• Title/Summary/Keyword: Metal Impurity

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Self-consistent electronic structure of impurities using the recursion method

  • Park, Jin-Ho;Cho, Hwa-Suck;Lee, Gun-Woo
    • Journal of Korean Vacuum Science & Technology
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    • v.2 no.1
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    • pp.13-19
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    • 1998
  • We have calculated the electronic structure of impurity atoms in metal host by using the tight binding model in the recursion method. For a self-consistent calculation, we assumed that the effect of impurity introduction was localized only at the impurity site and its neighbours. We calculated the Madelung term by limiting the contribution to Vm of the charge perturbations to the first shell around the impurity with Evjen technique. The calculated local density of states and charge transfer values have been compared with the experimental values for a single impurity in metal host. We fund that d-reso-nance state came from the repulsive interaction between impurity d-state and host band, and the position of d-resonance state depended on the difference of valence electrons between the host and the impurity. the results also showed that the charge transfer value between an impurity and host metal was comparable to the ionicity difference between them.

Analysis of Electric Fields Inside GIS with a Small Void in Spacer or with a Metal Impurity (고체 절연체 내부 공극 또는 금속 이물질 존재시의 GIS 내부의 전계 해석)

  • Min, Seok-Won;Kim, Yong-Jun;Kim, Eung-Sik
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.6
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    • pp.346-353
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    • 2000
  • In this paper, we developed 3 dimensional Surface Charge Method which could calculate electric fields inside GIS with a small void in solid insulator or with a metal impurity. We find a metal impurity makes much more non-uniform electric field distribution inside GIS than a small void. We also find electric field is much more increased when a metal impurity is close to solid insulator surface at high voltage conductor.

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Analysis of Electric Fields Inside GIS With Metal Impurity Using 3 Dimensional Surface Charge Method (일반 3차원 표면전하법을 이용한 금속 이물질이 유입된 GIS 내부의 전계 해석)

  • Kim, Y.J.;Min, S.W.;Kim, E.S.
    • Proceedings of the KIEE Conference
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    • 1999.07e
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    • pp.2117-2119
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    • 1999
  • In this paper, the electric fields inside GIS with metal impurity is analysed by the use of 3 dimensional Surface Charge Method. We find the metal impurity makes electric field distribution inside GIS non-uniform and causes breakdown of $SF_6$ gas in GIS.

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Analysis of Electric Fields Distribution Inside Optimal Model GIS with a Metal Impurity or a Void (최적화 모형의 고체 절연체 내부 공극 또는 금속 이물질 존재시의 GIS 내부 전계 분포 해석)

  • Min, Seok-Won;Song, Gi-Hyeon;Kim, Eung-Sik
    • The Transactions of the Korean Institute of Electrical Engineers A
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    • v.51 no.11
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    • pp.585-590
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    • 2002
  • In this paper, the 3 dimensional surface charge method is applied to calculate electric fields distribution inside a general and an optimal model of GIS with a metal impurity and a void respectively. We know the optimal model can reduce tangential electric fields at solid insulator surface to 70% of the general model and infulence fields distribution near a metal impurity. Meanwhile, we find the optimal model does not decrease field distribution inside a void in the insulator.

A study on the effect of material impurity concentration on radioactive waste levels for plans for decommissioning of nuclear power plant

  • Gilyong Cha;Minhye Lee;Soonyoung Kim;Minchul Kim;Hyunmin Kim
    • Nuclear Engineering and Technology
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    • v.55 no.7
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    • pp.2489-2497
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    • 2023
  • Co and Eu impurities in the SSCs are nuclides that dominantly influence the neutron-induced radioactive inventory in metal and concrete radwastes (radioactive wastes) during NPP decommission. The impurity concentrations provided by NUREG/CR-3474 were used for the practical range of Co and Eu impurity concentrations to be applied to the code calculations. Metal structures near the core were evaluated to be ILW (intermediate-level waste) for the whole range of Co impurity concentration, so the boundary line between ILW and LLW (low-level waste) has no change for the whole concentration range provided by NUREG/CR-3474. Also, the boundary line between VLLW (very low-level waste) and CW (clearance waste) in the concrete shield could alter a little depending on the Eu impurity concentration within the range provided by NUREG/CR-3474. From this work, it is found that the concentration of material impurities of SSCs gives no critical impact on determining radwaste levels.

