• 제목/요약/키워드: Metal Phosphate

검색결과 260건 처리시간 0.028초

니켈-크롬 합금에 대한 다용도 접착 시스템의 전단결합강도 (Shear bond strength of Universal bonding systems to Ni-Cr alloy)

  • 송소연;손병화;김종엽;신상완;이정열
    • 대한치과보철학회지
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    • 제53권4호
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    • pp.295-300
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    • 2015
  • 목적: 레진과 니켈-크롬 합금의 결합력에 미치는 금속 프라이머 및 다용도 접착제의 영향에 대하여 비교 평가하고자 한다. 재료 및 방법: 실험을 위해 120개의 니켈-크롬 합금(Vera Bond 2V) 디스크를 제작하여 아크릴 레진 실린더에 포매하였다. 시편의 표면은 220 grit, 600 grit의 실리콘 카바이드지로 연마한 뒤 $50{\mu}m$의 알루미늄옥사이드 입자를 분사하여 처리하였다. 실험군은 메탈 프라이머의 적용(Metal primer II, Alloy primer, Metal & Zirconia primer, MKZ primer)과 다용도 접착 시스템(Single Bond Universal, All Bond Universal)에 따라 6개 군으로 나뉘었다. 각 시편의 중앙에 높이 2 mm, 직경 3 mm로 복합레진을 충전하였으며, 제작된 모든 시편은 $37^{\circ}C$ 증류수에서 24시간 보관하였다. 만능시험기에 시편을 위치시킨 후 1 mm/min cross head speed로 전단결합강도를 측정하였다. 통계분석은0.05의 유의수준으로 일원분산분석을 시행하였고 Tukey's multiple coMParison test로 사후검정을 하였다. 결과: Single Bond Universal, All Bond Universal, Metal Primer II 3개 군과 Alloy Primer, MKZ Primer, Metal & Zirconia Primer 3개 군 사이에 통계학적으로 유의한 차이를 보였다(P<.001). 결론: 니켈-크롬 합금에 대한 다용도 접착 시스템의 전단결합강도는 Metal Primer II를 제외한 기존의 금속 프라이머를 적용했을 때 보다 높게 나타났다. 본 실험에서 더 나아가 다용도 접착 시스템 내 실란(Silane) 포함 여부에 따른 효과를 평가할 수 있는 연구가 필요할 것이다.

Possible Glass Systems for Non-Pb Dielectric Layers, Barrier Rib and Sealant in PDP

  • Kim, Hyung-Sun;Jung, Byung-Hae
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.391-394
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    • 2003
  • It is inevitable that reconsideration of the use of lead oxides in the electronics industry be undertaken as long as detrimental effects to the environment remain. To solve this problem, many recent studies on Pb-free compositions for PDP (plasma display panel) dielectric layers and also sealing glass compositions have been made. The present study was conducted to investigate whether the alternative systems for leadfree low firing glasses, detailed below, are available for use in PDP materials. The results suggest that low-melting phosphate glasses would be suitable as an alternative material for the Pb-based dielectric layer, sealants and barrier ribs in PDP.

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솔-젤법에 의한 $Li_2O-ZrO_2-P_2O_5-SiO_2$계 유리 고체전해질의 제조와 그의 이온전도성 (Preparation of $Li_2O-ZrO_2-P_2O_5-SiO_2$ based Glassy Solid Electrolytes by Sol-Gel Process and Their Ionic Conduction)

  • 박강석;김기원;강은태
    • 한국세라믹학회지
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    • 제31권6호
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    • pp.660-670
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    • 1994
  • Transparent, crack-free dried gel monoliths with a composition of LiZr1.5Si2P2O12.5 have been synthesized by the low temperature polymerization of the Sol-Gel technique using metal alkoxides as starting materials. After initial reaction (20~40 min), each metal alkoxide closely paralleled each other during the hydrolysis reactions. The safe drying conditions of gels with no creaks the control of the shrinkage rate. The gels converted into the glass by heat treatment at 75$0^{\circ}C$. FTIR data indicated that the gels were phase separated into silicarich and phosphate-rich regions with the lithium. XRD results showed the formation of crystalline LiH2PO4. The gels dried at 15$0^{\circ}C$ or fired at 75$0^{\circ}C$ contained the residual water. The high ionic conductivity at room temperature for these gels was attributed to the motion of protons.

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Voltammetric Studies of Guanine and Its Derivatives by (TEX)$Ru(bpy)^{2+/3+}$(/TEX) Mediator on Indium Tin Oxide Electrode

  • 김진형
    • Bulletin of the Korean Chemical Society
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    • 제21권7호
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    • pp.709-711
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    • 2000
  • Oxidizing metal complex mediates the electrochemical oxidation of guanine nucleotides. This catalysis results in an enhancement in cyclic voltammograms that yield the rate constant for the oxidation of guanine by the metal complex via digital simulation. The rate constant of oxidation of guanine by Ru(bpy)3(3+) is 6.4 x 10(5)M(-1)s(-l). The rate constant and the enhanced current depend on the number of phosphate groups on the sugar of nucleotidc. Also the modified guanine bases show different oxidation rate constants following the trend guanine-5'- monophosphatc (GMP) > 8-bromo-guanine-5'-monophosphate (8-Br-GMP) > xanthosine -5'-monophosphate (XMP) > inosinc-5'-monophosphate (IMP). The guanine bases derivatized differently are all distinguishable from one another, providing a basis for studying electrochemistry of DNA and RNA and developing electrochemical biosensors.

