• Bulletin of the Korean Chemical Society
• /
• v.35 no.6
• /
• pp.1901-1903
• /
• 2014

• Proceedings of the Korean Society of Rheology Conference
• /
• 2001.09a
• /
• pp.164.2-164
• /
• 2001

• The Korean Journal of Rheology
• /
• v.7 no.3
• /
• pp.173-180
• /
• 1995

LLDPE/LDPE 혼합물의 유변 물성과 필름가공특성 필름 물성 및 LLDPE의 extrudate 표면상태를 살펴보았다. LLDPE에 LDPE를 혼합함으로써 용융 강도가 크게 향상 되는 것을 볼수 있었으며 혼합비에 따라 필름의 기계적 물성이 변화하는 것을 볼수 있었다. 즉 최고의 물성을 나타내는 적절한 혼합비율이 존재하였다. 본논문에 사용된 LLDPE/LDPE 혼합물에 있어서는 LDPE의 함량이 15∼30wt%일 때 가장 우수한 기계적 물성을 얻을수 있 었다. LLDPE 필름의 표면 불량 문제를 보기위하여 capillary를 이용하여 LLDPE extrudate 의 표면 튀틀림(distortion)의 진행순서를 살펴본 결과, 전단 응력이 0.23MPa 일때 sharkskin이 발현함을 볼수 있었다.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.18 no.3
• /
• pp.69-73
• /
• 2010

The melt grafting of unsaturated silanes onto polypropylene (PP) in a twin-screw extruder and crosslinking in hot water were studied to enhance impact strength of polypropylene. The influence of grafting formulations on the melt flow rates of grafted PP and the gel percentages of crosslinked PP was investigated. 3-methacryloylpropyltrimethoxysilane (VMMS) unsaturated silane monomer was used. Benzoyl peroxide, (BPO) and Dicumyl peroxide (DCP) were used as an initiator. When benzoyl peroxide (BPO) was used as an initiator, higher gel percentage and impact strength than those of DCP has been observed. The maximum impact strength was obtained with 0.7 phr of BPO and 2phr of VMMS. The value is 8.7 kgf-cm/cm and it is on a parity with the value of with 20 phr of EOR mixed to PP.

• Journal of Adhesion and Interface
• /
• v.7 no.4
• /
• pp.28-31
• /
• 2006

Due to the miniaturization of MEMS and microelectronics the joining techniques also have to be adjusted. The dosing technology with viscous adhesives does not permit reproducible adhesive volumes, which are clearly under a nano-liter. A nano-liter means however a diameter of bonding area within the range of several 100 micrometers. Additional, viscous adhesives need a certain time, until they are cross linked or cured. The problem especially in the MEMS is the initial strength, since it gives the time, which is needed for joining an individual adhesive joint. The time up to the initial strength is with viscous, also with fast curing systems, within the range of seconds until minutes. Until the reach of the initial strength, the micro part must be fixed/held. Without sufficient adjustment/clamping it can come to a shift of the micro parts. Also existing micro adhesive bonding processes are not batch able, i.e. the individual adhesive joints of a micro system must be processed successively. In the context of the WCARP III 2006 now an innovative method is to be presented, how it is possible to solve the existing problems with micro bonding. i.e. a method is presented, which is batch able, possess a minimum joining geometry with some micrometers and is so fast that no problems with the initial strength arise. It is a method, which could revolutionize the sticking technology in the micro system engineering.

• Applied Chemistry for Engineering
• /
• v.7 no.1
• /
• pp.194-202
• /
• 1996

Hot melt adhesive based on the polyamide resin was studied to improve the conventional hot melt adhesives such as ethylene-vinyl acetate which have inherent problems against creep and heat resistance. It was found that the terpolymer of nylons6, nylon66, and nylon12 or the nylon blend instead of nylon homopolymer was suitable base resin for hot melt adhesives, since the disruption of regularity in the polymer chains reduced the crystallinity, resulting in lower melting point and melt viscosity. Also, the rheological properties of the polyamide based hot melt adhesive could be controlled by the incorporation of terpene resin, butyl benzyl phthalate, and paraffin wax. The results of melt viscosities and tensile properties of adhesive itself indicated that the optimum adhesion properties could be obtained through the blending of CM831/843P resins with weight ratio 75/25~50/50. The adhesion between steel and steel was tested by using lap shear geometry. It was found that the surface roughness of steel affected the adhesion strength.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.5 no.1
• /
• pp.27-32
• /
• 2006

Thermoplastic elastomer(TPE) has many advantages such as high flexibility, high elasticity and high elongation, etc. TPE is easily molded as plastic materials, therefore, many TPE parts are applied as home appliances and mechanical parts. However, its mechanical properties would be changed by injection molding conditions such as melt temperature, mold temperature, injection pressure and holding pressure, etc. In this study, the influences of the injection molding condition on the mechanical properties as tensile strength, hardness of thermoplastic vulcanizates(TPVs), which is one of the TPE, were investigated. By the injection molding experiment, the molding's tensile strength and hardness was influenced on the melt temperature and composition ratio of PP and EPDM. The morphology of moldings were shown by the scanning electron microscope.

• Design & Manufacturing
• /
• v.6 no.2
• /
• pp.1-5
• /
• 2012

Weld line in injection molded part is one of the defects in injection molding process. Weld line deteriorates not only appearance quality but mechanical property. In this study, ABS and PP were used as experimental materials. And weld line length, depth and strength have been examined according to the injection molding conditions. As the results of experimental studies, weld line length increased as flow rate increases for all materials. And the flow rate is most influenced to the creation of weld line length. Also weld line strength increased, as flow rate and melt temperature increase for all materials. The whole experiment results was similar to CAE analysis results.

• Textile Coloration and Finishing
• /
• v.22 no.1
• /
• pp.37-42
• /
• 2010

ABS/MWNT nanocomposites were prepared by using MWNT wrapped with SAN through melt compounding. Effect of wrapping of MWNT by SAN on the morphology, mechanical and electrical properties of ABS/MWNT were analyzed. It was found that SAN could wrap MWNT effectively indicated by the increased thickness after wrapping, which is presumably due to helical structure of polyacrylonitrile component in a block copolymer of SAN. MWNT was observed to be dispersed more evenly in ABS matrix by SAN wrapping, which resulted in improved tensile properties of the composites. On the other hand, there was little effect on the impact strength and electrical properties of ABS having inherently high impact strength.

• 한국금형공학회:학술대회논문집
• /
• 2008.06a
• /
• pp.115-119
• /
• 2008

Weld line in injection molded part is one of the defects in injection molding process. Weld line deteriorates not only appearance quality but mechanical property. In this study, ABS and PP were used as experimental materials. And weld line length, depth and strength have been examined according to the injection molding conditions. As the results of experimental studies, weld line length increased as flow rate increases for all materials. And the flow rate is most influenced to the creation of weld line length. Also weld line strength increased, as flow rate and melt temperature increase for all materials. The whole experiment results was similar to CAE analysis results.