• 제목/요약/키워드: Mercury emission

검색결과 87건 처리시간 0.027초

대기배출원의 수은배출특성 연구 (Emission characteristics of Mercury in Air Emission Sources)

  • 이대균;홍지형;석광설;이석조;이덕길;최덕일;박지현;장세경
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2003년도 춘계학술대회 논문집
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    • pp.324-324
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    • 2003
  • 국내의 수은 배출특성에 대하여는 소수의 연구자들이 환경대기 중 배출특성에 대하여 연구결과를 제시하고 있으나 실제로 어떤 배출원에서 얼마만한 양의 수은이 방출되는지, 또한 배출원에서의 수은의 형태나 거동 등 어떠한 특성을 가지는지에 대한 관련 연구는 수은 분석방법이 까다로운데다가 방법들간(흡광광도법, EPA 101A, 온타리오법 등)에 차이가 있고 미량분석이 갖는 어려움으로 거의 이루어지지 않고 있는 실정이다. (중략)

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우리나라 일부연안 해산 어류 중의 중금속 함량에 관한 연구 (A Study on the Content of Heavy Metals of Marine Fish in Korean Coastal water)

  • 성덕화;이용욱
    • 한국식품위생안전성학회지
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    • 제8권4호
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    • pp.231-240
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    • 1993
  • This study was carried out to find out the content of injurious heavy metals, such as mercury, lead, cadmium and arsenic of marine fish which had been captured in adjacent sea of Korea. From March, 1 to April, 30 in 1993. 60 sample of fishes were collected the adult fish and young fish. These samples were analyzed by the Mercury Analyzer and Inductively Coupled Plasma Emission Spectro Analyzer. The results of the study were summarized as follows: (1) The content of mercury in Therafra chalcograma was 0.112$\pm$0.034 ppm which was higher than other fishes, but Pseudosciaena manchurica and Pampus argenteus had lower (P<0.05). Although lead content of Trichiurus lepturus was 0.359$\pm$0.056 ppm, which was higher than other fishes. The lead content of Theragra chalcograma had lower to the almost same level. The cadmium content of the Theragra chalcograma was 0.069$\pm$0.010 ppm which was higher than other samples, but Pseudosciaena manchurica had 0.039$\pm$0.020 ppm to lower level. Though there was some fluctuation in the arsenic content which was 0.433~3.752 ppm, the arsenic content of Therafra chalcograma was 3.752$\pm$2.873 ppm which was the higher than any other fishes. But there are not statistical significances. (2) Heavy metal content by the maturity of the fishes: Mercury content of the old Pseudosciaena manchurica was 0.055$\pm$0.15 ppm comparing to the young's result of 0.030$\pm$0.009 ppm (P<0.05). Though there were some differences according to the maturity, but thee was no statistical significance. (3) In view of the correlation of the heavy metal content, for Pseudosciaena manchurica, high correlation was founded to r=0.6437 between mercury and cadmium (P<0.05). Though the content of mercury, arsenic cadmium and lead had positive correlation (r=0.2725) and negative correlation (r=-0.3958), but there was no significance at all. The other fishes were not found correlation between the heavy metal content. Positive correlation was found between age with mercury in Pseudociaena manchurica (r=0.7018, P<0.05). The negative correlation of age with lead content in the Pseudociaena Manchurica was signigicant (P<0.05). The correlation coefficient was r=-0.7623. The age with mercury content in Coloabis saira had high correlation (r=0.7201, P<0.05). Through the above analysis, it can get conclusion that injurious heavy metal content of the fishes in Korea such a mercury, lead, cadmium and arsenic were at the level of natural content. At present, guidelines of maximum residue level allowed at foreign countries about the injurious heavy metal have been used according to the kinds of fish but our government guideline for the marine fishes in only total mercury below 0.7 ppm and lead below 2 ppm. So more aggressive guidelines for the allowance level of heavy metals in marine fishes are required for the safety of foods.

