• Title/Summary/Keyword: Melt

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Oxygen Transport in Highly Boron Doped Silicon Melt

  • Terashima, K.;Abe, K.;Maeda, S.;Nakanishi, H.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.06a
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    • pp.207-209
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    • 1997
  • Influences of boron addition on the oxygen solubiligy in silicon melt and the amount of evaporation loss from the melt surface were investigated. It has been found the oxygen concentration increases from 2${\times}$1018 to 4${\times}$1018 atoms/㎤. The amount of evaporation loss was found to vary widely depending on the melt temperature. The amount of SiO evaporating form boron doped (∼102121 atoms/㎤) silicon melt at 1550$^{\circ}C$ is about twice as much as the value of non-doped melt.

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$\beta$-SiC Formation Mechanisms in Si Melt-C-SiC System (용융 Si-C-SiC계에서 $\beta$-SiC 생성기구)

  • 서기식;박상환;송휴섭
    • Journal of the Korean Ceramic Society
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    • v.36 no.6
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    • pp.655-661
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    • 1999
  • ${\beta}$-SiC formation mechanism in Si melt-C-SiC system with varying in size of carbon source was investigated. A continuous reaction sintering process using Si melt infiltration method was adopted to control the reaction sintering time effectively. It was found that ${\beta}$-SiC formation mechanism in Si melt-C-SiC system was directly affected by the size of carbon source. In the Si melt-C-SiC system with large carbon source ${\beta}$-SiC formation mechanism could be divided into two stages depending on the reaction sintering time: in early stage of reaction sintering carbon dissolution in Si melt and precipitation of ${\beta}$-SiC was occurred preferentially and then SIC nucleation and growth was controlled by diffusion of carbon throughy the ${\beta}$-SiC layer formed on graphite particle. Furthmore a dissolution rate of graphite particles in Si melt could be accelerated by the infiltration of Si melt through basal plane of graphite crystalline.

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Analysis of the Coupled Turbulent Flow and Macroscopic Solidification in Twin-Roll Continuous Casting Process (쌍롤식 연속주조공정에서의 난류유동 및 거시적응고 해석)

  • Kim, Deok-Su;Kim, U-Seung;Jo, Gi-Hyeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.3
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    • pp.285-295
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    • 2001
  • The transport phenomena in a wedge-shaped pool of twin-roll continuous caster are affected by the various operating parameters such as the melt-feed pattern, roll-gap thickness, melt-superheat, and casting speed. A computer program has been developed for analyzing the two-dimensional, steady conservation equations for transport phenomena during twin-roll continuous casting process in order to estimate the turbulent melt-flow, temperature fields, and solidification in the wedge-shaped pool. The turbulent characteristics of the melt-flow were considered using a low-Reynolds-number K-$\xi$ turbulence model. Based on the computer program, the effects of the different melt-feed patterns, roll-gap thicknesses, and superheats of melt on the variations of the velocity and temperature distributions, and the mushy solidification were examined. The results show that the liquidus line is located considerably at the upstream region, and in the lower region appear the well-mixed melt-flow and most widely developed mushy zone. Besides, the variation of melt-flow due to varying melt-feed patterns, affects mainly the liquidus line, and scarcely has effects on the solidus line in the outlet region.

Electromagnetic Shielding Effectiveness of Melt-blown Nonwoven Fabric with Width and Interval of Thin Copper Film (구리박막의 넓이와 간격에 따른 melt-blown 부직포의 전자파 차폐 효과)

  • Shin Hyun Sae;Son Jun Sik;Kim Young Sang;Jeong Jin Soo
    • Textile Coloration and Finishing
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    • v.16 no.5
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    • pp.42-47
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    • 2004
  • The main objective of this work is to develop melt-blown nonwoven fabric composite materials have electromagnetic shielding characteristics using thin copper film. Melt-blown nonwoven fabric is the matrix phase and thin copper films are the reinforcement of the composite materials. Thin copper films are incorporated as conductive fillers to provide the electromagnetic shielding property of the melt-blown nonwoven fabric. The width and interval of thin copper films in the nonwoven fabric are varied by changing 1, 3, 5 mm for thin copper film's width and 1, 3, 5 mm for thin copper film's interval. The shielding effectiveness(SE) of various melt-blown nonwoven fabrics is measured in the frequency range of 50 MHz to 1.8 GHz. The variations of SE of melt-blown nonwoven fabric with width and interval of thin copper films are described. Suitability of melt-blown nonwoven fabric for electromagnetic shielding applications is discussed. The results indicate that the melt-blown nonwoven fabric composite material using thin copper film can be used for the purpose of electromagnetic shielding.

Analysis on the discharge characteristics and spreading behavior of an ex-vessel core melt in the SMART

  • Sang Ho Kim;Jaehyun Ham;Byeonghee Lee;Sung Il Kim;Hwan Yeol Kim;Rae-Joon Park;Jaehoon Jung
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4551-4559
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    • 2022
  • The aim of this research is to analyze the characteristics of a core melt discharged from the reactor vessel and the spreading behavior the core melt in the reactor cavity of the SMART. First, a severe accident sequence under conservative conditions is simulated by the MELCOR code to obtain the conditions for an analysis of the spreading behavior and coolability of the ex-vessel melt. Second, the spreading behavior and coolability of the ex-vessel melt are analyzed by the MELTSPREAD code. The level, temperature, and pressure of the water in the cavity as well as the temperature, mass, composition, and discharge velocity of the melt were utilized to construct the ex-vessel analysis. The melt spread only to part of the cavity, and that the height of the corium in a static state was less than 25 cm. The characteristics of a small modular reactor on the spreading behavior and coolability of melt were analyzed. In the SMART, the amount of melt discharged into the cavity is relatively small and the area of the cavity is sufficiently large when compared to a high-power pressurized water reactor. It was found that the coolability of an ex-vessel core melt can be sufficiently secured.

