• 분석과학
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• 제11권4호
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• pp.235-242
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• 1998

이온 운반 물질로 키틴(poly-[$1{\rightarrow}4$]-${\beta}$-acetyl-D-glucosamine)을 사용하고, 지지체(matrix)로 Poly(vinyl chloride)(PVC)를, 가소제로는 Dioctyl sebacate(DOS)를 사용하여 키틴 막 전극을 제작하였다. 얇은 조각 형태의 키틴을 막자사발로 갈아 100 메시(mesh)의 체에 거른 후, 이때 모아진 일정 크기의 미세 가루를 사용하였다. 키틴 막 전극을 지시 전극으로 사용하여 금속 양이온들의 감응전위를 알아본 결과, 특히 $Cd^{2+}$와 $Cu^{2+}$에 대한 감응전위를 기울기(mV/decade)는 바탕 전해질이 pH 4 acetate buffer에서 각각 34.9 mV/decade, 34.0 mV/decade로 다른 금속 양이온들에 비하여 크게 나타났다. 또한 pH 영향을 조사해 본 결과, pH 2~12 범위에서 전위값이 일정하게 유지되었다.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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• pp.107-112
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• 2002

Ferritic stainless steels would be the most important alloys under the chloride environment. They are a cheaper alternative to austenitic stainless steels [1]. The present study is related to gas tungsten arc welding (GTAW) characteristics of Type 444 stainless steels. The heat of welding leads to grain coarsening in the HAZ and in the weld metal of ferritic stainless steels because they solidify directly from the liquid to the ferritc phase without any intermediate phase transformation. It is therefore recommended that these alloys be welded with a low heat input and at high welding speeds. Attempts to improve weldability were made by using of direct current straight polarity (DCSP) and pulsed current GTAW processes in this study. Measuring weld bead, grain size and Erichsen test were performed and the effects of heat input, pulse frequency on the weld metal and HAZ were studied. The main results were obtained as followings: decreasing heat input was effective to control the width of weld both in DCSP welding and in pulsed current welding; pulsed current welding was found to refine the grain size effectively and the finest grain size was found at the frequency of 150Hz in pulsed current welding; it was found that decreasing heat input also refine the HAZs effectively and the frequency had no different effect on HAZ at the same heat input; the ductility could be improved effectively in pulsed current welding.

• Bulletin of the Korean Chemical Society
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• 제29권10호
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• pp.1920-1926
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• 2008

We investigated the C-H bond activation mechanism of aldimine by the [RhCl$(PPH_3)_3$] model catalyst using DFT B3LYP//SBKJC/6-31G*/6-31G on GAMESS. Due to their potential utility in organic synthesis, C-H bond activation is one of the most active research fields in organic and organometallic chemistry. C-H bond activation by a transition metal catalyst can be classified into two types of mechanisms: direct C-H bond cleavage by the metal catalyst or a multi-step mechanism via a tetrahedral transition state. There are three structural isomers of [RhCl$(PH_3)_2$] coordinated aldimine that differ in the position of chloride with respect to the molecular plane. By comparing activation energies of the overall reaction pathways that the three isomeric structures follow in each mechanism, we found that the C-H bond activation of aldimine by the [RhCl$(PH_3)_3$] catalyst occurs through the tetrahedral intermediate.

• Fibers and Polymers
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• 제5권1호
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• pp.1-5
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• 2004

The ability of inherently conducting polymer (ICP) coated textiles to recover gold metal from aqueous solutions containing $[AuCl_4]^-$ was investigated. Nylon-lycra, nylon, acrylic, polyester and cotton were coated with a layer of polypyrrole (PPy) doped with 1,5-naphthalenedisulfonic acid (NDSA), 2-anthraquinonesulfonic acid (AQSA) or p-toluenesulfonic acid (pTS). Textiles coated with polyaniline (PAn) doped with chloride were also used. The highest gold capacity was displayed by PPy/NDSA/nylon-lycra, which exhibited a capacity of 115 mgAu/g coated textile, or 9700 mgAu/g polymer. Varying the underlying textile substrate or the ICP coating had a major effect on the gold capacity of the composites. Several ICP coated textiles recovered more than 90 % of the gold initially present in solutions containing 10 ppm $[AuCl_4]^-$ and 0.1 M HCl in less than 1 min. Both PPy/NDSA/nylon-lycra and PAn/Cl/nylon-lycra recovered approximately 60 % of the gold and none of the iron present in a solution containing 1 ppm $[AuCl_4]^-$, 1000 ppm $Fe^{3+}$ and 0.1 M HCl. The spontaneous and sustained recovery of gold metal from aqueous solutions containing $[AuCl_4]^-$ using ICP coated textiles has good prospects as a potential future technology.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집
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• pp.375-378
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• 2002

We investigated the reduction of etching damage by additive O$_2$ in etching gas and recovery of etching damage by O$_2$ annealing. The PZT thin films were etched using additive Ar or O$_2$ into Cl$_2$/CF$_4$ gas mixing ratio of 8/2. In order to recover ferroelectric properties of PZT thin films after etching, the etched PZT thin films were annealed at 600 C in O$_2$ atmosphere for 10 min. The remanent polarization is decreased seriously and fatigue is accelerated in the PZT sample etched in Ar/(C1$_2$+CF$_4$) plasma, whereas these characteristics are improved in O$_2$/(Cl$_2$/CF$_4$). From x-ray photoelectron spectroscopy (XPS) analysis, the intensities of Pb-O, Zr-O and Ti-O peaks are changed and the etch byproducts such as metal chloride and metal fluoride are reduced by O$_2$ annealing. From electron probe micro analyzer (EPMA) and auger electron spectroscopy(AES), O$_2$ vacancy is observed after etching. In x-ray diffraction (XRD), the structure damage in the additive O$_2$ into C1$_2$/CF$_4$ is reduced and the improvement of ferroelectric behavioral annealed sample is consistent with the increase of the (100) and (200) PZT peaks.

