• Title/Summary/Keyword: Melt infiltration

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Effect of Alloying Elements on Particulate Dispersion Behavior and Mechanical Properties in TiC Particulate Reinforced Magnesium Matrix Composites (TiC 입자강화 Mg 복합재료에 있어서 입자 분산거동 및 기계적 성질에 미치는 합금원소의 영향)

  • Lim, Suk-Won;Choh, Takao;Park, Yong-Jin
    • Journal of Korea Foundry Society
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    • v.14 no.3
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    • pp.240-247
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    • 1994
  • TiC particulate reinforced magnesium matrix composites were fabricated by melt stirring method. The effect of alloying elements on TiC particulate dispersion into molten magnesium and mechanical properties were investigated. The incorporation time is defined as the time required for dispersion of solid particles into molten metal. The incorporation time of TiC particles into molten pure magnesium was remarkably shorter and the particulated dispersion was more uniform than that of pure aluminum which was reported previously. The incorporation time was, prolonged by the addition of Al, Bi, Ca, Ce, Pb, Sn or Zn. The tensile strength increased and elongation decreased by the addition of Cu or Sn into the matrices and composites. Although, the tensile strength of the matrices and composites increased by alloying with Ca or Ce, the maximum elongation was observed at a content of about 1% for the matrices. By alloying with Zn, the tensile strength increased for the matrices and composites, but the elongation of the matrices increased. The pure magnesium and its alloy matrix composites reinforced with 20vol% TiC have the tensile strength of about 400MPa. This value is compared with the tensile strength of SiC whisker reinforced magnesium matrix composites fabricated by liquid infiltration method at the same volume fraction. There fore, the melt strirring method which has the advantages of simple process is considered to be efficient in fabricating magnesium matrix composites.

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A Groundwater Quality Assessment of the Shallow Aquifers in the Rural Area of Yongin (경기도 용인시 일대 천부 지하수의 수질특성 연구)

  • 우남칠;최미정;정성욱;이승구
    • Journal of the Korean Society of Groundwater Environment
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    • v.6 no.2
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    • pp.53-58
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    • 1999
  • This study was carried out evaluate to identify water quality and contamination characteristics of the shallow groundwater. and their seasonal variation in the rual area of the Yongin city. Groundwater sample were collected two times (in April and September) from a total of 19 well for domestic water supply. and surface-water samples from six locations. For cations, Ca and Mg predominated. In anion competition. the influence of Cl was obvious in the april samples. However. HCO$_3$ was a major component in the september samples. Electric conductivities and the concentrations of NO$_3$-N in groundwater samples significantly decreased from the april samples to the september samples This indicates a significant seasonal variation in the shallow groundwater composition. When the shallow aquifer is connected to the surface water. then metals sorbed on the stream sediments could occur at nearby wells through the induced recharge. Contaminants at ground surface appeared to be transported to the groundwater system infiltration during the spring melt.

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Characteristic Evaluation of the Fe-Al Alloy Preform Fabrication by Reactive Sintering Process for the Al Matrix Composites. (반응소결법으로 제조한 Al기 복합재용 Fe-Al합금 예비성형체의 특성평가)

  • Choi, Dap-Chon;Park, Sung-Hyuk;Joo, Hyung-Gon
    • Journal of Korea Foundry Society
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    • v.19 no.6
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    • pp.493-500
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    • 1999
  • Squeeze casting was used for fabricating a light metal base composite having high strength and wearresistance. Reactive sintering was used to prepare the preform of Squeeze casting. To utilize Fe-Al intermetallic compounds and SiC particle as a reinforcement, there needs to prepare Fe-Al mixed powder at 50, 60, 70at.%Al, and add SiC powder to the above mixture at 4, 7, 16, 24wt.%. The prepared mixture with SiC was reactive sintered in a tube furnace at $660^{\circ}C$ to get a porous hybrid preform of intermetallic compound and SiC. The preform prepared above was placed in a metal mold, preheated at $660^{\circ}C$ AC4C matrix was injected into the mold with the temperature of the melt at $610^{\circ}C$ After these processes, 66MPa was applied to the mold for 5 minute to finish the whole procedure. The maximum reaction temperature was increased with the increased Al amount, but decreased with the increased SiC amount. The density of the preform was decreased with SiC amount increase in the compacts due to swelling of the preform. An optical microscope was applied to observe the micro structure and the dispersion of the reinforcements. To analyze phases, We utilized XRD, EDS. Hardness test were chosen to get the information of mechanical properties. There were no significant changes in micro structure between the composite and preform. However, it was shown that uniform dispersion of the reinforcers and complete infiltration of the melt into the preform were achieved through the procedure of the squeeze casting. It was observed that the hardness of the composite is decreased with increased SiC amount, resulting from the volumetric expansion of the preform.