Cubic $ZrO_2$ Single Crystals Growth by Skull Method : Effect of Melt Homogenization in Crystallization (스컬(Skull)법에 의한 큐빅 $ZrO_2$단결정 성장 : 융액의 균질화가 결정성장에 미치는 영향)

  • 정대식;오근호
    • Journal of the Korean Ceramic Society
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    • v.27 no.5
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    • pp.597-604
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    • 1990
  • In Cubic ZrO2 crystal growth by Skull method, it was examined on effect of homonization on melt as keeping ZrO2(90mol%)-Y2O3(10mol%) melt with 1hr, 2hr, 4hrs, 8hrs, 16hrs, respectively. The optimum homonizing condition in this system was obtained by the examination between quality of grown crystals and soaking time of melt. It was obtained that the lower quality crystal could be produced in the longer holding melt than the optimum soaking time of melt in spite of the supposedly well homonized state, because the melt stability is sensibly dependent on the convective state of melt in skull method (cold crucible process).

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A Study on the Evaporation Behavior of Magnesium Alloy (AM50) Scrap Melt under Reduced Pressure (감압 하에서 마그네슘 합금(AM50) 스크랩 용탕의 증발 거동에 관한 연구)

  • Wi, Chang-Hyun;Hong, Seong-Hun;You, Byung-Don
    • Korean Journal of Metals and Materials
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    • v.48 no.3
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    • pp.241-247
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    • 2010
  • In order to develop the vacuum distillation process of magnesium alloy scrap, a fundamental study on the evaporation behavior of magnesium alloy (AM50) scrap melt was carried out. Melt temperature, pressure, reaction time, and initial specific surface area of melt were considered as experimental variables. The evaporation rate of magnesium increased with the increase of melt temperature and initial specific surface area of melt, and with the decrease of the pressure. The activation energy of magnesium evaporation reaction calculated by an Arrhenius plot decreased with the decrease of the pressure and with the increase of the initial specific surface area of melt. An empirical equation was derived for the evaporation rate of magnesium from AM50 alloy melt.

Processing Characteristics of Nylon 6 by Controlling the Melt Viscosity (용융 점도 조절에 의한 나일론6의 가공특성 연구)

  • Kim Hyogap;Kim Jun Kyung;Lim Soonho;Lee Kunwong;Park Min;Kang Ho-Jong
    • Polymer(Korea)
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    • v.29 no.6
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    • pp.565-570
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    • 2005
  • Melt processing characteristics of nylon 6 (N6) has been investigated by controlling the melt viscosity in melt impregnation process. Calcium stearate (CaST) was introduced as a lubricant for N6 and the melt viscosity of N6 decreased with adding only 1 wt$\%$ of CaST. In addition, reactive blending with polycaprolactone (PCL) was carried out by lowering the melt viscosity in N6. It was found that the melt viscosity of N6 could be controlled and further melt viscosity drop could be obtained by applying phenyl phosphite (PP) and diphenyl phosphite (DPP) to enhance the transesterification between N6 and PCL. Our approaches show that the melt viscosity of N6 could be reduced without loss of thermal stability which is the critical problem in high temperature melt impregnation process of N6.

Chemical Modification of Isotactic Polypropylene by Melt Blending

  • Kim, Jun-Young;Seo, Eun-Su;Park, Dae-Soon;Park, Kwang-Min;Kang, Seong-Wook;Lee, Chang-Hyung;Kim, Seong-Hum
    • Fibers and Polymers
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    • v.4 no.3
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    • pp.107-113
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    • 2003
  • The branched polypropylene (b-PP) was prepared by melt blending process with initiator, antioxidant, and functional monomers to improve the melt strength through the melt grafting. The melt flow index (MFI) of the b-PP was increased with increasing the initiator content. On the introduction of the alkylamine as the branching agents the MFI of the b-PP was increased, while that of the b-PP with the pentaerythritol triacrylate (PT) was decreased. It may be caused by the chain scission of the i-PP backbone due to the reduced thermal stability of the i-PP on the melt blending. The MFI of the b-PP without the antioxidant was increased due to the chain scission occurred during the melt processing, while on the introduction of the antioxidant, the MFI of the b-PP was decreased. The crystallization temperature of the b-PP was higher than that of PP, which was attributed to the branched chain structure. It was found that the PT was the most effective functional monomers for enhancing the melt properties of the b-PP.

Effect of chain structure of polypropylenes on the melt flow behavior

  • Lee, Young-Jun;Sohn, Ho-Sang;Park, Seung-Ho
    • Korea-Australia Rheology Journal
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    • v.12 no.3_4
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    • pp.181-186
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    • 2000
  • Rheological Properties of polypropylenes having different molecular structures (linear polypropylene (PPL) and branched one (PPB)) were studied. Both the extensional flow and oscillatory shear flow properties were checked. Especially, the melt strength of polypropylenes having various shear history were investigated by using in-house-made Rheometer (called SMER). Compared to linear polypropylene, the branched polypropylene shows enhanced melt strength during extensional flow due to the retarded relaxation of molecules. When the slope of melt tension was plotted against take up speed of melt strand, the characteristic peak was observed in case of branched polypropylene, while the linear polypropylene shows only monotonously decreasing pattern. This entanglement was partially disrupted by physical forces such as shear during melt extrusion. However, the melt strength of PPB after multiple extrusion is still higher than PPL, implying the loss of elasticity during multiple extrusion is not so comprehensive. On dynamic experiments, PPB shows typical shear thinning behavior and the tangent delta of PPB is lower than PPL, reflecting high elasticity of PPB.

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