• 제목/요약/키워드: Melt-spun

검색결과 152건 처리시간 0.032초

Imparting Disperse and Cationic Dyeability to Polypropylene through Melt Blending

  • Teli M. D.;Adivarekar R. V.;Ramani V.Y.;Sabale A.G.
    • Fibers and Polymers
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    • 제5권4호
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    • pp.264-269
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    • 2004
  • The present paper deals with improvement in disperse dyeablility as well as imparting of cationic dyeablility to difficultly dyeable polypropylene by a melt blending technique. Isotactic polypropylene (PP) was blended with fibre grade polybutylene terephthalate (PBT), cationic dyeable polyethylene terephthalate (CDPET) and polystyrene (PS), individually. The resulting binary blends were spun and drawn into fibres at draw ratio 2, 2.5, and 3. The compatibility of blends, structural changes of fibres in terms of X-ray crystallinity, relative crystallinity, sonic modulus, birefringence and thermal stability were examined. The blended fibres were found to be disperse dyeable by the conventional method of high temperature and high pressure dyeing. And this dye ability increased with increase in the level of substitution. PP/CDPET blend also exhibited dyeablility with cationic dyes in addition to that with disperse dyes. The optimum level of blending was predicted keeping in view of tenacity and thermal stability of melt blend fibres. The wash fastness properties of the dyed fibres were found to be of high rate.

급속응고중 외부자장에 의한 Nd-Fe-Co(-Zr)-B계 합금의 자기이방성 향상 (The Effect of Magnetic Field on Enhancing the Anisotropy of Melt-spun Nd-Fe-Co(-Zr)-B Alloy)

  • 이우영;최승덕;양충진
    • 한국자기학회지
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    • 제2권3호
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    • pp.233-238
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    • 1992
  • 유도용해법으로 $Nd_{14}Fe_{76}Co_4B_6$합금 및 $Nd_{10.5}Fe_{79}Co_2Zr_{1.5}B_7$합금의 급냉리본을 제조하고, 냉각속도와 급냉중 외부자장력이 결정이방성과 자기특성에 미치는 영향을 조사하였다. 토크자력계로 측정한 두 합금의 결정자기 이방성은 냉각속도가 증가함에 따라 급격히 감소하였다. 가장 우수한 자기 특성은 두 합금 모두 냉각속도 $V_s$=11 m/s에서 얻어졌으며, 자장중 급냉한 합금의 결정자기이방성 상수가 자장없이 급냉한 합금보다 30~40 % 높게 측정되었다. 외부 자장하에서 급냉된 $Nd_{10.5}Fe_{79}Co_2Zr_{1.5}B_7$합금은 냉각속도 $V_s$=11 m/s에서 $B_r$=8.82 kG, $_iH_c$=9.85 kOe 및 $(B{\cdot}H)_{max}$=16.4 MGOe의 우수한 자기특성을 보인다.

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Characterization of Structure and Motion of High-Speed Melt Spun Nylon 6 Fibers by Solid-State NMR Spectroscopy

  • 김준형;곽승엽;정호규;권익현;김상용
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1998년도 가을 학술발표회논문집
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    • pp.264-267
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    • 1998
  • 고속용융방사는 권취속도의 고속화에 의해 공정시간 및 제조비용 절감을 통해 생산성을 극대화할 수 있어 산업적으로 아주 중요한 섬유 형성 공정이다 또한 생산성의 향상을 위해 방사속도가 증가하는 추세인데, 이러한 경향은 공정-구조-역학적 성질의 관계를 정립해야 하는 필요성을 증가시키고 있다. (중략)

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브롬화 에폭시 수지와 나일론 6의 상용성 및 블렌드 수지의 물성에 관한 연구 (Study on the Compatibility of Brominated Epoxy Resin with Nylon 6 and the Characterization of the Blends)

  • 김환철
    • 한국염색가공학회지
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    • 제22권2호
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    • pp.155-162
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    • 2010
  • Nylon 6 was blended with a brominated epoxy resin, tetrabromobisphenol A diglycidyl ether (DGEBBA), to enhance flame retardant property. Thermal properties of the blends were analyzed by DSC. Melting point and crystallization temperature decreased as the amount of epoxy resin increased. Melt index and relative viscosity decreased as the amount of the epoxy resin increased. When the blended amount of the epoxy resin was below 5%, the melt index decreased while the relative viscosity slightly increased. The blend resin was successfully spun into fiber without swelling or drawing the resonance phenomena. However, both the tenacity and elongation of the fiber decreased by increasing the amount of the DGEBBA.

Glassy Dynamics in Giant Magnetoresistive Melt-spun Co-Cu

  • Idzikowski, B.;RoBler, U.K.;Handstein, A.;Eckert, D.;Wolf, M.;Nenkov, K.;Muller, K.H.
    • Journal of Magnetics
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    • 제4권3호
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    • pp.76-79
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    • 1999
  • We report results on metastable CuCo ribbons at low Co contents (2 and 10 at %), which were prepared by conventional melt-spinning technique and subsequent annealing. The properties of these materials cannot consistently be described by those of an assembly of superparamagnetic single-domain particles. Magnetic measurements related to magnetic dynamics reveal spin-glass-like properties. Especially, we find very slow nonequilibrium relaxation processes in Co10Cu90, which depend on prehistory, when probing the relaxation of the resistivity. The results are clear evidence for frustrated interaction effects due to magnetic couplings between Co clusters or precipitates in these alloys.

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급냉응고된 Mg-Al-Si-xCa 합금의 시효경화 및 미세조직 (Age Hardening and Microstructure in Rapidly Solidified Mg-Al-Si-xCa Alloys)

  • 김완철;박지하;류봉선;박원욱
    • 한국주조공학회지
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    • 제19권5호
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    • pp.433-439
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    • 1999
  • Rapidly solidified Mg-Al-Si base alloys containing Ca were obtained by melt spinning. The melt-spun ribbons were aged isochronally or isothermally to investigate age hardening phenomena and microstructural change according to the alloy composition. Age hardening occurred after aging at $200^{\circ}C$ for 1h mainly due to the precipitation of $Al_2Ca$ and $Mg_2Ca$, which have coherent interfaces with the matrix. With the increase of Ca content, the hardness values of the alloy ribbons were increased. Among the alloys, Mg-10Al-2 Si-3Ca alloy showed a good thermal stability at elevated temperature.

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