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Mechanical Properties of SiCp/AC8A Composites Fabricated by Pressureless Metal Infiltration Process (무가압함침법으로 제조한 SiCp/AC8A 복합재료의 기계적 성질)

  • 김재동;고성위;김형진
    • Composites Research
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    • v.15 no.3
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    • pp.1-10
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    • 2002
  • The effect of size of SiC particles and additive Mg content on the mechanical properties and wear characteristics were investigated for the SiCp/AC8A composites fabricated by pressureless infiltration process. Results showed that the hardness and the bending strength increased with decreasing the size of SiC particle. By increasing the Mg content the hardness of SiCp/AC8A composites increased due to the hard reaction products, however the bending strength decreased by formation of coarse precipitates and high porosity level. The SiCp/AC8A composites exhibited about 6 times higher wear resistance compared with AC8A alloy at high sliding velocity and as increasing the particle size, wear resistance was improved. The major wear mechanical of SiCp/AC8A composites exhibited the abrasive wear at low to high sliding velocity whereas AC8A alloy showed adhesive and melt wear at high sliding velocity.

A Study on the Fabrication Process and Melt Infiltration of Salt Core in Squeeze Casting Method (스퀴즈캐스팅용 Salt Core의 제조 및 용탕침투성에 관한 연구)

  • Kim, Ki-Bae;Noh, Sang-Woo;Lee, Ho-In;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.17 no.4
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    • pp.402-410
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    • 1997
  • Developing a salt core for squeeze casting process, two different salt cores(pure salt core and mixed salt core) were fabricated and investigated. Pure salt core was composed of 100% NaCl and mixed salt core was made by mixtures of NaCl with MgO(1%), $Na_2B_4O_7$(2%), and talc(1%) as a binder or a strengthening agent. Salt cores were compacted to various theoretical density, heat treated, and then squeeze-cast with molten Al alloy(AC8A). The compression strength of salt cores were measured and the squeeze-cast products were examined for shape retention, infiltration of molten metal into the cores, and microstructures. The shape of salt core compacted at above 75% of the theoretical density was maintained stably. The higher theoretical density of salt cores gave higher compression strength, and the compression strength of mixed salt core was higher than that of pure salt core. Namely at 90% theoretical density, the compression strength of mixed salt core was $6.3 kg/mm^2$, compared to $4.6 kgmm^2$ for pure salt core. At a squeeze casting pressure of $1000 kg/cm^2$, molten Al alloy was infiltrated into pure salt core of under 85% of the theoretical density. At squeeze casting pressure of $1000 kg/cm^2$, only mixed salt core above 90% of the theoretical density were valid, but the shape of the core was altered in the case of pure salt core at 90% of theoretical density. A key factor for developing a salt core for squeeze casting process was estimated as the ultimate compressive strength of salt core.

