• Title/Summary/Keyword: Membrane structure

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Effect of Electrolyte on Preperation of Porous Alumina Membrane by Anodic Oxidation (양극산화에 의한 다공성 알루미나 막의 제조시 전해질의 영향)

  • Lee, Chang-Woo;Hahm, Yeong-Min;Kang, Hyun-Seop;Chang, Yoon-Ho
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.1047-1052
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    • 1998
  • The porous alumina membrane was prepared from aluminum metal(99.8%) by anodic oxidation using DC power supply of constant current mode in aqueous solution of sulfuric, oxalic, phosphoric and chromic acid. Pore size and distribution, membrane thickness, morphology and crystal structure were examined with several anodizing conditions : reaction temperature, electrolyte concentration, current density and electrolyte type. It was found that ultrafiltration membrane was fabricated in electrolyte of sulfuric, and oxalic acid. On the other hand, microfiltration membrane was fabricated in electrolyte of phosphoric, and chromic acid. Also, it was shown that crystal structure of porous alumina membrane prepared in sulfuric, oxalic, and phosphoric acid was amorphous, whereas porous alumina membrane prepared in chromic acid had ${\gamma}$ type of crystal structure.

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Comparison study of the effect of blending method on PVDF/PPTA blend membrane structure and performance

  • Li, Hongbin;Shi, Wenying;Zhang, Yufeng;Zhou, Rong
    • Membrane and Water Treatment
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    • v.6 no.3
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    • pp.205-224
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    • 2015
  • A novel hydrophilic poly (vinylidene fluoride)/poly (p-phenylene terephthalamide) (PVDF/PPTA) blend membrane was prepared by in situ polycondensation of p-phenylene diamine (PPD) and terephthaloyl chloride (TPC) in PVDF solution with subsequent nonsolvent induced phase separation (NIPS) process. For comparison, conventional solution blend membrane was prepared directly by adding PVDF powder into PPTA polycondensation solution. Blend membranes were characterized by means of viscometry, X-ray photoelectron spectroscopy (XPS), Field Emission Scanning Electron Microscopy (FESEM). The effects of different blending methods on membrane performance including water contact angle (WCA), mechanical strength, anti-fouling and anti-compression properties were investigated and compared. Stronger interactions between PVDF and PPTA in in situ blend membranes were verified by viscosity and XPS analysis. The incorporation of PPTA accelerated the demixing rate and caused the formation of a more porous structure in blend membranes. In situ blend membranes exhibited better hydrophilicity and higher tensile strength. The optimal values of WCA and tensile strength were $65^{\circ}$ and 34.1 MPa, which were reduced by 26.1% and increased by 26.3% compared with pure PVDF membrane. Additionally, antifouling properties of in situ blend membranes were greatly improved than pure PVDF membrane with an increasing of flux recovery ratio by 25%. Excellent anti-compression properties were obtained in in situ blend membranes with a stable pore morphology. The correlations among membrane formation mechanism, structure and performance were also discussed.

Solid-state NMR Studies of Membrane Proteins Using Phospholipid Bicelles

  • Kim, Yong-Ae
    • Bulletin of the Korean Chemical Society
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    • v.27 no.3
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    • pp.386-388
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    • 2006
  • Membrane proteins in highly oriented lipid bilayer samples are useful for membrane protein structure determination. We used in the past planar lipid bilayers which were aligned and supported on the glass slide. These samples were mechanically aligned in a magnetic field. However, these stacks of glass slides with planar lipid bilayers are not well suited for use with a commercial solid-state NMR probe with a round coil. Therefore, a homebuilt solid-state NMR probe was built and used with a stack of thin glass plates wherein the RF coil was wrapped directly around the flat square sample. Recently, we began to use magnetically aligned bicelles that are suitable for the structure determination of membrane proteins by solid-state NMR spectroscopy without any effort to build a flat square coil probe. These bicelle samples are well suited for use with a commercial solidstate NMR probe with a round coil, are very easy to prepare and are very stable, so that they can be kept for more than a year. In this paper, we present the solid-state NMR spectra of optimized and magnetically oriented bicelle samples of membrane proteins.

Shape Finding and Stress Finding for Pneumatic Membrane Structures by Dynamic Relaxation Method (동적이완법에 의한 공기막구조물의 형태탐색과 응력해석)

  • 문창훈;이경수;배종효;최옥훈;한상을
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1999.04a
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    • pp.268-275
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    • 1999
  • The purpose of this study is to propose the method of determining the initial pneumatic membrane structures surface and stresses and displacements. Tension structure such as pneumatic membrane structures is stabilized by their initial prestress and air pressure. The process to find initial structural overall shape of tension structures produced by initial prestress called shape finding. One of the most important factor for the design of membrane structures is to search initial smooth surface, because unlike steel or concrete building elements which resist loads in bending, all tension structure forces are carried within the surface by membrane stress. The result for initial surface of pneumatic membrane element and maximum displacement in large deformation in analysis is compared with well-known nonlinear numerical method such as Newton-raphson method and dynamic relaxation method

