• Title/Summary/Keyword: Membrane thickness

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Molecular Weight Distribution Inside and Outside Capsules Using Coencapsulating Technology (공동캡슐화를 이용한 Capsule 내외부의 분자량 분포)

  • 이기선;임현수
    • KSBB Journal
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    • v.16 no.4
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    • pp.321-326
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    • 2001
  • The change of molecular weight inside and outside a capsule produced using coencapsulating technology was investigated. Chitosan and chitosanase were enveloped in this membrane and product released was a loaded the medium by the principle of size exclusion. The leakage of substrate corresponding to the agitation speed was controlled by adjusting the alginate and CaCO$_3$ concentrations. The optimal condition of alginate concentration and agitation speed were 0.5% and 40rpm, respectively. Membrane thickness and capsules diameter were 10 $\mu$m and approx. 3.0 - 1.5 mm, respectively. Molecular weight difference by concentration and alginate viscosity were of little significance. In accordance with the molecular weight distribution versus enzyme concentration relationship, low concentration of enzyme produced high molecular weight oligosaccharides. At a 1.5 mm capsule size the product diffusion rate to outer surface highest. The molecular weight distribution of the released oligosaccharides was ranged from 1000 to 6000 Da. More than 80% of the initial activity of encapsulated enzyme retained after 8hrs of reaction.

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Nanostructured PVdF-HFP/TiO2 Composite as Protective Layer on Lithium Metal Battery Anode with Enhanced Electrochemical Performance (PVdF-HFP/TiO2 나노복합체 보호층을 통한 리튬금속전지 음극의 전기화학적 성능 향상)

  • Lee, Sanghyun;Choi, Sang-Seok;Kim, Dong-Eun;Hyun, Jun-Heock;Park, Young-Wook;Yu, Jin-Seong;Jeon, So-Yoon;Park, Joongwon;Shin, Weon Ho;Sohn, Hiesang
    • Membrane Journal
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    • v.31 no.6
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    • pp.417-425
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    • 2021
  • As the demand for high-capacity batteries increases, there has been growing researches on the lithium metal anode with a capacity (3,860 mAh/g) of higher than that of conventional one and a low electrochemical potential (-3.040 V). In this study, using the anatase phased TiO2 nanoparticles synthesized by hydrothermal synthesis, a PVdF-HFP/TiO2 organic/inorganic composite material was designed and used as an interfacial protective layer for a Li metal anode. As-formed organic/inorganic-lithium composite thin film was confirmed through the crystalline structure and morphological analyses. In addition, the electrochemical test (cycle stability and voltage profile) confirmed that the protective layer of PVdF-HFP/TiO2 composite (10 wt% TiO2 and 1.1 ㎛ film thickness) contributed to the enhanced electrochemical performance of the lithium metal anode (Colombic efficiency retention: 90% for 77 cycles). Based on comparative test with the untreated lithium electrode, it was confirmed that our protective layer plays an important role to stabilize/improve the EC performance of the lithium metal negative electrode.

A Study on the Behavior of Wall-Support Joint of Steel Plate-Concrete Structure (SC(강판-콘크리트)구조 브라켓 접합부 거동에 관한 연구)

  • Kim, Woo Bum;Kim, Kang Sik
    • Journal of Korean Society of Steel Construction
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    • v.16 no.3 s.70
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    • pp.377-385
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    • 2004
  • An experimental and analytical study on the behavior of the wall-support joint in SC(steel plate-concrete) structure was performed. Nine full-scale specimens were tested with a horizontal monotonic load, all acting in the same plane, causing a uni-axial moment on the SC structure's wall-support beam joint. The main focus is to examine thenonlinear behavior and ultimate strength of the SC wall-support joint. The effects of parameters, such aslocation of support, thickness of the steel plate, and size of support, were studied. The yield strength and ultimate strength of the plate-concrete wall was defined by examining the load-deflection relationship, showing the tension membrane action.