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FMN-Based Fluorescent Proteins as Heavy Metal Sensors Against Mercury Ions

  • Ravikumar, Yuvaraj;Nadarajan, Saravanan Prabhu;Lee, Chong-Soon;Jung, Seunho;Bae, Dong-Ho;Yun, Hyungdon
    • Journal of Microbiology and Biotechnology
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    • 제26권3호
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    • pp.530-539
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    • 2016
  • Bacterial light-oxygen-voltage-sensing photoreceptor-derived flavin mononucleotide (FMN)-based fluorescent proteins act as a promising distinct class of fluorescent proteins utilized for various biomedical and biotechnological applications. The key property of its independency towards oxygen for its chromophore maturation has greatly helped this protein to outperform the other fluorescent proteins such as GFP and DsRed for anaerobic applications. Here, we describe the feasibility of FMN-containing fluorescent protein FbFP as a metal-sensing probe by measuring the fluorescence emission changes of a protein with respect to the concentration of metal ions. In the present study, we demonstrated the mercury-sensing ability of FbFP protein and the possible amino acids responsible for metal binding. A ratiometric approach was employed here in order to exploit the fluorescence changes observed at two different emission maxima with respect to Hg2+ at micromolar concentration. The engineered variant FbFPC56I showed high sensitivity towards Hg2+ and followed a good linear relationship from 0.1 to 3 μM of Hg2+. Thus, further engineering with a rational approach would enable the FbFP to be developed as a novel and highly selective and sensitive biosensor for other toxic heavy metal ions as well.

담수산 클로렐라(Chlorella vulgaris)의 수은 스트레스에 대한 엽록소형광 반응 (Chlorophyll a Fluorescence Response to Mercury Stress in the Freshwater Microalga Chlorella Vulgaris)

  • 오순자;고석찬
    • 한국환경과학회지
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    • 제22권6호
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    • pp.705-715
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    • 2013
  • The response of the freshwater microalga Chlorella vulgaris to mercuric ion ($Hg^{2+}$) stress was examined using chlorophyll a fluorescence image analysis and O-J-I-P analysis as a way to monitor the toxic effects of mercury on water ecosystems. The levels of photosynthetic pigments, such as chlorophyll a and b and carotenoids, decreased with increasing $Hg^{2+}$ concentration. The maximum photochemical efficiency of photosystem II(Fv/Fm) changed remarkably with increasing $Hg^{2+}$ concentration and treatment time. In particular, above $200{\mu}M\;Hg^{2+}$, considerable mercury toxicity was seen within 2 h. The chlorophyll a fluorescence transient O-J-I-P was also remarkably affected by $Hg^{2+}$; the fluorescence emission decreased considerably in steps J, I, and P with an increase in $Hg^{2+}$ concentration when treated for 4 h. Subsequently, the JIP-test parameters (Fm, Fv/Fo, RC/CS, TRo/CS, ETo/CS, ${\Phi}_{PO}$, ${\Psi}_O$ and ${\Phi}_{EO}$) decreased with increasing $Hg^{2+}$ concentration, while N, Sm, ABS/RC, DIo/RC and DIo/CS increased. Therefore, a useful biomarker for investigating mercury stress in water ecosystems, and the parameters Fm, ${\Phi}_{PO}$, ${\Psi}_O$, and RC/CS can be used to monitor the environmental stress in water ecosystems quantitatively.

대기 중 수은의 지역적 분포특성에 대한 비교연구-한반도의 도심과 산악지역을 중심으로 (Regional Distribution Characteristics of Total Gaseous Mercury in Air-Measurements from Urban and Mountainous Sites in Korea)

  • 김민영;김기현
    • 한국대기환경학회지
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    • 제17권1호
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    • pp.39-50
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    • 2001
  • The spatial distribution characteristics of airborbe mercury(Hg) were investigated used its concentration data from six measurement sites selected to represent:(1) three terminal sites with heavy traffic loads in urban area, (2) one urban residential site and (3) two mountainous sites in Korea. The measurement data obtained during September 1997 through May 1998 indicated that the mean concentration of Hg from different study sites were comparably high with the mean values spanning from 5-9ng./㎥. The concentration from all those sites were systmatically high compared to those of most background sites around world or to other Korean sites investigaed previously. When results of correlation analysis between Hg and relevant parameters were compared among different study sites. temperature was most frequently found out to be in strong correlation with Hg concentrations. Results of factor analysis also indicated that Hg concentrations could be affected simultaneously by th factors affecting such parameters as ozone, temperature, ozone, carbon monoxide, and PM. The findings of enhanced Hg levels from Ji-Ri Mountain relative to terminal site suggest that is distributions may be rather homogeneous not enough to clearly distinguish areal differences and the associated source signatures between urban and rural area. The existence of systmatically high concentrations from all investigated sites also indicate that the impact of its source processes should be quite ubiquitous, while highly variable in relatively long term scale.