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Verification for Reduction of Membrane Stress Measurement Equipment Size Using White Noise Sound Wave (화이트노이즈를 이용한 막장력 측정장치의 소형·경량화 검증)

  • Jin, Sang-Wook
    • Journal of Korean Association for Spatial Structures
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    • v.14 no.3
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    • pp.67-74
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    • 2014
  • The author has proposed and verified the accuracy through experiments on a method of measurement through the use of sound waves that not only can quantitatively measure each of the dual directions of the fiber axis with high accuracy of membrane tension created on the surface of the membrane structure, but also can be easily operated in the field of construction. This paper reports the solution for problems of variables caused in the process of downsizing of the measurement equipment in order for practical use, and verifies the correspondence possibility of various stress ratios.

Preparation of Cross-linked Asymmetric Membrane and Control of Its Morphology and Mechanical Property

  • Hong, Byung-Pyo;Ko, Moon-Young;Kwon, Byeong-Min;Byun, Hong-Sik
    • Korean Membrane Journal
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    • v.10 no.1
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    • pp.1-7
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    • 2008
  • Polystyrene-co-divinylbenzene (PS-co-DVB) asymmetric membranes were prepared. In order to control their structure and mechanical properties the degree of cross-linking and the composition of casting solution were varied. The rubber added PS-DVB membranes was also prepared to overcome the mechanical limitation of cross-linked membrane, and their mechanical properties were investigated. It was revealed that the concentration of polymer in the casting solution affected the determination of skin formation. When the PS-co-DVB membrane consists of styrene-butadiene (SB) rubber or liquid polybutadiene (PBD), the structures formed showed that the PS content in the PS/DVB system played an important role in determining the porous sublayer structure.

The method using dynamic load and static load figures out gust factor of the membrane structure (동적하중과 정적하중을 이용한 막구조의 거스트 계수 산출 방법)

  • Wang, Ben-Gang;Jeong, Jae-Yong;You, Ki-Pyo;Kim, Young-Moon
    • Proceeding of KASS Symposium
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    • 2008.05a
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    • pp.19-24
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    • 2008
  • The thesis is for gust factor needing when calculate the wind resistance design. For the gust factor, to the membrane structural model, carry through the wind tunnel test and the static load test. Therefore, at first through the tensile test of the fabric material, designate the material of the membrane structural model. Then, to saddle, wave, arch and point four kinds of basic shape membrane structural models, carry on the wind tunnel test, determine their dynamic load and distortion on lateral direction. Finally, according to distort situation of the membrane structure in the wind tunnel test, carry on the static load experiment outside of the wind tunnel, calculate static load which corresponding with distort. According to dynamic load and the static load, figure out gust factor of these kinds of basic membrane structure.

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On the New Design of Liquid Dome Chair in Membrane Type LNG Carrier (멤브레인형 LNG선박의 리퀴드 돔 체어 구조개발)

  • Kim, Jeong-Hwan;Kim, Yooil
    • Journal of the Society of Naval Architects of Korea
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    • v.54 no.5
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    • pp.361-367
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    • 2017
  • A membrane type LNG cargo tank is equipped with a pump tower and a liquid dome for loading and unloading of LNG. However, the membrane running continuously on the tank wall to prevent leakage of LNG is interrupted by the liquid dome, hence care should be taken in the design of liquid dome and its substructures. In case of GTT NO96 membrane type cargo containment system, chair structure is arranged along the periphery of the liquid dome targeting to support the membrane which is exposed to the both hull girder and thermal load. This paper proposes a new and simple chair structure, which outperforms traditional design from productivity point of view maintaining same level of structural safety. Strength assessment on the new design was performed to guarantee the structural safety of the new design, which includes strength, fatigue and crack propagation analysis.

Thermal Analysis of Insulation System for KC-1 Membrane LNG Tank (KC-1 Membrane LNG 탱크 단열시스템의 열해석에 관한 연구)

  • Hyeon-won, Jeong;Tae-hyun, Kim;Seog-soon, Kim;W.Jaewoo, Shim
    • Journal of Ocean Engineering and Technology
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    • v.31 no.2
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    • pp.91-102
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    • 2017
  • Recently, a new type of LNG membrane Tank called the "KC-1 membrane LNG Tank" was developed by KOGAS (Korean Gas Corporation). It is necessary to estimate the temperature distribution of the hull structure and insulation system for this new LNG tank, as well as the BOR (Boil-Off Rate) when exposed to outside temperature conditions to ensure the integrity of the tank structure and limit LNG evaporation, from a safety evaluation point of view. In this study, temperature distribution calculations for the hull structure and insulation system of the KC1 membrane tank were compared by employing four numerical approaches under the IGC condition. Approaches 1-3 studied 2D simulations and approach 4 used a 3D numerical simulation. Approach 1 was calculated by in-house Excel VBA codes and the three other approaches utilized ANSYS Fluent. The BOR of approach 4, the 3D simulation case, for the IGC condition was 0.0986%/day.