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Synthesis and Characterization of Au/TiO2 Nanoparticles with Core-shell Structure (Core-shell 구조의 Au/TiO2 나노 미립자의 합성 및 특성 평가)

  • ;Paul Mulvaney
    • Journal of the Korean Ceramic Society
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    • v.40 no.9
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    • pp.902-908
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    • 2003
  • Au/TiO$_2$ core-shell structure nanoparticles were synthesised by sol-gel process, and the morphology and crystallinity of TiO$_2$ shell were investigated by TEM and UV-Vis. absorption spectrometer. Au/TiO$_2$ core-shell structure nanoparticles could be prepared by the hydrolysis of TOAA (Titanium Oxide Acethylacetonate) in Au colloid ethanol solution with $H_2O$. The thickness of TiO$_2$ shell on the surface of Au particles was about 1 nm. To investigate the crystallinity of TiO$_2$ shell, UV light with 254 nm and radioactive lay of $^{60}$ CO were irradiated on the TiO$_2$ coated Au colloid ethanol solution. The surface plasmon phenomenon of Au nanoparticles appeared only when the radioactive lay was irradiated on the TiO$_2$ coated Au colloid ethanol solution. From these results, it was found that the TiO$_2$ shell was amorphous and the MUA (Mercaptoundecanoic Acid) layer on the Au particle for its dispersion didn't act as an obstacle to disturb the movement of electron onto the surface of Au particle.

A new species of Bangiopsis: B. franklynottii sp. nov. (Stylonematophyceae, Rhodophyta) from Australia and India and comments on the genus

  • West, John A.;de Goer, Susan Loiseaux;Zuccarello, Giuseppe C.
    • ALGAE
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    • v.29 no.2
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    • pp.101-109
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    • 2014
  • Small red algae, especially those previously referred to as 'primitive' are often overlooked, but can be quite abundant. These 'primitive' red algae are now placed in several classes distinct from the Florideophyceae, for example the Stylonematophyceae. A brownish-red filamentous alga was collected from a sandy tide pool at Cape Tribulation, Queensland, Australia. Cultured specimens were identified as Bangiopsis and conformed to the morphological characters of the genus (multicellular base, erect filaments branched or unbranched, uniseriate to multiseriate-tubular, single multilobed purple-red to red-brown plastid with central pyrenoid, vegetative cells released directly as spores). Molecular data of two plastid genes (rbcL, psbA) support placement of the Australian isolate and isolates from India in Bangiopsis. The genetic variation between these isolates and isolates from Puerto Rico previously attributed to B. subsimplex indicates that these should be considered as a separate species. As the type locality is in the Atlantic Ocean, French Guiana, and not far from Puerto Rico, and the Puerto Rican isolate has been used often in phylogenetic analyses, we propose that the Indian and Pacific Ocean isolates be designated a new species, B. franklynottii, to acknowledge Ott's many years of research on inconspicuous freshwater and marine red algae. Our research also highlights the lack of careful descriptions in many of the records of this genus and the lack of morphological characters to distinguish species. Especially within the morphologically simple red algae, morphological distinctness does not necessarily reflect evolutionary divergences.

Experimental and numerical investigation on the behavior of concrete-filled rectangular steel tubes under bending

  • Zhang, Tao;Gong, Yong-zhi;Ding, Fa-xing;Liu, Xue-mei;Yu, Zhi-wu
    • Structural Engineering and Mechanics
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    • v.78 no.3
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    • pp.231-253
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    • 2021
  • Pure bending loading conditions are not frequently occurred in practical engineering, but the flexural researches are important since it's the basis of mechanical property researches under complex loading. Hence, the objective of this paper is to investigate the flexural behavior of concrete-filled rectangular steel tube (CFRT) through combined experimental and numerical studies. Flexural tests were conducted to investigate the mechanical performance of CFRT under bending. The load vs. deflection curves during the loading process was analyzed in detail. All the specimens behaved in a very ductile manner. Besides, based on the experimental result, the composite action between the steel tube and core concrete was studies and examined. Furthermore, the feasibility and accuracy of the numerical method was verified by comparing the computed results with experimental observations. The full curves analysis on the moment vs. curvature curves was further conducted, where the development of the stress and strain redistribution in the steel tube and core concrete was clarified comprehensively. It should be noted that there existed bond slip between the core concrete and steel tube during the loading process. And then, an extensive parametric study, including the steel strength, concrete strength, steel ratio and aspect ratio, was performed. Finally, design formula to calculate the ultimate moment and flexural stiffness of CFRTs were presented. The predicted results showed satisfactory agreement with the experimental and FE results. Additionally, the difference between the experimental/FE and predicted results using the related design codes were illustrated.