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Changes in Atmospheric Mercury Concentrations in Seoul, Korea and its Significance: A Case Study Between 1997 and 2002

  • Kim Ki-Hyun;Kim Min-Young;Hong SM
    • Journal of Korean Society for Atmospheric Environment
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    • 제21권E1호
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    • pp.1-11
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    • 2005
  • The concentration levels of gaseous elemental mercury (GEM) in ambient air have been investigated from a monitoring station located in Yang Jae district of Seoul, Korea for a long-term period covering 1997 through 2002. The mean concentration of Hg, if computed based on its hourly measurement data for this six-year period, was $5.32\pm3.53 ng m^{-3} (N = 27,170)$. The inspection of the diurnal distribution patterns indicated the presence of notably high concentration levels during nighttime relative to daytime (e.g., the mean hourly value as high as $9 ng m^{-3}$ in winter nighttime). When divided seasonally, the highest mean of $6.12 ng m^{-3}$ was also observed during winter followed by spring, fall, and summer. The results of our analysis confirmed the relative dominance of winter (seasonally) or nighttime (diurnally), while exhibiting a complicated trend on a long-term basis. Examination of our data over a different temporal scale consistently indicated that dynamic changes in Hg concentrations occurred through time in line with changes in the strength and diversity of the source processes. It is thus acknowledged that the presence of unusually high Hg levels is the consequence of intense man-made activities, while such signatures can vary in a competitive manner.

무수은 제논 EEFL의 전기적 특성 (Electric Properties of Mercury-free Xe EEFL)

  • 이성진;김남군;이종찬;박노준;박대희
    • 한국전기전자재료학회논문지
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    • 제20권7호
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    • pp.650-657
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    • 2007
  • This paper had mentioned about CCP light source application for increasing the efficiency of Xe lamp the mercury-free lamp. In order to increase the efficiency of Xe EEFL, we designed and manufactured the lamp used by mixture gas of Xe, Ne and He. Also, we have analyzed the electrical and optical properties with the firing voltage, sustain voltage, paschen's curve, wall charge, and capacitance. As a result, the firing voltage decreased by increasing the ration of mixture gas. and, It is owing to include the gas with high ionization energy. The firing voltage decreased in condition happening the penning effect, Because the ion of metastable state created from penning effect, Which can encourage the ionization phenomena. Also, the wavelength of 467.12 is increase. because of the energy transition in the wavelength of 147 nm. therefore, we can know about the affection of phosphor with UV emission properties. Through an experiment, Xe 100 % and Xe 75 % confirmed same spectrum properties by each mixture gas ratio. In the case of Xe 50 %, spectrum properties appeared Xe discharge and Ne-He discharge. That analyzed an electrical and optical properties. Therefore, confirmed that is excellent because properties of firing voltage, wall charge, capacitance in Xe 50 %, Ne : He = 9 : 1. We offered parameter in inverter manufacture and lamp manufacture by electrical and optical properties.

Measurements of Atmospheric Gaseous Elemental Mercury over the Yellow Sea during 2007-2008

  • Nguyen, Duc Luong;Kim, Jin-Young;Shim, Shang-Gyoo;Jin, Hyoun-Cher;Zhang, Xiao-Shan
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2009년도 추계학술대회 논문집
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    • pp.255-258
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    • 2009
  • This study shows that the $Hg^0$ background concentration over the Yellow Sea was generally higher than those observed over other seas/oceans around the world. $Hg^0$ concentrations measured in the urban stomophere were significantly higher than the background concentration in China. Elevated $Hg^0$ concentrations at Deokjeok Island in Korea were attributed to long-range transport of mercury from high emission areas in China.

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