• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.610.2-610.2
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• 2006

• Transactions of the Korean hydrogen and new energy society
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• v.26 no.3
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• pp.271-277
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• 2015

The present paper discusses about noble idea on various reactions including hydrides, hydrogen peroxide and nano-sized metal powders, which do not emit toxic materials as well as carbon dioxide. Here in this paper, the very first-ever concept that heat energy can be generated from the direct reaction between sodium borohydride and hydrogen peroxide is presented. Sodium hydride as fuel can supply hydrogen reacting with oxygen provided by the decomposition of hydrogen peroxide solution. Solid sodium borohydride can be resolved in water and treated as liquid solution for the easy handling and the practical usage although its solid powder can be directly mixed with hydrogen peroxide for the higher reactivity. The thermodynamic analysis was conducted to estimate adiabatic reaction temperatures from these materials. The preliminary experiment on the reactions conducted using sodium borohydride powder and hydrogen peroxide water solution revealed that the self-propagating reaction can occur and that its reactivity increases with an increase of hydrogen peroxide concentration.

• Transactions of the Korean hydrogen and new energy society
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• v.26 no.4
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• pp.308-317
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• 2015

To investigate the effect of microstructure on the formation of the desorption peak, the volumetric thermal analysis technique (VTA) was applied to the Mg-13.5 wt% Ni hydride system. The sample made by the HCS (hydriding combustion synthesis) process had two kinds of Mg microstructures. Linear heating was started with various constant heating rates. Only one peak was appeared in the case of the small initial hydrogen wt% (0.83 wt%). Yet, two peaks were appeared with increasing initial hydrogen wt% (1.85 and 3.73 wt%) when only Mg was hydrogenated. The first peak was formed through the evolution of hydrogen from $MgH_2$, made by eutectic Mg. The second peak was formed through the evolution of hydrogen from $MgH_2$, made by primary Mg. Therefore, this result shows that the microstructure also has a considerable effect on forming the desorption peak. We have also derived the hydrogen desorption equations by VTA to get apparent activation energy when the rate-controlling step for the desorption of the hydrided system is the diffusion of hydrogen through the ${\alpha}$ phase and the chemical reaction ${\beta}{\rightarrow}{\alpha}$.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.314-314
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• 2010

For the optimal design of a tokamak-type reactor, self-consistent determination of a radial build of reactor systems is important and the radial build has to be determined by considering the plasma physics and engineering constraints which inter-relate various reactor systems. In a low aspect ratio (LAR) tokamak reactor with a superconducting toroidal field (TF) coil, the shield should provide sufficient protection for the superconducting TF coil and the shield plays a key role in determining the size of a reactor. To determine the radial build of a reactor, neutronic effects such as tritium breeding in the blanket, nuclear heating, and radiation damage to toroidal field (TF) coil has to be included in the systems analysis. In this work, the outboard blanket only is considered where tritium self-sufficiency is possible by using an inboard neutron reflector instead of breeding blanket. The reflecting shield should provide not only protection for the superconducting TF coil but also improved neutron economy for the tritium breeding in outboard blanket. Tungsten carbide, metal hydride such as titanium hydride and zirconium hydride can be used for improved shielding performance and thus smaller shield thickness. With the use of advanced technology in the shield, conceptual design of a compact superconducting LAR reactor with aspect ratio of less than 2 will be presented as a viable power plant.

• Journal of the Korean Society of Propulsion Engineers
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• v.25 no.3
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• pp.26-41
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• 2021

Titanium hydride potassium perchlorate (THPP) has played an important role as initiators of the propulsion system. However, the 'aging' may cause performance degradation and even give rise to a failure in the total system. In this study, various hygrothermal aging conditions were considered and the aging effects on thermodynamic and ignition characteristics of THPP are provided via thermal analysis and ignition measurements. Also, physical-chemical changes were identified by morphological analysis. In conclusion, thermal aging led to E_α decrease-high reactivity due to oxidizer decomposition whereas hygrothermal aging gave rise to an opposite tendency by fuel oxidation.