Determination of Pd(II) and Pt(II) Metal Cyano Complexes Using Capillary Electrophoresis

  • Lee, Hue-Jin;Lee, Sang-Ho;Chung, Koo-Soon;Lee, Kwang-Woo
    • Bulletin of the Korean Chemical Society
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    • 제15권11호
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    • pp.945-949
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    • 1994
  • Mixtures of cyano complexes of palladium(II) and platinum(II) were separated by capillary electrophoresis using a fused silica capillary as a separation column and 30 mM phosphate buffer (pH 7) containing 15 wt. % acetonitrile as a running buffer. By virtue of the high ionic mobilities of the negatively charged cyano complexes of Pd(II) and Pt(II), they were separated using a cathodic injection and anodic detection scheme. The metal complexes eluted through the capillary were detected by direct UV absorption at 214 nm. A linear relationship between peak area and concentration was obtained for both ions and the detection limit was lower than $10^{-14}$ mole. The proposed method was applied to real sample, e.g., anode slime obtained from an electrolytic copper refinary, as a method for the simultaneous determination of palladium and platinum.

소성된 Mg-Al Layered Double Hydroxide에 의한 비소(V)의 흡착 (Sorption of Arsenate by the Calcined Mg-Al Layered Double Hydroxide)

  • 서영진;강윤주;최정;김준형;박만
    • 한국토양비료학회지
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    • 제41권6호
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    • pp.369-373
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    • 2008
  • Mg-Al LDH를 이용하여 수용액중 비소와의 반응특성을 규명하고 비소 제거제로서 활용가능성을 규명하기 위하여 비소의 흡착특성, 제거효율 및 제거기작에 대한 조사를 하였다. Mg-Al LDH는 소성(calcination)에 의한 탈수로 Mg oxide 형태를 나타내었고 비소를 흡착시킨 결과 반응 22시간 이후에 흡착평형에 도달하였으며 흡착량은 약 530 mmol/kg정도였다. 반응농도별 LDH의 등온흡착은 L-type의 흡착반응을 나타내었다. 소성된 Mg-Al LDH는 용액중에서 재수화(rehydration) 될 때 비소가 LDH의 구조의 복구과정(reconstruction)에서 이온교환 반응에 의해 층간삽입이 일어나는 것으로 나타났다. LDH에 대한 arsenate와 phosphate, arsenate와 sulfate의 경쟁흡착 결과 arsenate와 phosphate의 선택성은 비슷한 편이었고, arsenate는 sulfate에 비해 선택성이 우수하였다. 따라서 calcined Mg-Al LDH는 비교적 높은 비소 제거효율을 나타내므로 비소 제거제로서 사용 가능성이 매우 높은 것으로 판단된다.

시판식품에서 분리된 단백분해성이 강한 Streptococcus sp.의 특성 (Characterization of Proteolytic Streptococcus sp. Isolated from Market Foods)

  • 장동석;이종선
    • 한국수산과학회지
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    • 제16권3호
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    • pp.225-230
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    • 1983
  • 본 연구는 단백질 분해성이 강한 세균을 분리하고 그 균의 특성과 균이 생성하는 효소의 성질을 알기 위하여 시판식품 즉 ground beef, cooked shrimp meat, perch fillet, oyster meat, beef with textured vegetable protein, fish digest 등에서 세균을 분리하였다. 분리된 740균주중에서 $30.8\%$에 해당하는 228균주가 단백질 분해성이 있었으며 이 중에서 단백질 분해성이 제일 강한 균주는 Streptococcus sp.였다. 본 균주는 배지에 $KH_{2}PO_4\;0.15\%,\;K_{2}HPO_4\;0.4\%$를 첨가하여 $37^{\circ}C$에서 6시간 배양했을 때 maximum growth에 도달하였고 균체외 단백질 분해효소의 활성은 배양 7시간경에 최고에 달하였다. 그리고 본 Streptococcus sp.가 생성한 균체외 단백분해효소는 EDTA나 o-phenanthroline에 강한 조해작용을 받고 phenylmethylsulfonylfluoride나 p-hydroxymercuribenzoate에 영향을 받지 않는 metal-chelator sensitive protease임을 알 수 있었다.

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Interaction of Ruthenium(II)[(1,10-phenanthroline)2benzodipyrido[3,2-a:2',3'-c]-phenazine]2+ with Single Stranded Poly(dA) and Poly(dT): Turning off the Light Switch

  • Lee, Jeong-Mi;Choi, Ji-Yoon;Kim, Jong-Moon;Lee, Sang-Yong;Lee, Hyo-Sun;Kim, Seog-K.;Cho, Tae-Sub
    • Bulletin of the Korean Chemical Society
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    • 제28권6호
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    • pp.965-969
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    • 2007
  • The spectral properties, namely the circular dichroism, electric absorption and luminescence properties, of Λ- and Δ-[Ru(II)(1,10-phenanthroline)2benzodipyrido[b:3,2-h:2',3'-j]phenazine]2+ ([Ru(phen)2BDPPZ]2+) in the presence and absence of single stranded poly(dA) and poly(dT) were compared in this work. In the presence of single stranded DNAs, hypochromism in the absorption spectrum and significant changes in the circular dichroism spectrum in the ligand absorption band were apparent, indicating the strong interaction of the [Ru(phen)2BDPPZ]2+ complex with the single stranded DNAs. The luminescence intensity of the Ru(II) complex decreased stoichiometrically with increasing concentrations of the single stranded DNAs. All of these spectral changes were independent of the configuration of the Ru(II) complex and the nature of the DNA bases. Therefore, it is conceivable that both enantiomers of the [Ru(phen)2BDPPZ]2+ complex interact electrostatically with the negatively charged phosphate groups of DNA. However, the spectral properties of [Ru(II)(1,10-phenanthroline)3]2+ were not altered even in the presence of single stranded DNAs. Therefore, the size of the ligand involved in the interaction of the metal complex with the phosphate group of DNA may play an important role, even when the nature of the interaction is electrostatic.