
• /
• 제8권4호
• /
• pp.667-672
• /
• 1997

고용량 Nickel/Metal hybride 전지의 온도 거동을 3차원 유한요소법 software인 NISA를 사용하여 해석하였다. 전지 내부의 열전도에는 미분형 에너지 수지식을, 외부 대기와의 접촉면은 대류 열전달 방식을 사용하였다. 전지 온도에 영향을 미치는 요소인 열발생량과 대류 열전달계수에 대한 실험을 행하였고, 이 결과로부터 일반식을 도출하였다. 금속 재질의 cooling fin을 사용하므로써 급속한 충전이나 방전시 야기될 수 있는 온도 상승을 상당 부분 방지할 수 있었다. 전지 외벽에 열전도도가 낮고 얇은 절연물질을 부착하여도 최고온도의 상승에 미치는 영향은 미미하였다.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2011년도 추계학술대회 초록집
• /
• pp.97.2-97.2
• /
• 2011

Pt-Ru and Pt-Ni bimetallic catalysts were prepared and tested for heavy hydrocarbon reforming. Metals were supported on CGO($Ce_{0.8}Gd_{0.2}O_{2.0-x}$) by incipient wetness method. The prepared catalysts were characterized by Temperature programmed reduction(TPR). Oxidative steam reforming of n-dodecane was conducted to compare the activity of the catalysts. The reforming temperature was varied from $500^{\circ}C$ to $800^{\circ}C$ at fixed $O_2$/C of 0.3, $H_2O$/C of 3.0 and GHSV of 5,000/h.Reduction peaks of metal oxide, surface CGO and bulk CGO were detected. Reduction temperature of metal oxide decreased over the bi-metallic catalysts. It is considered that interaction between metals leads to decrease interaction between metal and oxygen. On the other hands, reduction temperatures of surface CGO were dectected in the order of Pt-Ru > Pt-Ni > Pt. low reduction temperatures of surface CGO indicates the low activation energy for oxygen ion conduction to metal. Oxygen ion conduction is known as de-coking mechanism of ionic conducting supports such as CGO. In activity test, fuel conversion was in the same order of Pt-Ru > Pt-Ni > Pt. Especially, 100% of fuel conversion was obtained over Pt-Ru catalysts at $500^{\circ}C$.

• 동력기계공학회지
• /
• 제18권2호
• /
• pp.70-76
• /
• 2014

A specimen of weld metal was prepared by GTA welding with weld wire of super duplex stainless steel. Aging treatment was conducted for the sample at the temperature range of 700 to $900^{\circ}C$ for 5 to 300 minutes. The effect of aging temperature and time to pitting corrosion of weld metal has been investigated and the results were derived as follows. The volume fraction of ${\sigma}$ phase tends to increase with an increase of aging temperature and time. Pitting potential Ep representing pitting corrosion was found to tend to decrease with an increase of aging time at 700 to $900^{\circ}C$. And most of the pits formed near the ${\sigma}$-phase in the ferrite and seemed to propagated to austenite.

• ETRI Journal
• /
• 제41권6호
• /
• pp.820-828
• /
• 2019

A highly reliable conductive adhesive obtained by transient liquid-phase sintering (TLPS) technologies is studied for use in high-power device packaging. TLPS involves the low-temperature reaction of a low-melting metal or alloy with a high-melting metal or alloy to form a reacted metal matrix. For a TLPS material (consisting of Ag-coated Cu, a Sn96.5-Ag3.0-Cu0.5 solder, and a volatile fluxing resin) used herein, the melting temperature of the metal matrix exceeds the bonding temperature. After bonding of the TLPS material, a unique melting peak of TLPS is observed at 356 ℃, consistent with the transient behavior of Ag₃Sn + Cu₆Sn₅ → liquid + Cu₃Sn reported by the National Institute of Standards and Technology. The TLPS material shows superior thermal conductivity as compared with other commercially available Ag pastes under the same specimen preparation conditions. In conclusion, the TLPS material can be a promising candidate for a highly reliable conductive adhesive in power device packaging because remelting of the SAC305 solder, which is widely used in conventional power modules, is not observed.

• 대한치과보철학회지
• /
• 제38권4호
• /
• pp.461-471
• /
• 2000

This study evaluated the effect of degassing on the ceramic bond strength of two Ni-Cr alloys under varying holding time at the upper limit temperature and atmospheric conditions. Metal specimens were divided into 5 groups for each alloy according to degassing conditions prior to porcelain application no degassing, degassing under vacuum without hold, degassing under vacuum with hold for 5 min. and 10 min. respectively at the upper limit temperature and degassing in air. Total number of metal ceramic specimens was eighty and each group had eight specimens. The ceramic bond strength was measured by four-point flexural test using Instron and the fractured surface was examined under SEM. The results obtained were as follows. 1. Degassing in air improved the ceramic bond strength of Ni-Cr alloys. 2. In degassing under vacuum, hold at the upper limit temperature was advantageous to the ceramic bonding of Ni-Cr alloys. 3. After ceramic metal bond test, metal surfaces were partially covered with the thin porcelain layer, and the cohesive failures in porcelain were predominant in groups showing higher ceramic bond strength.

• 한국해양공학회지
• /
• 제26권6호
• /
• pp.27-32
• /
• 2012

The effects of reheating during welding on the microstructure and impact toughness of weld metal in 25% Cr super duplex stainless steels were investigated. Using different heat inputs, weld metals with different reheated regions were obtained. This showed that, depending on the reheating temperature, the microstructure in the reheated region was quite different from that of the as-deposited microstructure. When reheated into the ${\gamma}+{\alpha}$ temperature range, fine intragranular austenite was formed in the as-deposited columnar structure. However, when reheated above the ${\alpha}$ solvus temperature range, most of the columnar structure disappeared and fine equiaxed austenite and ferrite were formed. Because of the larger amount of fine austenite in the reheated region, a higher impact toughness was obtained in the weld metal with a higher amount of reheated region.