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Mechanical Properties and Wear Behaviour of $Al/SiC/Al_{2}O_{3}$ Composite Materials ($Al/SiC/Al_{2}O_{3}$복합재료의 기계적 성질 및 마멸특성)

  • 임흥준;김영한;한경섭
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.10
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    • pp.2498-2508
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    • 1993
  • $Al/SiC/Al_{2}O_{3}$ hybrid composites are fabricated by squeeze infiltration method. From the misconstructive of $Al/SiC/Al_{2}O_{3}$ hybrid composites fabricated by squeeze infiltration method, uniform distribution of reinforcements and good bondings are found. Hardness value of $Al/SiC/Al_{2}O_{3}$ hybrid composites increases linearly with the volume fraction of reinforcement because SiC whisker and $Al_{2}$O$_{3}$ fiber have an outstanding hardness. Optimal aging conditions are obtained by examining the hardness of $Al/SiC/Al_{2}O_{3}$ hybrid composites with different aging time. Tensile properties such as Young's modulus and ultimate tensile strength are improved up to 30% and 40% by the addition of reinforcements, respectively. Failure mode of $Al/SiC/Al_{2}O_{3}$ hybrid composites is ductile on microstructural level. Through the abrasive wear test and wear surface analysis, wear behaviour and mechanism of 6061 aluminum and $Al/SiC/Al_{2}O_{3}$ hybrid composites are characterized under various testing conditions. The addition of SiC whisker to $Al/SiC/Al_{2}O_{3}$ composites gives rise to improvement of the wear resistance. The wear resistance of $Al/SiC/Al_{2}O_{3}$ hybrid composites is superior to that of Al/SiC composites. The wear mechanism of aluminum alloy is mainly abrasive wear at low speed range and adhesive and melt wear at high speed range. In contrast, that of $Al/SiC/Al_{2}O_{3}$ hybrid composites is abrasive wear at all speed range, but severe wear when counter material is stainless steel. As the testing temperature increases, wear loss of aluminum alloy decreases because the matrix is getting more ductile, but that of $Al/SiC/Al_{2}O_{3}$ hybrid composites is hardly varied. Oil lubricant is more effective to reduce the wear loss of aluminum alloy and $Al/SiC/Al_{2}O_{3}$ hybrid composites at high speed range.

Effect of Hot Extrusion on the Mechanical Properties of 6061 Aluminum Alloy composites Reinforced with SiC whisker (SiC휘스커로 강화한 6061 Al합금 복합재료의 기계적 특성에 미치는 열간압출의 영향)

  • Kim, Jun-Su;Lim, Su-Geun
    • Journal of Korea Foundry Society
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    • v.16 no.2
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    • pp.132-140
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    • 1996
  • Both cast and extruded composites of SiC whisker reinforced 6061 Al alloy matrix were fabricated by high pressure infiltration of the alloy melt into the SiC preform and subsequent hot extrusion of the composite ingots. The micro structures, age hardening behavior and mechanical properties have been examined on the both cast and extruded composites of SiCw/6061. The cast composites of SiCw/6061 were obtained in which SiC whiskers were randomly oriented. Hot extrusion of these cast composites lead to alignment of the whisker in the direction of extrusion. Strengthening effect of whisker in the extruded composites is lower than that of the cast composites. The cast composites of SiCw/6061 showed higher thensile strength and lower elongation than extruded composites of SiCw/6061 at all testing temperatures. Lower tensile strength and higher elongation of the extruded composites were attributable to fine grain structures in which grain boundary sliding occruued preferentially at elevated temperatures.

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Fabrication of $Al_2O_3/Al$ Composites by Replacement Reaction of Molten Metal Al (용융 Al의 치환반응에 의한 $Al_2O_3/Al$ 복합체의 제조)

  • 정두화;김용진;배원태
    • Journal of the Korean Ceramic Society
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    • v.34 no.6
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    • pp.591-600
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    • 1997
  • Al2O3/Al composites were produced by displacement reaction method, which was carried out by immersing the sintered silica preform, which was prepared from fused silica powder, in molten aluminum. Because the molten aluminum did not penetrate into the silica preform with higher than 20% of porosity when the displacement reaction was accomplished at 100$0^{\circ}C$ for 10 hours in air atmosphere, the optimum range of sintering temperature of silica preform was from 135$0^{\circ}C$ to 140$0^{\circ}C$. The microstructure of this Al2O3/Al composites showed three-dimentionally co-continuous alumina, which provides wear resistance and high stiffness, and aluminium which acts as a toughnening phase. The grain size of the alumina in composites did not change with the particle size of the silica preform. The exact shape of the preform was retained and a net-shaped composite was produced. The representative Al2O3/Al composite prepared in this study showed 3.30mg/㎤ of bulk density, 350-430 MPa of flexural strength, 7.0 MPa.m1/2 of fracture toughness, and good machinability.

