• Proceedings of the KIEE Conference
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• 1998.11c
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• pp.764-766
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• 1998

An evaluation method for oxygen permeable characteristics of the membrane covering to each cathode of multiple cathode - single anode type dissolved oxygen sensor, which has high reproducibility and is capable of measuring multiple components in solutions. For this purpose, a measuring circuit for the multiple cathode type DO sensor was designed to lower the noise signal by adapting a digital LPF to readout the sensor output accurately. Digital LPF is designed by setting up the transfer function to set the cutoff frequency to 10Hz, and the transfer function is programmed by C language, and then the filtering characteristics are evaluated with the simulation and experiments. Using this LPF added measuring circuit for the multiple cathode type DO sensor, we have obtained the calibration factor for each cathode to calibrate the variation of the output signals. The calibration factor was obtained by measuring the sensor output signal followed by oxygen partial pressure, using the same oxygen permeable membrane at each cathode of the multiple cathode type DO sensor.

• Journal of the Korean Society of Industry Convergence
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• v.23 no.6_2
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• pp.1059-1065
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• 2020

Demand for pressure sensors is increasing in various fields such as machinery, healthcare and medical care. A recent study is being conducted to create sensors that are more sensitive and have longer linear sections based on measurement principles. In this paper, a film-type sensor with a membrane structure was developed to measure the pressure distributed in the axial direction of a hot roll laminator. Performance of sensors was evaluated by resistance and durability according to membrane diameter. The resistance of the membrane sensor varies according to the contact state and contact area of the electrode. Therefore, the membrane diameter selection is important. Experiments showed the most pronounced variation in resistance under pressure at 8 mm in diameter of membrane. Reliability evaluation of sensors was carried out at room temperature and high temperature. The pressure on the sensor was pressurized 1000 times to measure the initial resistance and the resistance after the evaluation to analyze the change. Sensors showed stable results with low resistance changes of 5.15% and 6.27%, respectively. A large area sensor manufactured using the developed sensor also showed reliable results.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.792-796
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• 2002

In this work, porous silicon(PS) layer is used as a sensing material to detect organic gases. To do this, PS sensors with membrane structure are fabricated. The sensors were made by applying the technologies of membrane formation by anisotropic etching of silicon, and PS layer formation by anodization in HF solution. From fabricated sensors, current-voltage (I-V) curves were measured against ethanol (called alcohol), methanol and acetone gases evaporated from 0.1 to 0.5% solution concentrations at $36^{\circ}C$. As the result, all curves showed rectifying behavior due to a diode structure between Si and PS, and the conductance of sensor devices increased largely with the organic solution concentration at high voltage of 5V.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.28 no.1
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• pp.41-50
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• 2023

Dissolved oxygen sensors have characteristics in which data drift occurs over time. Therefore, in-situ calibration of the dissolved oxygen sensor is essential to accurately measure the concentration of dissolved oxygen in seawater. In order to provide a method for in-situ calibration, appropriate number of samples for calibration, and laboratory calibration interval of the dissolved oxygen sensor, the dissolved oxygen sensor values were compared with the measured values by titration on a total of 133 samples from three different cruises in the Indian Ocean, Pacific Ocean, and East Sea over a period of about one year. As a result, it is preferable to calibrate the sensor value using the correlation of a straight line obtained by directly comparing the final concentration value given by the sensor and the measured value. For the accurate calibration, at least 30 samples must be used to enable in-situ calibration within an accuracy range of about 1%. In addition, it is recommended that a laboratory calibration should perform within 1 year for the membrane type dissolved oxygen sensor for CTD to achieve a performance of 70% or more.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.11
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• pp.963-968
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• 2002

In this work, porous silicon (PS) layer is investigated as a sensing material to detect organic vapors such as ethanol (called alcohol), methanol, and acetone in low concentrations. To do this, PS sensors were fabricated. They have a membrane structure and comb-type electrodes were used to detect the change of electrical resistance effectively. PS layer on Si substrates was formed by anodization in HF solution of 25%. From fabricated sensors, current-voltage (Ⅰ-Ⅴ) curves were measured for gases evaporated from 0.1 to 0.5% organic solution concentrations at 36$\^{C}$. As the result, all curves showed rectifying behavior due to a diode structure between Si and the PS layer. The conductance of most sensors increased largely at high voltage of 5V, but the built-in potential on the measured Ⅰ-Ⅴ curve was lowered inversely by the adsorption effect of the organic vapors with high dipole moment.

• Journal of the Korean Chemical Society
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• v.41 no.12
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• pp.653-660
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• 1997

Silicone rubber-matrix membranes doped with tetradecyltrimethylammonium chloride (TDTMACl) are used to enhance electrode performance for chloride measurements in physiological samples. The optimized membrane formulation incorporates 95.4 wt% silicone rubber and 4.6 wt% TDTMACl, and its pH response is negligible in the range of pH 6-10. The TDTMACl-doped silicone rubber membrane exhibits sub-Nernstian response to chloride from 10 to 300 mM (-37.5 mV/decade), but its selectivities for chloride over other anions are remarkably enhanced: KpotCl,NO3=1.3, KpotCl,I=2.0, KpotCl,Sal=0.8, KpotCl,SCN=2.0 and KpotCl,ClO4=0.8. Furthermore, since the silicone rubber-matrix membrane exhibits better adhesion to the solid surface than do PVC membranes, the lifetime of the coated-wire type membrane electrode is greatly improved. The response properties toward chloride and salicylate for solid-state sensor are not significantly changed after at least 35 days of use.

• Journal of the Korean Applied Science and Technology
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• v.30 no.2
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• pp.258-263
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• 2013

New conducting polymers containing heterocyclic ring with carbazole, EDOT and benzobisthiazole were synthesized and characterized by organic spectroscopic methods. Potentiometric ion-selective membrane electrodes (ISMEs) have been extensively used for ion analysis in clinical, environmental, and industeial fields owing to its wide response range (4 to 7 orders of magnitude), no effect of sample turbidity, fast response time, and ease of miniaturization. Considerable attention has been given to alternative use of room temperature vulcanizing (RTV)-type silicone rubber(SR) owing to its strong adhesion and high thermal durability. Unfortunately, the high membrane resistance of SR-based (ISMs)(2 to 3 higher orders of magnitude compared to those of poly(vinyl chloride)(PVC)-based ones) has significantly restricted its application. Herein we demonstrate a new method to reduce membrane resistance via addition of new conducting polymer into the SR-based ISMs.