• Korea-Australia Rheology Journal
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• v.13 no.1
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• pp.1-12
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• 2001

This paper describes the application of our recently developed two-phase model for flow-induced crystallization (FIC) to the simulation of fiber spinning and film blowing. 1-D and 2-D simulations of fiber spinning include the combined effects of (FIC), viscoelasticity, filament cooling, air drag, inertia, surface tension and gravity and the process dynamics are modeled from the spinneret to the take-up roll device (below the freeze point). 1-D model fits and predictions are in very good quantitative agreement with high- and low-speed spinline data for both nylon and PET systems. Necking and the associated extensional softening are also predicted. Consistent with experimental observations, the 2-D model also predicts a skin-core structure at low and intermediate spin speeds, with the stress, chain extension and crystallinity being highest at the surface. Film blowing is simulated using a "quasi-cylindrical" approximation for the momentum equations, and simulations include the combined effects of flow-induced crystallization, viscoelasticity, and bubble cooling. The effects of inflation pressure, melt extrusion temperature and take-up ratio on the bubble shape are predicted to be in agreement with experimental observations, and the location of the frost line is predicted naturally as a consequence of flow-induced crystallization. An important feature of our FIC model is the ability to predict stresses at the freeze point in fiber spinning and the frost line in film blowing, both of which are related to the physical and mechanical properties of the final product.l product.

• Advanced Composite Materials
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• v.17 no.3
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• pp.191-214
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• 2008

Polypropylene/layered silicate nanocomposites containing maleic anhydride grafted polypropylene were prepared by melt compounding and their rheological behavior was investigated in shear flow. Transient and steady shear flows were simulated numerically by using the K-BKZ integral constitutive equation along with experimentally determined damping functions under dynamic oscillatory and step strain shear flows. Nonlinear shear responses were predicted with the K-BKZ constitutive equation using two different damping functions such as the Wagner and PSM models. It was observed that PP-g-MAH compatibilized PP/layered silicate nanocomposites have stronger and earlier shear thinning and higher steady shear viscosity than pure PP resin or uncompatibilized nanocomposites at low shear rate regions. Strong damping behavior of the PP/layered silicate nanocomposite was predicted under large step shear strain and considered as a result of the strain-induced orientation of the organoclay in the shear flow. Steady shear viscosity of the pure PP and uncompatibilized nanocomposite predicted by the K-BKZ model was in good agreement with the experimental results at all shear rate regions. However, the model was inadequate to predict the steady shear viscosity of PP-g-MAH compatibilized nanocomposites quantitatively because the K-BKZ model overestimates strain-softening damping behavior for PP/layered silicate nanocomposites.

• Polymer(Korea)
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• v.35 no.6
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• pp.593-598
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• 2011

The IPA-co-HDO-co-(TPA/MA) copolymers for all-vanadium redox flow battery were synthesized by melt condensation polymerization using isophthalic acid(IPA), 1,6-hexandiol (HDO), terephthalic acid(TPA) and maleic anhydride(MA). The amination of chloromethylated IPA-co- HDO-co-(TPA/MA)(CIHTM) copolymer was carried out using trimethylamine, and the anion exchange membrane was also prepared by UV crosslinking reaction. The structure and thermal stability of IHTM copolymers were confirmed by FTIR, $^1H$ NMR, and TGA analysis. The anion membrane properties such as water uptake, ion exchange capacity, electric resistance and electrical conductivity, were measured by gravimetry, titration and LCR meter. The efficiency of the all-vanadium redox flow battery was analyzed. The ion exchange capacity, electric resistance and electrical conductivity were 1.10 meq/g, $1.98{\Omega}{\cdot}cm^2$, and 0.009 S/cm, respectively. The efficiency of charge-discharge, voltage, and energy for the allvanadium redox flow battery were 96.5, 74.6, 70.0%, respectively.

