• Bulletin of the Korean Chemical Society
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• 제23권12호
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• pp.1719-1723
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• 2002

1,5-diphenylcarbazone was immobilized on sodium dodecyl sulfate coated alumina. The alumina particle was effectively used for collection of mercury(II) and methylmercury cations at sub-ppb level. The adsorbed mercury was eluted with l mol $L^{-1}$ of hydrobromic acid solution. The mercury(II) was then directly measured by cold vapor atomic absorption spectrometry utilizing tin (II) chloride where as the total mercury was determined after the oxidation of methylmercury into the inorganic mercury. The methylmercury concentration was calculated by the difference between the value of total mercury and mercury (II). Mercury (II) and methylmercury cations were completely recovered from water with a preconcentration factor of 100 (for 1 L solution.) Relative standard deviation at Hg L ${\mu}gL^{-1}$ level 1.7%(n=8) and the limit of detection was 0.11 ${\mu}gL^{-1}$. The procedure was applied to spring water, well water and seawater and accuracy was assessed through recovery experiments.

• Journal of Korean Neurosurgical Society
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• 제49권4호
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• pp.245-247
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• 2011

There were only a few reports of mercury on pulmonary artery. However, there is no data on surgery related mercury dissemination. The objective of the present article is to describe one case of postoperative injected mercury dissemination. A 19-year-old man presented severe neck pain including meningeal irritation sign and abdominal pain after injection of mercury for the purpose of suicide. Radiologic study showed injected mercury in the neck involving high cervical epidural space and subcutaneous layer of abdomen. Partial hemilaminectomy and open mercury evacuation of spinal canal was performed. For the removal of abdominal subcutaneous mercury, C-arm guided needle aspiration was done. After surgery, radiologic study showed disseminated mercury in the lung, heart, skull base and low spinal canal. Neck pain and abdominal pain were improved after surgery. During 1 month after surgery, there was no symptom of mercury intoxication except increased mercury concentration of urine, blood and hair. We assumed the bone work during surgery might have caused mercury dissemination. Therefore, we recommend minimal invasive surgical technique for removal of injected mercury. If open exposures are needed, cautious surgical technique to prohibit mercury dissemination is necessary and normal barrier should be protected to prevent the migration of mercury.

• 생약학회지
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• 제18권1호
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• pp.34-40
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• 1987

Onion extracts were tested for effects on the growth and lactic acid production of Lactobacillus bulgaricus in the medium containing mercury. The media containing mercury were added with onion extracts and inoculated with the bacterium and then incubated at $39^{\circ}$ for four days. All of the onion extracts examined increased the growth and lactic acid production of the bacterium in the medium containing mercury. At the addition of the edible portion extract of onion to the medium containing 5 ppm, 10 ppm and 20 ppm mercury, the higher the concentration of the onion extract was added, the greater the increasing effect on the growth and lactic acid production. The brown peel extract of onion increased the growth and lactic acid production of the bacterium in the medium containing mercury at all concentrations. The higher the concentration of the extract added, the more effective the increasing effect. The onion solutions of edible portion and brown peel extracted at $90^{\circ}\;to\;100^{\circ}$ showed more desirable effects than those extracted at the room temperature. Among four kinds of the onion extracts, the brown peel solution extracted at $90^{\circ}\;to\;100^{\circ}$ was the most effective in increase of the growth and lactic acid production in the medium containing mercury.

• Journal of Ecology and Environment
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• 제47권2호
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• pp.42-48
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• 2023

An adult male Eurasian river otter (Lutra lutra) with ataxia and lethargy was rescued. Through the necropsy of this otter with neurological symptoms, a broad range of vascular damage caused by mercury toxicity in several organs, hepatocellular necrosis, and vacuolation in the brain. In mercury examination, liver, kidney, and hair showed values of 0.878 ± 0.027, 1.807 ± 0.049, and 5.712 ± 0.102 ㎍/g, respectively. Compared with certified reference material, it was confirmed that the concentration of mercury were 6.7 times, 13.7 times, and 43.3 times higher, respectively. When the symptoms and diagnosis results were comprehensively reviewed, this otter's demise was revealed due to mercury poisoning. The mercury concentration in the liver does not exceed the lowest observed effect level of 3.4 ㎍/g. However, even at low concentrations, long-term accumulation can cause symptoms including neuropathy, and the possibility that these heavy metals have accumulated in other wild animals cannot be ruled out. It seems that continuous monitoring using sentinel animals is necessary.