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Influences of Fractionation of Stable Isotopic Composition of Rain and Snowmelt on Isotopic Hydrograph Separation (강우와 융설의 안정동위원소 변동에 의한 동위원소 수문분리법의 계통오차계산)

  • Lee, Jeonghoon;Koh, Dong-Chan;Choo, Mi Kyung
    • Journal of the Korean earth science society
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    • v.35 no.2
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    • pp.97-103
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    • 2014
  • An isotopic hydrograph separation technique has been able to determine the contribution of new water (event water such as rain or snowmelt) and old water (pre-event water like groundwater) to a stream hydrograph for last several decades using stable water isotopes. It is based on the assumption that the isotopic compositions of both new water and old water at a given instant in time are known and the stream water is a mixture of the two waters. In this study, we show that there is a systematic error (standard error in the new water fraction) in the isotopic hydrograph separation if the average isotopic compositions of new water were used ignoring the temporal variations of those of new water. The standard error in the new water fraction is caused by: (1) the isotopic difference between the average value and temporal variations of new water; (2) the new water fraction as runoff contributing to the stream during rainfall or spring melt; and (3) the isotopic differences between new and old water (inversely). The standard error is large, in particular, when new water dominates the stream flow, such as runoff during intense rainfall and in areas of low infiltration during spring melt. To reduce the error in the isotopic hydrograph separation, incorporation of fractionation in the isotopic composition of new water observed at a point should be considered with simultaneous sampling of new water, old water and stream water.

EFFECT OF $CEO_2$ ADDITION IN GLASS COMPOSITION ON THE STRENGTH OF ALUMINA-GLASS COMPOSITES (알루미나-유리 복합체용 글래스의 조성에서 $CeO_2$의 함량변화가 강도에 미치는 영향)

  • Lee, Hwa-Jin;Song, Kwang-Yeob;Kang, Jeong-Kil
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.5
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    • pp.595-605
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    • 2000
  • Dental ceramics have good aesthetics, biocompatibility, low thermal conductivity, abrasion resistance, and color stability. However poor resistance to fracture and shrinkage during firing process have been limiting factors in their use, particularly in multiunit ceramic restorations. A new method for making all-ceramic crowns that have high strength and low processing shrinkage has been developed and is referred to as the Vita In-Ceram method. This study was performed to investigate the effect of $CeO_2$ addition in borosilicate glasses on the strength of alumina-glass composites. Porous alumina compacts were prepared by slip casting and sintered at $1,100^{\circ}C$ for 2 hours. Dense composites were made by infiltration of molten glass into partially sintered alumina at $1,140^{\circ}C$ for 4 hours. Specimens were polished sequentially from #800 to #2000 diamond disk. and the final surface finishing on the tensile side was received an additional polishing sequence through $1{\mu}m$ diamond paste. Biaxial flexure test was conducted by using ball-on-three-ball method at a crosshead speed of 0.5mm/min. To examine the microstructural aspect of crack propagation in the alumina-glass composites, Vickers-produced indentation crack was made on the tensile surface at a load of 98.0 N and dwell time of 15 sec, and the radial crack patterns were examined by an optical microscope and a scanning electron microscope. The results obtained were summarized as follows; 1. The porosity rates of partially sintered alumina decreased with the rising of firing temperature. 2. The maximum biaxial flexure strength of 423.5MPa in alumina-glass composites was obtained with an addition of 3 mol% $CeO_2$ in glass composition and strength values showed the aspect of decrease with the increase of $CeO_2$ content. 3 The biaxial flexure strength values of alumina-glass composites were decreased with rising the firing temperature. 4. Observation of the fracture surfaces of alumina-glass composites indicated that the enhancement of strength in alumina-glass composites was due to the frictional or geometrical inter-locking of rough fracture surfaces and ligamentary bridging by intact islands of materials left behind the fracture front.

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