Fabrication of a FBAR device using a novel process and the effect of bottom electrode on the frequency response (신 공정을 이용한 멤브레인형 체적탄성파 공진기의 제작 및 하부전극이 주파수 응답특성에 미치는 영향)

  • Kim, Bo-Hyun;Kim, Do-Young;Cho, Dong-Hyun;Lee, Jin-Bock;Park, Jin-Seok
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1594-1596
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    • 2004
  • Film bulk acoustic resonator (FBAR) devices which adopt a membrane-type configuration are fabricated by a novel process. In contrast to the conventional FBAR structure, the newly fabricated resonator doesn't employ any supporting layer below or above it, so that the properties of piezoelectric layer are not influenced by the bottom electrode material. FBAR devices with Mo/AlN/Metal configuration are also fabricated. The frequency response characteristics ($S_{11}$) of the devices fabricated using the proposed process are compared with those of the conventional devices. The return losses are also estimated, in terms of the kind and thickness of bottom electrode materials.

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Biodentine-a novel dentinal substitute for single visit apexification

  • Nayak, Gurudutt;Hasan, Mohammad Faiz
    • Restorative Dentistry and Endodontics
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    • v.39 no.2
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    • pp.120-125
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    • 2014
  • Use of an apical plug in management of cases with open apices has gained popularity in recent years. Biodentine, a new calcium silicate-based material has recently been introduced as a dentine substitute, whenever original dentine is damaged. This case report describes single visit apexification in a maxillary central incisor with necrotic pulp and open apex using Biodentine as an apical barrier, and a synthetic collagen material as an internal matrix. Following canal cleaning and shaping, calcium hydroxide was placed as an intracanal medicament for 1 mon. This was followed by placement of small piece of absorbable collagen membrane beyond the root apex to serve as matrix. An apical plug of Biodentine of 5 mm thickness was placed against the matrix using pre-fitted hand pluggers. The remainder of canal was back-filled with thermoplasticized gutta-percha and access cavity was restored with composite resin followed by all-ceramic crown. One year follow-up revealed restored aesthetics and function, absence of clinical signs and symptoms, resolution of periapical rarefaction, and a thin layer of calcific tissue formed apical to the Biodentine barrier. The positive clinical outcome in this case is encouraging for the use of Biodentine as an apical plug in single visit apexification procedures.

Impurities in the methanol fuel on the performance of direct methanol fuel cell (직접메탄올 연료전지의 성능에 미치는 메탄올 연료의 불순물)

  • Peck, Dong-Hyun;Lee, Jae-Hyuk;Park, Young-Chul;Lim, Seongyop;Kim, Sang-Kyung;Jung, Doo-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.124.1-124.1
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    • 2010
  • The impurities in the methanol fuel that is used for direct methanol fuel cell (DMFC) could greatly affect the performance of membrane electrode assemblies (MEA). The most common impurities in the commercial methanol fuel are mainly ethanol, acetone, acetaldehyde, or ammonia. In this study, the effect of impurities in methanol fuel was investigated on the performance of MEA. The MEA for DMFC were prepared using a semi-automatic bar-coating machine, which can prepare the catalyst layer with uniform thickness for MEA. As a result, a single cell supplied with one of the 6 different kinds of methanol fuels showed a significant degradation of the fuel cell performance. The most common impurities in the commercial methanol fuel is mainly ethanol, acetone, acetaldehyde, or ammonia. The effects of the kind and the concentration of impurities in the methanol fuels were investigated on the performance of MEA for DMFC. We will propose the optimum compositions and limit concentration of impurities in methanol fuel for high performance of MEA for DMFC.

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Involvement of Vascular NAD(P)H Oxidase-derived Superoxide in Cerebral Vasospasm after Subarachnoid Hemorrhage in Rats

  • Kim, Dong-Eun;Kim, Chi-Dae
    • The Korean Journal of Physiology and Pharmacology
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    • v.6 no.1
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    • pp.15-19
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    • 2002
  • The role of vascular NAD(P)H oxidase in subarachnoid hemorrhage (SAH)-induced vasospasm in the basilar artery was examined in a rat model. Arterial vasospasm characterized by increased wall thickness and decreased lumen size was observed at 5 to 7 days after $2^{nd}$ injection of blood into cisterna magna, and these changes were significantly ameliorated by pretreatment of diphenyleneiodonium $(DPI,\;25\;{\mu}l\;of\;100\;{\mu}M),$ an inhibitor of NAD(P)H oxidase. To determine the time course of changes in the vascular NAD(P)H oxidase activity, cerebral vasculature was isolated at different time intervals from 12 hrs to 14 days after injection of autologous blood. At 24 hrs after the second injection of blood, the NAD(P)H oxidase activity was markedly increased with an enhanced membrane translocation of p47phox, but by 48 hours both the enzyme activity and p47phox translocation regained normal values, and were remained unchanged up to 14 days after SAH. However, no significant changes in the expression of p22phox mRNA was observed throughout the experiments. These findings suggest that the activation of NAD(P)H oxidase by which assembly of the oxidase components enhanced and subsequent production of superoxide in the early stages of SAH might contribute to the delayed cerebral vasospasm in SAH rats.