• Journal of Preventive Medicine and Public Health
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• 제13권1호
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• pp.27-34
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• 1980

Purpose of this study is to find out proper means of estimating the urinary mercury excretion in the normal individuals. Whole void volume was collected every 2 hours beginning from 6 o'clock in the morning until 6 o'clock next morning. Mercury excretion in each urine specimen was measured by NIOSH recommended dithizone colorimetric method (Method No.: P & CAM 145). Urinary concentration of mercury was adjusted by two means: specific gravity of 1.024 and a gram of creatinine excretion per liter of urine comparing the data with the unadjusted ones. Mercury excretion in 24-hour urine specimen was calculated by adding the amounts measured with the hourly collected specimens of each individual. Statistical analysis of the urinary mercury excretion revealed the following results: 1. Frequency distribution curve of mercury excreted in urine of hourly specimens was best fitted to power function expressed in the form of $y=ax^b$. Adjustment of the urinary mercury concentration by creatinine excretion was shown to be superior($y=1674x^{-1.52},\;r^2=0.95$) over nonadjustment($y=2702x^{-1.57},\;r^2=0.92$) and adjustment by specific gravity of 1.024($y=4535x^{-1.66},\;r^2=0.93$). 2. Both log-transformed mercury excretion in hourly voided specimens and mercury excretion itself in 24 hour specimens showed the normal distributions. 3. The frequency distribution of mercury adjusting the urinary concentration of mercury by creatinine excretion was best fitted to a theoretical normal distribution with the sample means and standard deviation than those unadjusted or adjusted with specific gravity of 1.024. 4. Average urinary mercury excretions in 24-hour urine specimen in an individual were as follows: a) Unadjusted mercury excretion mean and standard deviation : $$18.6{\pm}13.68{\mu}gHg/l$$. median : $$16.0\;{\mu}gHg/l$$. range : $$0.0-55.10\;{\mu}gHg/l$$. b) Adjusted with specific gravity mean : $$20.7{\pm}11.76\;{\mu}gHg/l{\times}\frac{0.024}{S.G-1.000}$$ median : $$20.7\;{\mu}gHg/l{\times}\frac{0.024}{S.G-1.000}$$ range : $$0.0-52.9\;{\mu}gHg/l{\times}\frac{0.024}{S.G-1.000}$$ c) Adjusted with creatinine excretion mean and standard deviation : $$10.5{\pm}6.98\;{\mu}gHg/g$$ creatinine/l median : $$9.4\;{\mu}gHg/g$$ creatinine/l range : $$0.0-26.7\;{\mu}gHg/g$$ creatinine/l 5. No statistically significant differences were found between means calculated from 24-hour urine specimens and those from hourly specimens transformed into logarithmic values. (P<0.05).

• 대한치과의사협회지
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• 제23권2호통권189호
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• pp.161-164
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• 1985

This study was carried out for the purpose of evaluating the blood mercury concentration of dentists in Korea. Samples of blood were collected from 35 dentists during daily practice in November, 1984. The mercury level in the blood was measured by mercury analyses system (Sugiyama-Gen Environmental Science Co. LTD) The result obtained from this study ws the mean of total blood mercury level of dentists was 41.62 μg/100ml and the range 17.3μg/100ml~133.3μg/100ml.

• Molecular & Cellular Toxicology
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• 제4권3호
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• pp.235-245
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• 2008

Exposure to mercury was assessed in 125 Korean (Gwangju and Busan) and 373 Chinese primary school students (Xinguang village, Goumen town) using hair mercury analysis from November 2006 to September 2007. The geometric mean concentration of mercury was higher among Korean children with recording 0.73 ${\mu}g$/g, compared to Chinese children of 0.12 ${\mu}g$/g, which indicated statistically difference (P<0.01). The mean concentration of Korean children living near incineration facilities was higher by recording 0.76 ${\mu}g$/g while the average concentration of their counterpart in Korea reached 0.69 ${\mu}g$/g. In case of Chinese children, those who are living near power plants showed higher level with posting 0.16 ${\mu}g$/g while the others recorded 0.10 ${\mu}g$/g (P<0.01). Intake of fish was found to be related to hair mercury level. In case of Korean children, those with high fish intake recorded 0.79 ${\mu}g$/g in terms of the geometric mean concentration while the others with low fish intake posted 0.61 ${\mu}g$/g. Among Chinese children, those who often eat fish recorded 0.13 ${\mu}g$/g compared to the others with low fish intake of 0.11 ${\mu}g$/g. On the other hand, amalgam dental fillings have limited influence on mean hair mercury level. As for vaccination, within a month of vaccination, the geometric mean concentration of Korean children reached 0.76 ${\mu}g$/g, and in case of 15 days after injection, the level was 1.20 ${\mu}g$/g. In China, the level of children at one month after receiving injection stood at 0.15 ${\mu}g$/g while the level within 15 days was 0.13 ${\mu}g$/g. Multiple regression analysis showed that BMI, passive smoking, and fish consumption are closely related to hair mercury level among the Korean subjects. In China, hair mercury level was affected by age, location, passive smoking, fish consumption, and vaccination. Explanatory power was 21.6% with $R^2$=0.216.