• Design & Manufacturing
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• v.6 no.1
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• pp.5-11
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• 2012

The sink mark on boss parts is generated by the volumetric shrinkage that is caused by both the molding thickness and the boss wall thickness. The volumetric shrinkage is caused by packing pressure and its amount tends to decrease by increasing the packing pressure. The packing pressure can therefore increase the flow rate to a boss part and causes the depth of sink mark to increase. As the molding thickness and the boss wall thickness in the boss part can increase the part volume, these may yield bad solidifying and also extend the molding cycle. In this paper, both the injection molding test and the flow analysis were carried out to investigate the effect of sink mark that was generated in the boss wall thickness of injection molded products. The sink mark could also be caused by thickness ratio of boss part. For a given thickness ratio of boss, several molding process parameters such as packing pressure, packing time and melt temperature, affecting to generation of the sink mark were discussed.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2004.10a
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• pp.327-330
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• 2004

Laser aided direct metal deposition (LADMD) process offers the ability to make a metal component directly from 3-D CAD dimensions. A 3-D object can be formed by repeating laser cladding layer by layer. The key of the build-up mechanism is the effective control of powder delivery and laser power to be irradiated into the melt-pool. A feedback control system using optical sensors is introduced to control laser power and powder mass flow rate. Using H13 tool steel and $CO_2$ laser system, comprehensive analysis are executed to test the efficiency of the system. In addition, the dimensional characteristics of directed deposited material are investigated with the parameters of deposition thickness, laser power, traverse speed and powder mass flow rate.

• 한국연소학회:학술대회논문집
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• 2007.05a
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• pp.168-175
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• 2007

Ash melting chamber is one of the key facility of the pyrolysis-melting incineration system, and it should be designed and operated very carefully for avoiding solidification of slag. In this study, an example of numerical and experimental scale-up process of the melting chamber, in which high speed air is injected to the molten slag and generates bubbles, which enhances agitation of the slag and char combustion, is presented. Cold flow test, combustion and melting test in a lab-scale (30 kg/hr) chamber and a pilot scale (200 kg/hr) chamber. Minimum energy for maintaining molten slag is derived, and it was found that the molten slag can be maintained efficiently by concentrating heat into the bubbling slag.

• Proceedings of the KIEE Conference
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• 1998.11c
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• pp.1054-1060
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• 1998

Previous counter-current flow limitation (CCFL) and critical heat flux (CHF) studies included investigations on the inlet entrance, inclined channel and gap effects for the most part. In this study, the local CHF correlation was presented to be used in the numerical analysis for the 3 dimensional hemispherical geometry. Also, first-principle analyses were performed to determine the maximum heat removal capability from the debris through the gap that may be formed during a core melt accident. The maximum heat removal capability by gap cooling can be applied in quantitatively assessing the severe accident management measures.

• Journal of Welding and Joining
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• v.18 no.3
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• pp.76-82
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• 2000

In this study, three-dimensional heat flow in laser beam welding for deep penetration was analyzed by using F.E.M common code, and then the results were compared with the experimental data. The models for analysis are full penetration welds and are made at three different laser powers (6, 9.9, 4.5 kW) with two different welding speeds (5.8mm/s, 5mm/s). The characteristics of thermal absorption by the workpiece during deep penetration laser welding can be represented by a combination of line heat source through the workpiece and distributed heat source at the top surface due to the plasma plume above the top surface. This gives an insight into the way in which the beam interacts with the material being welded. The analyses performed with the combined heat source models show comparatively good agreement between the experimental and calculated melt temperature isotherm, i.e, the fusion zone boundary. The results are used to explain the "nail head" appearance of fusion zone, which is quite common in laser beam welds.eam welds.

• Korea-Australia Rheology Journal
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• v.18 no.3
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• pp.143-151
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• 2006

We analyzed the non-Newtonian and non-isothermal flow in a single screw extruder system and investigated the mixing performance with respect to the screw speed and the screw pitch. The viscosity of polymer melt was described with Carreau-Yasuda model. The mixing performance was computed numerically by tracking the motions of particles in the screw element system. The extent of mixing was characterized in terms of the deformation rate, the residence time distribution, and the strain. The results revealed that the high screw speed reduces the residence time but increases the deformation rate while the small screw pitch increases the residence time. It is concluded that the high screw speed increases the dispersive mixing performance and the small screw pitch increases the distributive mixing performance.

• Proceedings of the KSME Conference
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• 2003.11a
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• pp.139-144
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• 2003

Laser melting problems with deformed substrates are investigated by axisymmetric numerical simulations. Source-based method is used to solve the energy equation, and the momentum equations are solved in the liquid domain with SIMPLER algorithm. Using a laser beam with a top-hat heat flux distribution, this study is performed to examine the effect of surface deformation, beam power density and surface tension force on the melt pool during laser melting. Surface temperature decreases with increasing surface deformation, while surface velocity increases. It is found that surface deformation, beam power density and surface tension force have a very significant effect on heat transfer and fluid flow during laser melting.