• 전기화학회지
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• 제10권3호
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• pp.179-183
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• 2007

The corrosion behavior of metal covered with mortar under a wet-dry cyclic condition were investigated to apply for the measurement of corrosion rates of reinforcing steel in concrete structure. The carbon steel in mortar having t=3 mm cover thickness was exposed to the alternate condition of 6 h immersion in chloride containing solution and 18 h drying at $25^{\circ}C$ and 50%RH. The electrochemical phenomena of a carbon steel and mortar interface was explained by an equivalent circuit consisting of a solution resistance, a charge transfer resistance and a CPE(Constant Phase Element). The corrosion rates were monitored continuously during exposure using an AC impedance technique. Simultaneously, the current distribution over the working electrode during impedance measurement was analyzed from the phase shift, $\theta$, in an intermediate frequency. The result showed that corrosion rate monitoring using an AC impedance method is suitable under the given exposure conditions even during the drying period when the metal is covered with the wetted mortar.

• Bulletin of the Korean Chemical Society
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• 제35권7호
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• pp.2109-2113
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• 2014

Solvent extraction of Fe(III) from chloride solution by using a mixture of D2EHPA (Di-(2-ethylhexyl)-phosphoric acid) and TBP (Tri-butyl phosphate) and the reductive stripping of Fe(III) from the loaded organic were investigated. Quantitative extraction of Fe(III) from the solution (Fe concentration = 90 g/L) was accomplished in two cross-current extraction stages by using the mixture of D2EHPA and TBP. In order to facilitate the stripping efficiency, a reductive stripping method was employed by using $H_2SO_3$ or $Na_2SO_3$ as a reducing agent. The addition of $H_2SO_4$ into reducing agents led to improvement in the stripping efficiency while high concentration acid would suppress it. Both of the mixtures of $H_2SO_4+H_2SO_3$ and $H_2SO_4+Na_2SO_3$ showed good efficiency for the stripping of Fe(III), while the latter was recommended as the stripping solution based on the economics and experimental condition.

• 전기화학회지
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• 제7권4호
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• pp.179-182
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• 2004

The aim of this study is to investigate the initiation and propagation of crevice corrosion for ferritic stainless steel in artificial crevice based on micro capillary tube method. The 430 stainless steel in artificial crevice is potentiostatically polarized in different sodium chloride solutions. Potentiodynamic and potentiostatic polarization data were measured in situ. The potentials in the crevice were measured by depth profile using the 0.04 mm diameter micro capillary tube inserted in the crevice. The potentials in the crevice ranged from -220 mV to -360 mV vs SCE from opening to bottom of crevice, which are lower than the external surface potential, -200 mV vs SCE. Such a potential drop induced the change of the metal surface state from passive to active. The surface of metal is located in passive state in -200 mV but the inner surface keeps active state below -220 mV, Thus these results show that the It drop mechanism in the crevice was more objective for evaluation and the method was easier to reproduce. Therefore the potential drop is one of the reasons for crevice corrosion by measuring the potentials in narrow crevice with a new micro measuring system.

• Bulletin of the Korean Chemical Society
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• 제26권6호
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• pp.882-886
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• 2005

Copper(II) ion-selective PVC membrane electrode based on 2-mercaptobenzoxazole as a new ionophore and o-nitrophenyl octyl ether (o-NPOE) as plasticizer is proposed. This electrode revealed good selectivity for $Cu^{2+}$ over a wide variety of other metal ions. Effects of experimental parameters such as membrane composition, nature and amount of plasticizer, and concentration of internal solution on the potential response of $Cu^{2+}$ sensor were investigated. The electrode exhibits good response for $Cu^{2+}$ in a wide linear range of 5.0 ${\times}$ 10−.6-1.6 ${\times}$ $10^{-2}$ mol/L with a slope of 29.2 ${\pm}$ 2.0 mV/decade. The response time of the sensor is less than 10 s, and the detection limit is 2.0 ${\times}$ $10^{-6}$ mol/L. The electrode response was stable in pH range of 4-6. The lifetime of the electrode was about 2 months. The electrode revealed comparatively good selectivities with respect to many alkali, alkaline earth, and transition metal ions.

• Bulletin of the Korean Chemical Society
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• 제25권10호
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• pp.1465-1470
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• 2004

A short and efficient synthesis, solvent extraction and potentiometric measurements of new thiazole-containing naphtho-crown ethers are reported. The naphthalene moiety enhances the ammonium ion selectivity over potassium ion. The selectivity of ${NH_4}^+/K^+$ follows the trend $3\;{\approx}\;2\;>\;1$, indicating that the differences in conformational changes of 2 and 3 in forming ammonium complexes affect little on the resulting ammonium/potassium extraction selectivity ratio. The ammonium ion-selective electrodes were prepared with noctylphenyl ether plasticized poly(vinyl chloride) membranes containing 1-4 the effect of one naphthalene unit introduced on either right (2) or left (3) side of thiazolo-crown ether on their potentiometric properties (e.g., ammonium ion selectivity over other cations, response slopes, and detection limits) were not apparent. However, the ammonium ion selectivity of 1, 2 and 3 over other alkali metal and alkaline earth metal cations is 10-100 times higher than that of nonactin.