A Study on Thermal and Mechanical Behaviors of Micro Reformer (마이크로 리포머의 열 및 역학적 거동 분석)

  • Hwang W.H.;Jang J.H.;Kil J.H.;Kim S.J.;Lee R.W.;Kim S.H.;Chung K.H.;Oh Y.S.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.235-239
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    • 2005
  • We analyzed the thermal and mechanical behaviors of micro reformer for the purpose of design verifications and modification of micro channels. The reformer designed for hydrogen generation from methanol is essential to PEM(Proton Exchange Membrane) type fuel cell. For the mobile applications, the size and the simplicity would be the most critical issues. We utilized silicon process for micro reformer to obtain the thickness thinner than 2 mm thick. We have used commercial simulation software, IDEAS, to analyze the thermal and mechanical characteristics of micro reformer structure. The heat generation rates of heaters, heat transfer rates, and fluid temperatures are derived from thermal equilibrium relation and these values were used for thermal boundary conditions. We also analyzed the thermal stresses, thermal deformations to examine the possibility of failure.

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Development of a flat shell element by using the hybrid Trefftz plane element with drilling D.O.F. and the DKMQ element (면내 회전 자유도가 추가된 hybrid Trefftz 평면 요소와 DKMQ 요소를 이용한 4 절점 평면 셸 요소의 개발)

  • 최누리;추연석;이승규;이병채
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.855-859
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    • 2004
  • We develop a new four-node flat shell element which is accurate, efficient, and suitable to be used on general purpose. The new element has a hybrid Trefftz element with drilling degrees of freedom as a membrane part. We define the two independent displacement field: the internal displacement field that satisfies governing equations in the domain a priori and the boundary displacement field that is usually used as a conventional finite element method. The hybrid Trefftz variational formulation connects these two displacement fields on the boundary of the domain. To add drilling degrees of freedom, we introduce the Allman's quadratic displacement field to the boundary displacement field. As a result, our flat shell element has 6 degrees of freedom per a node. We also use the well-known DKMQ plate bending element for the plate part of the proposed element. The DKMQ element satisfies Mindlin-Reissner‘s plate theory along the edge of the element and gives proper behavior regardless of the thickness. A series of numerical experiments shows that the performance of the new element such as accuracy, rate of convergence, robustness to mesh quality, and so on.

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Development of High Frequency pMUT Based on Sputtered PZT

  • Lim, Un-Hyun;Yoo, Jin-Hee;Kondalkar, Vijay;Lee, Keekeun
    • Journal of Electrical Engineering and Technology
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    • v.13 no.6
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    • pp.2434-2440
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    • 2018
  • A new type of piezoelectric micromachined ultrasonic transducer (pMUT) with high resonant frequency was developed by using a thin lead zirconate titanate (PZT) as an insulation layer on a floating $10{\mu}m$ silicon membrane. The PZT insulation layer facilitated acoustic impedance matching at active pMUT, leading to a high performance in the acoustic conversion property compared with the transducer using $SiO_2$ insulation layer. The fabricated ultrasonic devices were wirelessly measured by connecting two identical acoustic transducers to two separate ports in a single network analyzer simultaneously. The acoustic wave emitted from a transducer induced a $3.16{\mu}W$ on the other side of the transducer at a distance of 2 cm. The transducer performances in terms of device diameters, PZT thickness, annealings, and different DC polings, etc. were investigated. COMSOL simulation was also performed to predict the device performances prior to fabrication. Based on the COMSOL simulation, the device was fabricated and the results were compared.