• Journal of the Society of Cosmetic Scientists of Korea
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• v.38 no.4
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• pp.271-276
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• 2012

In this study, the dispersion ability of powder in low viscosity solubilization system that depends on variety and amount of additives and powders was investigated. A PMMA powder shows outstanding dispersion ability because of its repulsive force of partially charged chain and low density of porous structure. A sample, which contains salts, showed better dispersion tendency than a sample without any additives. The dispersion ability was quantity of salts dependent. Furthermore, a sample with divalent ion salts, like $MgSO_4$, showed better dispersion tendency than that of monovalent ion salts, like NaCl or KCl. The reason for the better dispersion tendency was due to the existence of ionized salts around the powders which significantly improves repulsive force between powders and consequently reduces powder aggregation. The sample with chelating agent, like EDTA as an additive, had improved dispersion ability. EDTA chelates and blocks metal cation therefore anion's character is maximized and repulsive force between powders is improved. As a result, salts and EDTA help to improve the powder dispersion ability and the stability of product.

• Transactions of the Korean hydrogen and new energy society
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• v.18 no.3
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• pp.317-324
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• 2007

The conversion reaction of ortho to para hydrogen was studied. The percentage of ortho and para hydrogen is mainly dependent on the equilibrium temperature. Because this reaction is known to be accelerated by the catalyst such as nickel-silicate and ruthenium on silica, we focused in the test and development of the catalysts. We studied metal-silicates because they provide high metal dispersion on support. Nickel-silicate, ruthenium-silicate and mixed-silicate were prepared by the coprecipitation method and used in the reaction at the temperature of liquid nitrogen. The conversion was measured by the difference of thermal conductivity between reference gas and sample gas. The activation condition was important and it affected the activities of the catalysts. Nickel-silicate showed high activities. Ruthenium-silicate also showed relative high activities but mixed-silicate showed poor activities.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.142-143
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• 2006

Recently, automotive engines have changed to the silent chain system in order to reduce noise and to improve reliability. High contact fatigue strength is needed for the sprockets of silent chain system. As a result, a high-contact-fatigue-strength P/M material was developed using the technology of surface rolling, which densifies the surface layer of sintered parts. It was established that the contact fatigue strength of the developed material was a great improvement over that of the conventionally used sintered material.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.11a
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• pp.198-198
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• 2006

Tin doped $In_2O_3$ sputtering target is widely used to produce a various kinds of flat panel display because of high transmittance in visible region and high electrical conductivity. In2O3 and SnO2 powders were prepared by a homogeneous precipitation method using metal source, respectively, the calcining and sintering behavior of the indium-tin oxide(In2O3-SnO2) composite powders were studied. The tin oxide(SnO2) dispersion condition in ITO sputtering target was improved by increasing calcining temperature. And the tin oxide dispersion was also improved by reducing the tin oxide contents in the ITO target from 30 to 5wt%. SnO2 dispersion and densification of ITO target is very difficult to control due to sublimation of SnO2 at over 1150C.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.5
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• pp.390-397
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• 2010

0.5wt% Ru/$\alpha-Al_2O_3$ catalysts are prepared by deposition-precipitation method for the preferential CO oxidation In order to investigate the effect of pH on the Ru dispersion and particle size, the pH of precursor solution is adjusted to between 5.5 and 9.5. 0.5wt% Ru/$\alpha-Al_2O_3$ catalyst prepared at the pH of 6.5 has high Ru dispersion of 17.9% and small particle size of 7.7nm. In addition, 0.5wt% Ru/$\alpha-Al_2O_3$ catalyst prepared at the pH 6.5 is easily reduced at low temperatures below $150^{\circ}C$ due to high dispersion of $RuO_2$ particle and shows high CO conversion over 90% in the wide temperature range between $100^{\circ}C$ and $160^{\circ}C$. Moreover, the deposition-precipitation is a feasible method to improve the Ru dispersion as compared to the impregnation method. The 0.5wt% Ru/$\alpha-Al_2O_3$ catalyst prepared by deposition-precipitation exhibits higher CO conversion than 0.5wt% Ru/$\alpha-Al_2O_3$ catalysts prepared by impregnation due to higher metal dispersion and better reducibility at low temperature.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.76.1-76.1
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• 2015