• 치위생과학회지
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• 제12권3호
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• pp.253-258
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• 2012

치과용 아말감은 수은, 구리, 아연, 은과 같은 여러 가지 금속으로 이루어진 합금으로 구성되었다. 아말감은 내구성과 진료 시 사용의 편리성과 경제적인 이유로 치과영역에서 가장 흔히 사용되고 효과적인 수복물질로 이용되었다. 하지만 수복물질로서의 대중성과 긴 역사에도 불구하고 아말감에 포함된 수은의 노출로부터 가져올 수 있는 잠재적 부작용 또는 합병증에 대한 염려로 논란이 계속되고 있다. 특히 어린이들의 경우 수은의 독성에 대한 위험성이 더 높기 때문에 우리는 어린이에게서 치과용 아말감과 요중 수은농도의 관련성에 대하여 알아보고자 하였다. 대도시 지역 내 두 개 초등학교 1~4학년 재학생을 대상으로 하여 구강검진과 설문조사를 시행하였으며, 구강검진 당일 채취한 소변시료를 이용하여 요중 수은농도를 분석하였다. 결과는 구강 내 아말감 충전치아가 없는 아동과 비교 했을 때 79개 이상, 10개 이상 갖는 아동의 요중 수은농도가 높아지는 상관관계가 나타났다. 결론적으로 어린이의 구강 내 아말감 충전치면수와 요중 수은농도는 관련성이 있는 것으로 사료된다.

• Environmental Analysis Health and Toxicology
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• 제22권2호통권57호
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• pp.185-188
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• 2007

PM10 and PM2.5 in ambient air were collected in Seongbuk-gu area of Seoul for one year, from April 2005 to February 2006, and the concentration of PM-bound mercury was monitored. The annual concentrations of particles were $66.4{\pm}43.2{\mu}g/m^3\;(47.6{\pm}19.1{\mu}g/m^3-106.1{\pm}78.0{\mu}g/m^3)$ in PM10 and $37.2{\pm}20.4{\mu}g/m^3\;(28.0{\pm}23.4{\mu}g/m^3{\sim}42.7{\pm}21.4{\mu}g/m^3)$ in PM2.5, which is about 56% of PM10 concentration. The annual average concentrations of mercury were $0.125{\pm}0.078ng/m^3\;in\;PM10\;and\;0.141{\pm}0.080ng/m^3$ in PM2.5, respectively. In April of Asian dust season in Korea, mercury showed the highest concentration in both PM10 and PM2.5.

• 한국환경보건학회지
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• 제44권1호
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• pp.24-30
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• 2018

Objectives: Based on the amount of amalgam, the duration of exposure, and the water pH, this study aims to investigate the change patterns in the mercury concentrations in water after amalgams have been introduced into sewage water. It is expected that the study results will be useful in improving the system for regulating the amount of mercury that is introduced into the environment. Methods: During the study, a glass test-tube with a cap was washed and disinfected using the glass laboratory device washing method. Then, 1, 2, 3, and 4 tabs were placed into a 10 mL pH 4 solution and 10 mL pH 7 distilled water. Each specimen was prepared in duplicate. The mean of the two mercury concentrations was used as the representative value, and the mercury concentration was measured using a mercury measurement device (DMA-80, Milestone, Italy) a total of eight times at one-week intervals. Results: The results show that the lower was the pH, the higher was the amount of amalgam. Also the longer was the duration, the more significant was the increase of mercury concentration in the water. Conclusions: Dental clinics are collected separately from dental clinics that used them. Given this, dental clinics in Korea must have the necessary facilities to separately collect mercury at their level. In addition, proper disposal systems and social attention to the proper management of dental wastes are required to prevent environmental pollution from mercury.