• 제목/요약/키워드: Metal temperature

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저온 PEMFC용 금속분리판 코팅의 내구 특성 연구 (Coating Durability of Metal Bipolar plate for Low Temperature PEMFC)

  • 강성진;전유택
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
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    • pp.82.2-82.2
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    • 2010
  • The development of bipolar plate having high efficiency and chemical properties has a major impact on fuel cell applications commercialization. Even though graphite bipolar plate has high electric conductivity and chemical resistance, it has demerits about mass production and brittle property for commercialization. Hence, metallic bipolar plate can be substitute for fuel cell bipolar plate. Although its inadequate corrosion behavior under PEMFC environment lead to a deterioration of membrane by dissolved metal ions, metallic bipolar plate for PEMFC is more suitable for automotive and residential power generation system because of its high mechanical strength, low gas permeability and applicability to mass production. Therefore, several types of coating has been applied to prevent corrosion and oxide film growth and to achieve more high durability. This work presents durability of coated metal bipolar plate for low temperature PEMFC which made for fuel cell vehicle. This results showed surface treatment increase long-term durability, even electric conductivity and corrosion resistance.

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마그네슘합금 판재의 온간 디프 드로잉성에 관한 연구 (A Study on the Warm Deep Drawability of Mg- Alloy Sheet Metal)

  • 이용길;김종호;이종섭
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2003년도 추계학술대회논문집
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    • pp.117-120
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    • 2003
  • Warm deep drawing which is one of the new forming technologies to improve formability of sheet metal is applied to the cylindrical cup drawing of Mg-alloy sheet metal. In experiments the temperature of die and blank holder is varied from room temperature to $300^{\circ}C$, while the punch is cooled by circulation of coolant to increase the fracture strength of workpiece on the punch corner area. Test material chosen for experiments is AZ31 magnesium sheet metal. Teflon film as a lubricant is used on both sides of a workpiece. The limit drawing ratio as well as thickness distributions of drawn cups are investigated and validity of warm deep drawing process is also discussed.

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2-D Braided Textile 금속복합재료의 성형과 특성 해석 (Fabrication and Analytical Characterization of 2-D Braided Textile Metal Matrix Composites)

  • 이상관;김효준;변준형;홍순형
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2001년도 춘계학술발표대회 논문집
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    • pp.38-41
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    • 2001
  • A new 2-D braided textile metal matrix composite was developed and characterized. The constituent materials consist of PAN type carbon fiber as reinforcements and pure aluminum as matrices. The braided preforms of different braider yarn angles were fabricated. For a fixed bundle size of 12K, three braider yarn angles was selected: $30^{\circ}$, $45^{\circ}$, and $60^{\circ}$. The braided preforms were infiltrated with pure Al by vacuum assisted squeeze casting. Through the investigation of melt pressing methods and the effects of process parameters such as applied pressure, and pouring temperature, the optimal process conditions were identified as follows: applied pressure of 60MPa, pouring temperature of $800^{\circ}C$. Using the measured geometric parameters, 3-D engineering constants of metal matrix composites have been determined from the elastic model, which utilizes the coordinate transformation and the averaging of stiffened and compliance constants based upon the volume of each reinforcement and matrix material.

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역확산화염과 촉매금속 기판을 이용한 탄소 나노튜브와 나노섬유의 연소합성 (Synthesis of Carbon Nanotubes and Nanofibers on a Catalytic Metal Substrate by an Inverse Diffusion Flame)

  • 이교우;정종수;황정호
    • 한국연소학회지
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    • 제7권4호
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    • pp.21-28
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    • 2002
  • Synthesis of carbon nanotubes and nanofibers on a metal substrate by an ethylene fueled inverse diffusion flame was illustrated. Stainless steel plates were used for the catalytic metal substrate. Multi-walled carbon nanotubes and nanofibers with a diameter range of 30-80nm were found on the substrate. The temperature of the substrate played an important role in the formation of carbon nanotubes and nanofibers. The pathway to the nanotubes and nanofibers could be determined by the temperature history of the substrate.

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순수 티타늄 주조체의 주형온도에 따른 용탕반응성 및 표면거칠기 (Metal-Mold Reaction and Surface Roughness Measurement of Pure Titanium Casting Specimens with Mold Temperatures)

  • 차성수;송영주;박수철
    • 대한치과기공학회지
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    • 제32권4호
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    • pp.297-305
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    • 2010
  • Purpose: The purpose of this study was to observe the change of metal-mold reaction and surface roughness in titanium casting specimens for phosphate-silica alumina bonded investment with mold temperatures. Methods: The metal-phosphate silica alumina bonded mold interface reaction and surface roughness of titanium casting specimens according to mold temperatures were investigated. The Specimens were analysed by scanning electron microscopy and surface roughness tester. Results: The oxidation behavior indicated by the growth of oxide thickness. The titanium-oxide layer were consisted two layer of a porous external and a dense internal one. The reaction layer and surface roughness increased with increasing investment material temperature. Conclusion: In this work, The most suitable mold temperature in casting of pure titanium was $200^{\circ}C$.