Optical resonances of metallic or dielectric nanoantennas enable to effectively convert free-propagating electromagnetic waves to localized electromagnetic fields and vice versa. Plasmonic resonances of metal nanoantennas extremely modify the local density of optical states beyond the optical diffraction limit and thus facilitate highly-efficient light-emitting, nonlinear signal conversion, photovoltaics, and optical trapping. The leaky-mode resonances, or termed Mie resonances, allow dielectric nanoantennas to have a compact size even less than the wavelength scale. The dielectric nanoantennas exhibiting low optical losses and supporting both electric and magnetic resonances provide an alternative to their metallic counterparts. To extend the utility of metal and dielectric nanoantennas in further applications, e.g. metasurfaces and metamaterials, it is required to understand and engineer their scattering characteristics. At first, we characterize resonant plasmonic antenna radiations of a single-crystalline Ag nanowire over a wide spectral range from visible to near infrared regions. Dark-field optical microscope and direct far-field scanning measurements successfully identify the FP resonances and mode matching conditions of the antenna radiation, and reveal the mutual relation between the SPP dispersion and the far-field antenna radiation. Secondly, we perform a systematical study on resonant scattering properties of high-refractive-index dielectric nanoantennas. In this research, we examined Si nanoblock and electron-beam induced deposition (EBID) carbonaceous nanorod structures. Scattering spectra of the transverse-electric (TE) and transverse-magnetic (TM) leaky-mode resonances are measured by dark-field microscope spectroscopy. The leaky-mode resonances result a large scattering cross section approaching the theoretical single-channel scattering limit, and their wide tuning ranges enable vivid structural color generation over the full visible spectrum range from blue to green, yellow, and red. In particular, the lowest-order TM01 mode overcomes the diffraction limit. The finite-difference time-domain method and modal dispersion model successfully reproduce the experimental results.

• Journal of The Korean Astronomical Society
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• v.17 no.2
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• pp.69-103
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• 1984

Five different calibrations of metal abundances of globular clusters are examined and these are compared with metallicity ranking parameters such as $(Sp)_c$, . Q39 and IR-indices. Except for the calibration $[Fe/H]_H$ by the high dispersion echelle analysis. the other calibration scales are correlated with the morphological parameters of red giant branch. In the $[Fe/H]_H$-scale. the clusters later than ${\sim}F8$ have nearly a constant metal abundance. $[Fe/H]_H{\simeq}-1.05$, regradless of morphological characteristics of horizontal branch and red giant branch. By the two fundamental calibration scales of $[Fe/H]_L$ (derived by the low dispersion analysis) and $[Fe/H]_{{\Delta}s}$ (derived by the spectral analysis of RR Lyrae stars). the globular clusters are divided into the halo clusters with [Fe/H]<-1.0 and the disk clusters confined within the galactocentric distance ${\tau}_G=10\;kpc$ and galactic plane distance |z|=3 kpc. In this case the abundance gradient is given by d[Fe/H]/$dr_G{\approx}-0.05\;kpc^{-1}$ and d[Fe/H]/$d|z|{\simeq}-0.08\;kpc^{-1}$ within ${\tau}_G=20\;kpc$ and |z|=10 kpc, respectively. According to these characteristics of the spatial distribution of globular clusters. the chemical evolution of the galactic globular clusters can be accounted for by the two-zone (disk-halo) slow collapse model when the $[Fe/H]_L$-or $[Fe/H]_{{\Delta}s}$-scale is applied. In the case of $[Fe/H]_H$-scale, the one-zone fast collapse model is preferred for the evolution of globular clusters.