Experiences and attitudes toward aesthetic procedures in East Asia: a cross-sectional survey of five geographical regions

  • Kwon, Soo-Ha;Lao, William Wei-Kai;Lee, Che-Hsiung;Hsu, Angela Ting-Wei;Koide, Satomi;Chen, Hsing-Yu;Cho, Ki-Hyun;Tanaka, Eiko;Cheon, Young-Woo;Chang, Tommy Nai-Jen
    • Archives of Plastic Surgery
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    • v.48 no.6
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    • pp.660-669
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    • 2021
  • Background The demand for aesthetic procedures continues to grow globally, particularly in East Asian countries. The popularity of specific aesthetic procedures varies, however, depending on the particular East Asian geographical region being studied. This study aimed to evaluate the experiences of and attitudes toward aesthetic procedures in five East Asian countries/regions, including China, Japan, South Korea, Hong Kong, and Taiwan. Methods To recruit participants, an online questionnaire was designed and distributed on social media networks between May 2015 and March 2016. The statistical analysis was conducted using SPSS software, version 22.0. Results A total of 3,088 people responded (approximately 600 in each country/region). Of these, 940 participants (47.8%) responded that they had experienced at least one aesthetic procedure in the past. Taiwan had the highest number of participants who had experienced at least one procedure (264/940, 41%), with primarily non-surgical experiences. Only in South Korea did surgical cosmetic experiences exceed non-surgical cosmetic experiences (55.9% vs. 44.1%). The popularity of particular procedures and the motivation for undergoing aesthetic procedures varied by country. Conclusions The popularity of aesthetic procedures continues to evolve. Similar trends were observed across the East Asian regions; however, each country had its unique demands and preferences. The information provided by this study can help aesthetic plastic surgeons further understand the patients in their corresponding region, customize their practice, and develop the requisite skills.

In-plane structural analysis of blind-bolted composite frames with semi-rigid joints

  • Waqas, Rumman;Uy, Brian;Wang, Jia;Thai, Huu-Tai
    • Steel and Composite Structures
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    • v.31 no.4
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    • pp.373-385
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    • 2019
  • This paper presents a useful in-plane structural analysis of low-rise blind-bolted composite frames with semi-rigid joints. Analytical models were used to predict the moment-rotation relationship of the composite beam-to-column flush endplate joints that produced accurate and reliable results. The comparisons of the analytical model with test results in terms of the moment-rotation response verified the robustness and reliability of the model. Abaqus software was adopted to conduct frame analysis considering the material and geometrical non-linearities. The flexural behaviour of the composite frames was studied by applying the lateral loads incorporating wind and earthquake actions according to the Australian standards. A wide variety of frames with a varied number of bays and storeys was analysed to determine the bending moment envelopes under different load combinations. The design models were finalized that met the strength and serviceability limit state criteria. The results from the frame analysis suggest that among lateral loads, wind loads are more critical in Australia as compared to the earthquake loads. However, gravity loads alone govern the design as maximum sagging and hogging moments in the frames are produced as a result of the load combination with dead and live loads alone. This study provides a preliminary analysis and general understanding of the behaviour of low rise, semi-continuous frames subjected to lateral load characteristics of wind and earthquake conditions in Australia that can be applied in engineering practice.

