• 대한설비공학회지:설비저널
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• 제5권3호
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• pp.169-177
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• 1976

The importance of surface conditions of nucleate boiling is well recognized and it has been known that the heat transfer to boiling liquid is closely related to the bubble population density. The bubble population density should depend on various factors such as heat flux, surface roughness, surface contamination, properties of liquid, etc. In this paper the effect of surface conditions on heat transfer in nucleate boiling is treated. The experiments were carried out with distilled water boiler, on the horizontal heating surfaces, sintered with various bronze particle, under atmospheric pressure. In addition, experimental investigation for the polished bronze surface was performed. By studing a coefficient Xb defined by eq. (9), which represents the bubble foaming ability of heating surface, generalized fomula on the heat transfer in the nucleate toiling were expressed. The coefficient $X_b$, determined empirically, is not constant and indicates a major influence of the sintered metal surfaces on the $\Delta$, necessary to sustain nucleate boiling at any given heat flux. In this study, the main results are obtained as follows; (1) At low temperature difference, the coefficient $X_b$ of sintered metal surface was found to he higher than the polished surface throughout the full range of experiments. (2) The optimum sintered structure showing the maximum coefficient $X_b$ has been confirmed to exist and it is encountered when particle diameter is $256{\mu}$.

• 한국주조공학회지
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• 제16권6호
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• pp.523-536
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• 1996

This paper relates to fabrication processing analysis of metal matrix composites by the injection of liquid metal into a fibrous preforms. One dimensional heat transfer analysis during squeeze infiltration process of aluminum base composites has been studied. An analysis method was investigated for the temperature distribution, infiltration velocity and melt infiltration characteristics with the commercial preform with short fiber array. When molten metal is infiltrated in a fibrous preform with random orientation, phase transformation will be occurred in a region such as molten metal, solidified region, preform region and infiltration composites region. a mathematical modelling for a solidification phenomena in fabrication process of metal matrix composites using a squeeze infiltration technique was investigated by the basic relations for liquid metal into a fibrous preform. The temperature distribution of theoretical results was compared with experimental data.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.1388-1393
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• 2003

In this study, analytic stress-displacement solutions are obtained by using a shear lag modeling constructed for the spliced joint area with a splicing gap filled with adhesive material of elastic modulus $E_{a}$ in the fiber metal laminate (FML) which is known to have excellent fatigue, corrosion and fire-flame resistant characteristics while with relatively low densities compared to the conventional aluminum alloys for lightweight structures.

• Bulletin of the Korean Chemical Society
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• 제20권6호
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• pp.657-662
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• 1999

The variation of Jahn-Teller(J-T) distortion imposed on various metallo- tetraphenylporphyrins(MTPPS;M=ZnⅡ,PdⅡ,PtⅡ,and RhⅢ) has been investigated by time-resolved resonance Raman spectroscopy. B1g and B2g modes of the triplet(π,π*) states for the heavy-metal porphyrins exhibit the enhancement of their intensities compared with those of 3ZnⅢTPP, while the enhancement of phenyl internal mode is reduced. These results suggest that the J-T distortion becomes manifest as the metal size increases, and consequently the porphyrin-to-phenyl ring charge transfer in the excited triplet state is inhibited.

• 한국세라믹학회지
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• 제45권4호
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• pp.196-203
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• 2008

Metal-carbon/$TiO_2$ composite photocatalysts were thermally synthesized through the mixing of anatase to metal(Cu, Zn) containing phenol resin in an ethanol solvent coagulation method. The BET surface area increases, with the increase depending on the amount of metal salt used. From SEM images, metal components and carbon derived from phenol resin that contains metal was homogeneously distributed to composite particles with porosity. XRD patterns revealed that metal and titanium dioxide phase can be identified for metal-carbon/$TiO_2$ composites, however, the diffraction peaks of carbon were not observed due to the low carbon content on the $TiO_2$ surfaces and due to the low crystallinity of the amorphous carbon. The results of a chemical elemental analysis of the metal-carbon/$TiO_2$ composites showed that most of the spectra for these samples gave stronger peaks for C, O, treated metal components and Ti metal compared to that of any other elements. According to photocatalytic results, the MB degradation can be attributed to the three types of synergetic effect: photocatalysis, adsorptivity and electron transfer, according to the light absorption between the supporter $TiO_2$, metal species, and carbon layers.