혼합 금속 분말의 고온 치밀화 거동 (Densification Behavior of Mixed Metal Powders under High Temperature)

  • 조진호;김기태
    • 대한기계학회논문집A
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    • 제24권3호
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    • pp.735-742
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    • 2000
  • Densification behaviors of mixed metal powder under high temperature were investigated. Experimental data of mixed copper and tool steel powder with various volume fractions of Cu powder were obtained under hot isostatic pressing and hot pressing. By mixing the creep potentials of McMeeking and co-workers and of Abouaf and co-workers originally for pure powder, the mixed creep potentials with various volume fractions of Cu powder were employed in the constitutive models. The constitutive equations were implemented into a finite element program (ABAQUS) to compare with experimental data for densification of mixed powder under hot isostatic pressing and hot pressing. Finite element calculations by using the creep potentials of Abouaf and co-workers agreed reasonably well with experimental data, however, those by McMeeking and co-workers underestimate experimental data as observed in the case of pure metal powders.

$Si_3N_4/SM45C$ 접합부의 응력해석 및 파괴특성 (Fracture Characteristics and Stress Analysis of $Si_3N_4/SM45C$ Joint)

  • 김기성
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 1998년도 추계학술대회 논문집
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    • pp.248-253
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    • 1998
  • Recently, the uses of Ceramic/metal bonded joints, resin/metal joints, adhesive joints, composite materials which are composed of dissimiliar materials have increased in various industry fields. Since the ceramic/metal bonded joints material is made at a high temperature, residual stress distributions due to differences in material properties were investigated by varying material parameters. The two dimensional finite element analysis was performed to study residual stress distribution in Si3N4/SM45C bonded joint with a copper interlayer between the silicon nitride(Si3N4) and the structural carbon steel(SM45C) and 4-point bending tests were carried out under room temperature. Fracture surface and crack propagation path were observed using scanning electron microscope and characteristics of its fracture was discussed.

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Magnetoresistance behavior of $La_{1-\chi}Sr_\chiCoO_{3-\delta}$ films around the metal-insulator transition

  • Park, J. S.;Park, H. G.;Kim, C. O.;Lee, Y. P.;V. G. Prokhorov
    • 한국진공학회지
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    • 제12권S1호
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    • pp.100-103
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    • 2003
  • The magnetoresistance (MR) of $La_{1-\chi}S_{\chi}CoO_{3-\delta}$ films prepared by pulsed-laser deposition were investigated in order to clarify the magnetotransport properties around the metal-insulator transition. For the films in the metallic state ($\chi$ > 0.25), the MR(T) manifests a small peak at the Curie temperature due to the spin-disorder scattering. The transition of the film into the insulating state ($\chi\;\leq$ 0.25) is accompanied by an essential growth of the MR and results in a significant increase in the MR(T) with decreasing temperature, due to a phase separation into the ferromagnetic-metal clusters and the insulating matrix.

금속산화물을 이용한 이산화황과 산화질소의 동시재거( II ) -금속산화물과 이산화황의 반응- (Simultaneous Removal of SO$_2$ and NO by Using Metal Oxide( II ) -Oxidative Sorption of SO$_2$ by Metal Oxide-)

  • 신창섭
    • 한국안전학회지
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    • 제6권4호
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    • pp.26-33
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    • 1991
  • To remove SO$_2$ from flus gas, cupric oxide, manganese oxide and iron oxide were studied with varying loading value. The experiment was carried out in a flow reactor and the reactants were prepared by impregnation method using alumina. The reaction temperature was varied from 30$0^{\circ}C$ to 45$0^{\circ}C$. Experimental results showed that all of these metal oxides were effective on SO$_2$ removal reaction and cupric oxide was the best reactant. The sample with 10wt% loading value was better reactant than with 20wt% because in case of 20wt% loading, metal dispersion on the alumina surface was not uniform. And the SO$_2$ removal efficiency was increased with the reaction temperature.

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질화알루미늄과 금속간 계면접합에 관한 연구: 계면반응과 미세구조 형성이 접합체 강도에 미치는 영향 (Joining of AIN Ceramics to Metals: Effect of Reactions and Microstructural Developments in the Bonded Interface on the Joint Strength)

  • 박성계
    • 한국분말재료학회지
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    • 제4권3호
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    • pp.196-204
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    • 1997
  • Joining of AIN ceramics to W and Cu by active-metal brazing method was tried with use of (Ag-Cu)-Ti alloy as insert-metal. Joints were produced under various conditions of temperature, holding time and Ti-content in (Ag-Cu) alloy Reaction and microstructural development in bonded interface were investigated through observation and analysis by SEM/EDS, EPMA and XRD. Joint strengths were measured by shear test. Bonded interface consists of two layers: an insert-metal layer of eutectic Ag- and Cu-rich phases and a reaction layer of TiN. Thickness of reaction layer increases with bonding temperature, holding time and Ti-content of insert-metal. It was confirmed that the growth of reaction layer is a diffusion-controlled process. Activation energy for this process was 260 KJ/mol which is lower than that for N diffusion in TiN. Maximum shear strength of 108 MPa and 72 MPa were obtained for AIN/W and AIN/Cu joints, respectively. Relationship between processing variables, joint strength and thickness of reaction layer was also explained.

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