• 한국산업융합학회 논문집
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• 제25권5호
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• pp.835-842
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• 2022

In this study, the membrane degassing process of the sweep gas - vacuum combination type was proposed for ammonia wastewater treatment. The effect of pH, initial ammonia concentration and scale-up on ammonia degassing performance was investigated. As a result, as the pH and the initial ammonia concentration increased, the degassing permeate flux was improved. On the other hand, the ammonia mass transfer coefficient increased as the initial ammonia reduced, which seems to be due to the driving force of the sweep gas-vacuum combination type membrane degassing system proposed in this study. In addition, 80 mg NH₃/min of the ammonia degassing rate was achieved using a 6×28 inch size module. Better degassing performance is expected if consideration for maintaining vacuum pressure is involved in the scale-up design.

• 한국산업융합학회 논문집
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• 제26권6_2호
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• pp.1171-1181
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• 2023

In this study, a sweep gas - vacuum hybrid type membrane degassing process was proposed for ammonia wastewater treatment. In addition, the ammonia selective recovery of the hybrid type membrane degassing process was also investigated. As a result, the hybrid type membrane degassing process showed better degassing performance (54.9 mg NH₃/m²min for 360 min) than the sweep gas type (32.3 mg NH₃/m²min) or vacuum type (22 mg NH₃/m²min). Additionally, the hybrid type membrane degassing process showed an excellent ammonia selectivity (103 times compared to Na+ Na⁺, 133 times compared to Ca²⁺). The ammonia selectivity was appeared to be due to the conversion characteristics of ammonium ion / dissolved ammonia depending on pH. The results in this study are expected to be used in the development of ammonia wastewater treatment and ammonia recovery in the future.

• 한국막학회:학술대회논문집
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• 한국막학회 2001년도 제14회 심포지엄 : 제2회 분리막 표준화(The 2nd Standardization of Membranes)
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• pp.113-138
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• 2001

• Fibers and Polymers
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• 제7권2호
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• pp.186-190
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• 2006

The application of a degassing system to mercerization process was investigated. It was found that the physical properties of cotton fabrics mercerized in the degassed NaOH solution were superior to those mercerized in NaOH solution. The degree of penetration of the degassed water was examined by measuring wicking height. The wicking height in the degassed water without the wetting agent is higher than that of the saturated water with 0.1 % of wetting agent.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2003년도 가을 학술발표회 논문집
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• pp.185-186
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• 2003

막을 이용한 분리기술은 다양한 종류의 혼합물에서 원하는 물질을 분리 정제하는 기술로 여기에는 고-액, 액-액, 기-액분리가 모두 포함된다 현재까지 분리공정은 주로 여과, 증류, 추출, 흡착등 방법이 있으나 에너지소비가 많고, 설비투자비가 많이 들며 효율이 낮아 비경제적이라는 문제점을 가지고 있고 이와 같은 문제점을 해결하기 위하여 최근 주목받고 있는 기술이 막을 이용한 분리기술이다. 막을 이용한 분리기술의 장점은 앞서 언급한 바와 같이 에너지소비와 설비비를 최소화하면서도 고효율의 분리효과를 얻을 수 있다는 점에 있다. (중략)

• 한국막학회:학술대회논문집
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• 한국막학회 2003년도 The 4th Korea-Italy Workshop
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• pp.133-135
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• 2003

The removal of dissolved oxygen(DO) from water was studied using a poly(vinyliene fluoride)(PVDF) hollow fiber membrane contactor(HFMC) with the vacuum degassing process(VDP), Asymmetric porous PVDF hollow fiber membranes (HFM) for membrane contactor were prepared by a wet phase inversion method. In spinning of these PVDF hollow fibers, dimethy lacetamide (DMAc), LiCl and pure water were used as a solvent, a pore-forming additive and internal/external coagulant, respectively. The characteristics of the structure(pore size, porosity etc.) of the prepared PVDF HFMs as a function of concentration of pore-forming additive in polymer dope solution were studied. Also, the removal efficiency of DO from water according to flow rates of water, using PVDF HFMC with VDP, was studied. The performance of the asymmetric porous PVDF HFMC and a symmetric porous PP HFMC commercialized were compared. As a result, the asymmetric porous PVDF HFMC showed higher removal efficiency of DO than that of a symmetric porous PP HFMC.

• 멤브레인
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• 제30권5호
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• pp.326-332
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• 2020

본 연구에서는, 혐기성 처리수에 용해된 바이오가스의 회수를 위해 불화 실리카/고분자 중공사 복합막을 제조하고 막접촉기에서의 성능을 평가하였다. 복합막은 상용 폴리에테르이미드인(PEI) Ultem^®을 이용하여 만든 중공사막 표면에 불화 실리카를 강력한 공유 결합을 통해 코팅하는 방법으로 제조되었다. 막접촉기는 바이오가스로 포화된 수용액을 중공사의 외부에 공급하고, 중공사 내부로 기체를 투과시키는 방법으로 운전하였다. 높은 공극률을 가진 중공사막(PEI-fSiO₂-A)은 액상 속도가 0.03 m/s일 때 메탄 회수 유량이 8.25 × 10^-5 ㎤ (STP)/㎠·s에 달했고 불화 실리카에 의해 표면 소수성이 매우 높아져 물과의 접촉각이 75.6°에서 120~122°로 향상되었다. 본 연구에서 제조된 복합막은 바이오가스의 투과 속도와 소수성 모두에서 탈기용으로 제조된 상용 폴리프로필렌 막보다 우수한 성능을 나타냈다.