• Journal of Korean Vacuum Science & Technology
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• 제2권1호
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• pp.13-19
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• 1998

We have calculated the electronic structure of impurity atoms in metal host by using the tight binding model in the recursion method. For a self-consistent calculation, we assumed that the effect of impurity introduction was localized only at the impurity site and its neighbours. We calculated the Madelung term by limiting the contribution to Vm of the charge perturbations to the first shell around the impurity with Evjen technique. The calculated local density of states and charge transfer values have been compared with the experimental values for a single impurity in metal host. We fund that d-reso-nance state came from the repulsive interaction between impurity d-state and host band, and the position of d-resonance state depended on the difference of valence electrons between the host and the impurity. the results also showed that the charge transfer value between an impurity and host metal was comparable to the ionicity difference between them.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제49권6호
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• pp.346-353
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• 2000

In this paper, we developed 3 dimensional Surface Charge Method which could calculate electric fields inside GIS with a small void in solid insulator or with a metal impurity. We find a metal impurity makes much more non-uniform electric field distribution inside GIS than a small void. We also find electric field is much more increased when a metal impurity is close to solid insulator surface at high voltage conductor.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 하계학술대회 논문집 E
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• pp.2117-2119
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• 1999

In this paper, the electric fields inside GIS with metal impurity is analysed by the use of 3 dimensional Surface Charge Method. We find the metal impurity makes electric field distribution inside GIS non-uniform and causes breakdown of $SF_6$ gas in GIS.

• 대한전기학회논문지:전력기술부문A
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• 제51권11호
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• pp.585-590
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• 2002

In this paper, the 3 dimensional surface charge method is applied to calculate electric fields distribution inside a general and an optimal model of GIS with a metal impurity and a void respectively. We know the optimal model can reduce tangential electric fields at solid insulator surface to 70% of the general model and infulence fields distribution near a metal impurity. Meanwhile, we find the optimal model does not decrease field distribution inside a void in the insulator.

• Nuclear Engineering and Technology
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• 제55권7호
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• pp.2489-2497
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• 2023

Co and Eu impurities in the SSCs are nuclides that dominantly influence the neutron-induced radioactive inventory in metal and concrete radwastes (radioactive wastes) during NPP decommission. The impurity concentrations provided by NUREG/CR-3474 were used for the practical range of Co and Eu impurity concentrations to be applied to the code calculations. Metal structures near the core were evaluated to be ILW (intermediate-level waste) for the whole range of Co impurity concentration, so the boundary line between ILW and LLW (low-level waste) has no change for the whole concentration range provided by NUREG/CR-3474. Also, the boundary line between VLLW (very low-level waste) and CW (clearance waste) in the concrete shield could alter a little depending on the Eu impurity concentration within the range provided by NUREG/CR-3474. From this work, it is found that the concentration of material impurities of SSCs gives no critical impact on determining radwaste levels.

• 한국세라믹학회지
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• 제22권3호
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• pp.29-34
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• 1985

The IR spectra of he heavy metal fluoride glasses showed peaks at $1, 400cm^{-1}$ or $1, 100cm^{-1}$ due to metal oxyfluoride impurities. The intensity of this band and hence the oxide impurity content of the glass could be reduced considerably by the use of reactive atmosphere melting under $CCl_4$ In comparison with the fundamental IR absorption band of heavy metal oxides the oxide impurity bands observed in the heavy metal fluoride glasses are multiphonon bands due to a 2-phonon absorption process. The envelope of the a vs. v curve beyond thue fundamental region shows the exponential fall off of a with increasing v-typical of intrinsic multiphonon absorption. In the multiphonon region the amount of structure is intermediate between that observed for covalent solids and that for ionic solids.

• 전력전자학회논문지
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• 제17권5호
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• pp.445-452
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• 2012

The impurity detection method applied to existing discriminated the normality(R, L, C) and impurity(Metal) load using mutual RFID/ID method in the contactless power supply in which the primary side and the secondary side are completely separation by using the contactless transformer. However, this kind of system is caused the high cost of the system and complexity of control. Therefore, in this paper was proposed the contact-less power transfer using the primary current that determine normality or impurity load by compare the primary current Amplitude to reference quantity value and design the 3[W] contact-less power transfer and conduct an experiment for demonstrate the validity.

• E2M - 전기 전자와 첨단 소재
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• 제10권5호
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• pp.447-452
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• 1997

Effects of metal impurities in insulation of distribution cables on electrical conduction of distribution cables was investigated. Samples of Al, Cu, Fe are fabricated as metallic impurities, and measured electrical conductivity in the voltage range of 0~10 KV. Temperature dependent effect of hysteresis curves and the relationship between forward and reverse current due to impurity content are discussed.

• 자원리싸이클링
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• 제25권4호
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• pp.49-53
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• 2016

주석 폐자원으로부터 회수된 주석 조금속을 메탄술폰산 전해액에서 전해정련을 수행하여 고순도 주석을 회수하고자 하였다. 전해정련층 표면형상을 관찰한 결과 주석 전해정련 시 glycol계 유기첨가제를 통해 균일하게 주석이 전착되었고, 수지상 형상 및 박리현상은 발생하지 않았다. 주석 조금속 및 전해정련층의 순도를 ICP-OES로 분석한 결과 주석 조금속은 은, 구리, 납, 니켈 등의 불순물이 함유되어 97.280 wt.%의 주석순도를 나타내었고, 전해정련을 수행 후 순도 분석결과 주석의 순도는 99.956 wt.%으로 증가하였다. 순환 전압전류 시험결과 유기첨가제는 주석 전해정련 시 불순물의 환원반응을 억제 또는 가속시키는 역할을 하는 것으로 판단된다.

• 방사성폐기물학회지
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• 제18권4호
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• pp.481-496
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• 2020

After nuclear power plants are permanently shut down and decommissioned, the remaining irradiated metal components such as stainless steel, carbon steel, and Inconel can be used as neutron absorber. This study investigates the possibility of reusing these metal components as neutron absorber materials, that is burnable poison. The absorption cross section of the irradiated metals did not lose their chemical properties and performance even if they were irradiated over 40-50 years in the NPPs. To examine the absorption capability of the waste metals, the lattice calculations of WH 17×17 fuel assembly were analyzed. From the results, Inconel-718 significantly hold-down fuel assembly excess reactivity compared to stainless steel 304 and carbon steel because Inconel-718 contains a small amount of boron nuclide. From the results, a 20wt% impurity of boron in irradiated Inconel-718 enhances the excess reactivity suppression. The application of irradiated Inconel-718 as a burnable absorber for SMR core was investigated. The irradiated Inconel-718 impurity with 20wt% of boron content can maintain and suppress the whole core reactivity. We emphasize that the irradiated metal components can be used as burnable absorber materials to control the reactivity of commercial reactor power and small modular reactors.