• 한국재료학회지
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• 제32권12호
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• pp.522-527
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• 2022

Among efforts to improve techniques for the chemical vapor deposition of large-area and high-quality graphene films on transition metal substrates, being able to reliably transfer these atomistic membranes onto the desired substrate is a critical step for various practical uses, such as graphene-based electronic and photonic devices. However, the most used approach, the wet etching transfer process based on the complete etching of metal substrates, remains a great challenge. This is mainly due to the inevitable damage to the graphene, unintentional contamination of the graphene layer, and increased production cost and time. Here, we report the systematic study of an H₂ bubbling-assisted transfer technique for graphene films grown on Cu foils, which is nondestructive not only to the graphene film but also to the Cu substrate. Also, we demonstrate the origin of the graphene film tearing phenomenon induced by this H₂ bubbling-assisted transfer process. This study reveals that inherent features are produced by rolling Cu foil, which cause a saw-like corrugation in the poly(methyl methacrylate) (PMMA)/graphene stack when it is transferred onto the target substrate after the Cu foil is dissolved. During the PMMA removal stage, the graphene tearing mainly appears at the apexes of the corrugated PMMA/graphene stack, due to weak adhesion to the target substrate. To address this, we have developed a modified heat-press-assisted transfer technique that has much better control of both tearing and the formation of residues in the transferred graphene films.

• 한국정밀공학회지
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• 제14권4호
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• pp.72-77
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• 1997

In the temperature analysis of hot metal forming process, the heat transfer conditions between the work-piece and the tool have improtant influences upon the temperature distribution. The accuracy of thermal analysis depends on the proper description of boundary conditions including heat transfer. At the contact surface of two materials with different temperatures, this requires the knowledge of the overall heat transfer coefficient. In order to determine the overall heat transfer coefficient, a technique is developed. The technique involves temperature measurement by using thermocouples during hot upsetting operations and finite element computation. The overall heat transfer coefficient is determined using a non-linear optimization technique.

• 전력전자학회논문지
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• 제21권6호
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• pp.542-545
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• 2016

This work proposes a capacitive coupling-based wireless battery charging circuit that is built with vehicle glasses for electric vehicles. A capacitive coupling wireless power transfer offers many advantages, such as low metal impact and low energy transfer efficiency changes in accordance with changes in position. However, a large coupling capacitor is needed for high power transfer. Therefore, a new capacitive coupling-based wireless power transfer LLC resonant converter built with the glasses of an electric vehicle is proposed. The proposed converter is composed of coupling capacitors with glasses of an electric vehicle and two transformers for impedance transformation. The proposed LLC converter can transfer large power and obtain high efficiency with zero voltage switching. The validity and features of the proposed circuit is verified by experimental results with a 1.2 kW prototype.

• BMB Reports
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• 제34권6호
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• pp.551-558
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• 2001

We extended the measurable time scale of DNA dynamics to submicrosecond using a long-lifetime metal-ligand complex, $[Ru(phen)_2(dppz)]^{2+}$ (phen=1,10-phenanthroline, dppz=dipyrido[3,2-a:2',3'-c]phenazine) (RuPD), which displays a mean lifetime near 350 ns. We partially characterized the fluorescence resonance energy transfer (FRET) in calf thymus DNA from RuPD to nile blue (NB) using frequency-domain fluorometry with a high-intensity, blue light-emitting diode (LED) as the modulated light source. There was a significant overlap of the emission spectrum of the donor RuPD with the absorption spectrum of the acceptor NB. The F$\ddot{o}$rster distance ($R_0$) that was calculated from the spectral overlap was $33.4\;{\AA}$. We observed dramatic decreases in the steady-state fluorescence intensities of RuPD when the NB concentration was increased. The intensity decays of RuPD were matched the closest by a triple exponential decay. The mean decay time of RuPD in the absence of the acceptor NB was 350.7 ns. In a concentration-dependent manner, RuPD showed rapid intensity decay times upon adding NB. The mean decay time decreased to 184.6 ns at $100\;{\mu}M$ NB. The FRET efficiency values that are calculated from the mean decay times increased from 0.107 at $20\;{\mu}M$ NB to 0.474 at $100\;{\mu}M$ NB concentration. The use of FRET with a long-lifetime metal-ligand complex donor is expected to offer the opportunity to increase the information about the structure and dynamics of nucleic acids.

• 공업화학
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• 제33권6호
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• pp.618-623
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• 2022

분리판은 반응물 및 전자를 전달하고 부산물인 물과 열을 배출하며, 막전극접합체의 지지체 역할을 하는 고분자전해질 연료전지의 핵심 구성요소이다. 따라서 분리판의 유로 구조는 연료전지의 성능을 향상시키는데 중요한 역할을 한다. 본 연구에서는 압축률이 다른 구리 폼을 cathode 분리판에 적용한 25 cm² 단위 전지를 이용하여 성능 평가를 수행하였다. 금속 폼의 압축률이 증가할수록 총 저항이 감소하였으며, 특히 전하전달과 물질전달 저항이 사형 유로에 비해 크게 개선되어 중전류밀도 및 고전류밀도 영역에서 전압 손실을 줄일 수 있었다. 가압한 공기를 사용한 사형 유로 구조의 경우 연료전지의 성능이 압축한 금속 폼(S3)을 적용한 유로와 중전류밀도 영역까지는 큰 차이가 없었으나, 고전류밀도 영역에서는 유로 구조의 한계로 낮은 성능을 보였다.