• 제어로봇시스템학회:학술대회논문집
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• 2005.06a
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• pp.1400-1404
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• 2005

This paper presents the temperature control of aluminum plate by using Peltier element. Peltier effect is heat pumping phenomena by electric energy as one of the thermoelectric effect. So if current is charged to Peltier element, it absorbs heat from low temperature side and emits heat to high temperature side. In this experiment, Peltier element is used to control the temperature of small aluminum plate with current control and operating cooling fan only while cooling duration. Operating cooling fan only while cooling duration is proper to get more rapid heating and cooling duration. As a result of experiment, it takes about 100sec period to repeating temperature between $35^{\circ}C$ and $70^{\circ}C$ and about 80sec from $40^{\circ}C$ to $70^{\circ}C$ in ambient air temperature $25^{\circ}C$ and while operating cooling fan only in cooling duration. Future aim is to apply this temperature control method in actuating SMHA(special metal hydride actuator) which is applicable in Siver project acting in low frequency range by using Peltier element for heating and cooling.

• Transactions of the Korean hydrogen and new energy society
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• v.7 no.2
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• pp.165-171
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• 1996

The effect of rolling on the charge-discharge property was studied for metal hydride negative electrode. $(LM)Ni_{3.6}Al_{0.4}Co_{0.7}Mn_{0.3}$(pleateau pressure : below 1 atm at room temperature, volume expansion : 9%, entalpy : $8.7kcal/molH_2$) alloy was prepared by arc melting, and then it was coated with various copper weight percent. The copper coated alloys were then rolled with the different reduction ratio. From the results, it was found that the maximum discharge capacity increased with increasing reduction ratio, and 15wt% copper coated sample shows the highest discharge capacity, 324mAh/g, after rolling with 30% reduction ratio. In view of cycle life for the negative electrode, the 15wt% copper coated electrode which was rolled with 13% reduction ratio showed the longest cycle life compared with other electrodes.

• Proceedings of the SAREK Conference
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• 2006.06a
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• pp.346-351
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• 2006

When metallic alloys are reacted to hydrogen, heat transfer of storage tank effects hydrogen storage rate and capacity. If pulsating heat pipe are used to improve heat transfer efficiency, production of hydrogen storage tank can be more simple and economical. Experiment of heat pipe was conducted by varying working fluids and heat flux. According to supply heat flux, test indicate that R-22 and R-l42b were found lower temperature difference between evaporator and condenser than R-134a and Ethanol. Thermal resistances of R-22 and R-142b were also lower than others. Using R-142b as a working fluid, heat pipe type hydrogen storage tank is tested in absorption and desorption processes.

• Bulletin of the Korean Chemical Society
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• v.16 no.2
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• pp.149-153
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• 1995

We have grown GaAs epilayers by chemical beam epitaxy(CBE) using unprecracked hydrides and metal organic compounds via a surface decomposition process. This result shows that unprecracked arsine (AsH3) or monoethylarsine (MEAs) can be used in chemical beam epitaxy(CBE) as a replacement of a precracked AsH3 source in CBE. It was also found that the uptake of carbon impurity in epilayers grown using trimethylgallium(TMG) with unprecracked AsH3 or MEAs was significantly reduced compared to that in epilayers grown by CBE process employing TMG and arsenics produced from precracked hydrides. We propose a surface structural model suggesting that the hydrogen atoms play an important role in the reduction of carbon content in GaAs epilayer. Intermediates like dihydrides from hydride sources were also considered to hinder carbon atoms from being incorporated into the epilayers or to remove other carbon containing species on the surface.

• Analytical Science and Technology
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• v.13 no.2
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• pp.151-157
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• 2000

Effects of acids and pre-reductants in the analysis of arsenic have been studied by hydride generation-atomic absorption spectrometry. The analytical results were strongly dependent on the acid concentrations. All the pre-reductants was very effective to observe the arsenic signal at strong acid concentrations (3 M-5 M). However, at the low acid condition (${\leq}0.1M$), L-cysteine only showed a reasonable effect on the absorption signal. When the sample was treated with the nitric acid, absorption signal was unstable and was also decreased. Although interference effects were observed from metal ions such as $Cr^{6+}$ and $Br^{5+}$ at low acid condition, the generation of hydride could be increased by the strong acid condition.