Numerical analysis of simply supported one-way reinforced concrete slabs under fire condition

  • Ding, Fa-xing;Wang, Wenjun;Jiang, Binhui;Wang, Liping;Liu, Xuemei
    • Computers and Concrete
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    • v.27 no.4
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    • pp.355-367
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    • 2021
  • This paper investigates the mechanical response of simply supported one-way reinforced concrete slabs under fire through numerical analysis. The numerical model is constructed using the software ABAQUS, and verified by experimental results. Generally, mechanical response of the slab can be divided into four stages, accompanied with drastic stress redistribution. In the first stage, the bottom of the slab is under tension and the top is under compression. In the second stage, stress at bottom of the slab becomes compression due to thermal expansion, with the tension zone at the mid-span section moving up along the thickness of the slab. In the third stage, compression stress at bottom of the slab starts to decrease with the deflection of the slab increasing significantly. In the fourth stage, the bottom of the slab is under tension again, eventually leading to cracking of the slab. Parametric studies were further performed to investigate the effects of load ratio, thickness of protective layer, width-span ratio and slab thickness on the performance of the slab. Results show that increasing the thickness of the slab or reducing the load ratio can significantly postpone the time that deflection of the slab reaches span/20 under fire. It is also worth noting that slabs with the span ratio of 1:1 reached a deflection of span/20 22 min less than those of 1:3. The thickness of protective layer has little effect on performance of the slab until it reaches a deflection of span/20, but its effect becomes obvious in the late stages of fire.

Behaviour and design of bolted endplate joints between composite walls and steel beams

  • Li, Dongxu;Uy, Brian;Mo, Jun;Thai, Huu-Tai
    • Steel and Composite Structures
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    • v.44 no.1
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    • pp.33-47
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    • 2022
  • This paper presents a finite element model for predicting the monotonic behaviour of bolted endplate joints connecting steel-concrete composite walls and steel beams. The demountable Hollo-bolts are utilised to facilitate the quick installation and dismantling for replacement and reuse. In the developed model, material and geometric nonlinearities were included. The accuracy of the developed model was assessed by comparing the numerical results with previous experimental tests on hollow/composite column-to-steel beam joints that incorporated endplates and Hollo-bolts. In particular, the Hollo-bolts were modelled with the expanded sleeves involved, and different material properties of the Hollo-bolt shank and sleeves were considered based on the information provided by the manufacture. The developed models, therefore, can be applied in the present study to simulate the wall-to-beam joints with similar structural components and characteristics. Based on the validated model, the authors herein compared the behaviour of wall-to-beam joints of two commonly utilised composite walling systems (Case 1: flat steel plates with headed studs; Case 2: lipped channel section with partition plates). Considering the ease of manufacturing, onsite erection and the pertinent costs, composite walling system with flat steel plates and conventional headed studs (Case 1) was the focus of present study. Specifically, additional headed studs were pre-welded inside the front wall plates to enhance the joint performance. On this basis, a series of parametric studies were conducted to assess the influences of five design parameters on the behaviour of bolted endplate wall-to-beam joints. The initial stiffness, plastic moment capacity, as well as the rotational capacity of the composite wall-to-beam joints based on the numerical analysis were further compared with the current design provision.