IR Edge and Oxide Impurity Absorption in Heavy Metal Fluoride Glasses (플루오르화중금속 유리의 적외선에지 및 산화물(불수물) 흡수)

  • 정기호
    • Journal of the Korean Ceramic Society
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    • v.22 no.3
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    • pp.29-34
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    • 1985
  • The IR spectra of he heavy metal fluoride glasses showed peaks at $1, 400cm^{-1}$ or $1, 100cm^{-1}$ due to metal oxyfluoride impurities. The intensity of this band and hence the oxide impurity content of the glass could be reduced considerably by the use of reactive atmosphere melting under $CCl_4$ In comparison with the fundamental IR absorption band of heavy metal oxides the oxide impurity bands observed in the heavy metal fluoride glasses are multiphonon bands due to a 2-phonon absorption process. The envelope of the a vs. v curve beyond thue fundamental region shows the exponential fall off of a with increasing v-typical of intrinsic multiphonon absorption. In the multiphonon region the amount of structure is intermediate between that observed for covalent solids and that for ionic solids.

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The Metal Detection using Primary Current in Contact-less Power Supply (무접점 전원공급 시 1차측 전류를 이용한 금속 물질 검출에 관한 연구)

  • Kim, Yu-Seok;Yu, Joo-Hee;Kim, Choon-Sam;Sung, Won-Ki
    • The Transactions of the Korean Institute of Power Electronics
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    • v.17 no.5
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    • pp.445-452
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    • 2012
  • The impurity detection method applied to existing discriminated the normality(R, L, C) and impurity(Metal) load using mutual RFID/ID method in the contactless power supply in which the primary side and the secondary side are completely separation by using the contactless transformer. However, this kind of system is caused the high cost of the system and complexity of control. Therefore, in this paper was proposed the contact-less power transfer using the primary current that determine normality or impurity load by compare the primary current Amplitude to reference quantity value and design the 3[W] contact-less power transfer and conduct an experiment for demonstrate the validity.

Effects of Metal Impurtities in Insulation of Distribution Cables on Electrical Conduction of Distribution Cables (배전 케이블의 절연체내 불순물이 전기전도도에 미치는 영향)

  • 이우선;김남오;정용호;최재곤;김형곤;김상준
    • Electrical & Electronic Materials
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    • v.10 no.5
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    • pp.447-452
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    • 1997
  • Effects of metal impurities in insulation of distribution cables on electrical conduction of distribution cables was investigated. Samples of Al, Cu, Fe are fabricated as metallic impurities, and measured electrical conductivity in the voltage range of 0~10 KV. Temperature dependent effect of hysteresis curves and the relationship between forward and reverse current due to impurity content are discussed.

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Study on the Surface Morphology and Control of Impurity by Organic Additive for Tin electro-refining (주석 전해정련에서 유기첨가제에 따른 표면형상 및 전해불순물 제어에 관한 연구)

  • Park, Sung Cheol;Son, Seong Ho;Kim, Yong Hwan;Han, Chul Woong;Lee, Ki-Woong
    • Resources Recycling
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    • v.25 no.4
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    • pp.49-53
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    • 2016
  • The electro-refining process was performed to purify the casted tin crude metal from waste tin in methanesulfonic acid. The surface morphologies of electrodeposited tin on cathode were observed, the dendrite and delamination were inhibited by glycol group of organic additive. The impurity concentrations of tin crude metal and deposited metal were analyzed using ICP-OES. Quantitative analysis on casted tin crude metal showed that it consists of tin with 97.280 wt.% and several impurity metals of Ag, Cu, Pb, Ni, and etc. After tin electro-refining, the purity of tin increased up to 99.956 wt.%. Reduction current by cyclic voltammetry seems to be closely related to behavior of impurity in tin electro-refining.

A Study on Reusable Metal Component as Burnable Absorber Through Monte Carlo Depletion Analysis

  • Muth, Boravy;Alrawash, Saed;Park, Chang Je;Kim, Jong Sung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.4
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    • pp.481-496
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    • 2020
  • After nuclear power plants are permanently shut down and decommissioned, the remaining irradiated metal components such as stainless steel, carbon steel, and Inconel can be used as neutron absorber. This study investigates the possibility of reusing these metal components as neutron absorber materials, that is burnable poison. The absorption cross section of the irradiated metals did not lose their chemical properties and performance even if they were irradiated over 40-50 years in the NPPs. To examine the absorption capability of the waste metals, the lattice calculations of WH 17×17 fuel assembly were analyzed. From the results, Inconel-718 significantly hold-down fuel assembly excess reactivity compared to stainless steel 304 and carbon steel because Inconel-718 contains a small amount of boron nuclide. From the results, a 20wt% impurity of boron in irradiated Inconel-718 enhances the excess reactivity suppression. The application of irradiated Inconel-718 as a burnable absorber for SMR core was investigated. The irradiated Inconel-718 impurity with 20wt% of boron content can maintain and suppress the whole core reactivity. We emphasize that the irradiated metal components can be used as burnable absorber materials to control the reactivity of commercial reactor power and small modular reactors.