Factors of Successful Development of Smart Cities

  • Iryna, Kalenyuk;Iryna, Uninets;Yevhen, Panchenko;Nataliia, Datsenko;Maxym, Bohun
    • International Journal of Computer Science & Network Security
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    • v.22 no.7
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    • pp.21-28
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    • 2022
  • The increase in the number of large cities and the size of their population sharpens attention to the new role of cities as entities to ensure a high-quality, safe and modern life of citizens, which has become significantly more active in recent years. The rapid spread of smart cities in the modern world has actualized the issue of analyzing their success and assessing the role of various factors in this. Every success of a smart city is always the result of a unique combination of the most modern technologies, environmental and social initiatives, skillful and consistent management, as well as available human potential. The purpose of the article is to analyze the success factors of smart cities based on the generalization of the results of the most famous ratings. In order to identify the impact of various factors, primarily intellectual, on the success and leadership positions of smart cities, the following ratings were consistently analyzed: Smart City Index (SCI), City in Motion Index (CIMI), Global Power City Index (GPCI), Global Cities Index (GCI), Global Cities Outlook (GCO). They have a different list of indicators and main pillars (dimensions), but all ratings take into account aspects such as: governance, ICT, mobility, functionality, human capital, etc. The highest correlation coefficient, that is, the strongest linear relationship of the CIMI index was found with such factors as: Human capital, Economy, Governance and Technologies. Summarizing the results of the TOP 20 smart cities according to different ratings allowed us to confirm that the list of leaders is very similar in all ratings. Among those cities that are in the TOP-20 in all five indexes are: London, Sydney and Singapore. There are four indices: New York, Paris, Tokyo, Copenhagen, Berlin, Amsterdam, Melbourne. Achieving leadership positions in smart city rankings is always the result of a combination and synergy of certain factors, and first of all, it is the quality of human capital. The intensity and success of the use of information and communication technologies in locality management processes, city planning and improvement of the city's living conditions depend on it.

Experimental study of strength characteristics of reinforced broken rock mass

  • Yanxu Guo;Qingsong Zhang;Hongbo Wang;Rentai Liu;Xin Chen;Wenxin Li;Lihai Zhang
    • Geomechanics and Engineering
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    • v.33 no.6
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    • pp.553-565
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    • 2023
  • As the structure of broken rock mass is complex, with obvious discontinuity and anisotropy, it is generally necessary to reinforce broken rock mass using grouting in underground construction. The purpose of this study is to experimentally investigate the mechanical properties of broken rock mass after grouting reinforcement with consideration of the characteristics of broken rock mass (i.e., degree of fragmentation and shape) and a range of reinforcement methods such as relative strength ratio between the broken rock mass and cement-based grout stone body (λ), and volumetric block proportion (VBP) representing the volumetric ratio of broken rock mass and the overall cement grout-broken rock mass mixture after the reinforcement. The experimental results show that the strength and deformation of the reinforced broken rock mass is largely determined by relative strength ratio (λ) and VBP. In addition, the enhancement in compressive strength by grouting is more obvious for broken rock mass with spherical shape under a relatively high strength ratio (e.g., λ=2.0), whereas the shape of rock mass has little influence when the strength ratio is low (e.g., λ=0.1). Importantly, the results indicate that columnar splitting failure and inclined shear failure are two typical failure modes of broken rock mass with grouting reinforcement.

A passive vibration isolator with bio-inspired structure and inerter nonlinear effects

  • Jing Bian;Xu-hong Zhou;Ke Ke;Michael CH Yam;Yu-hang Wang;Yue Qiu
    • Structural Engineering and Mechanics
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    • v.88 no.3
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    • pp.221-238
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    • 2023
  • This paper developed and examined a novel passive vibration isolator (i.e., "X-inerter") motivated by combining a bio-inspired structure and a rack-pinion inerter. The bio-inspired structure provided nonlinear stiffness and damping owing to its geometric nonlinearity. In addition, the behavior was further enhanced by a gear inerter that produced a special nonlinear inertia effect; thus, an X-inerter was developed. As a result, the X-inerter can achieve both high-static-low-dynamic stiffness (HSLDS) and quasi-zero stiffness (QZS), obtaining ultra-low frequency isolation. Furthermore, the installed inerter can produce a coupled nonlinear inertia and damping effect, leading to an anti-resonance frequency near the resonance, wide isolation region, and low resonance peak. Both static and dynamic analyses of the proposed isolator were conducted and the structural parameters' influence was comprehensively investigated. The X-inerter was proven to be comparatively more stable in the ultra-low frequency than the benchmarking QZS isolator due to the nonlinear damping and inertia properties. Moreover, the inertia effect could suppress the bio-inspired structure's super- and sub-harmonic resonance. Therefore, the X-inerter isolator generally possesses desirable nonlinear stiffness, nonlinear damping, and unique nonlinear inertia, designed to achieve the ultra-low natural frequency, the anti-resonance property, and a wide isolation region with a low resonance peak.