• Korean Chemical Engineering Research
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• 제56권5호
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• pp.767-772
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• 2018

전기유변(ER) 현상을 위해 제시된 메커니즘들이 중에서 정전기 분극 모델과 전도 모델이 이론적인 측면에서 적합한 것으로 알려져 있다. 그러나 이 모델들은 자체적인 제한들 때문에 효과적인 ER 액체의 개발에 적절한 도움이 되지 못했다. 이 문제를 해결하기 위해 Onsager 이론으로 확장한 Maxwell-Wagner 분극 모델을 개발하였다. 확장한 Maxwell-Wagner 분극 모델은 항복응력의 전기장 주파수 및 전기장 크기의 비제곱 의존성을 설명할 수 없는 정전기 분극 모델의 단점과 전기장 하에서의 입자의 미세 구조 변화를 예측할 수 없는 전도 모델의 단점을 해결할 수 있었다. 또한 이 모델은 정전기 분극 모델과 전도 모델에서 예측할 수 없었던 항복응력에의 입자 전도도 영향을 고려할 수 있는 장점도 있어 효과적인 ER 액체의 개발에 기여하리라 판단된다.

• Korean Chemical Engineering Research
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• 제58권3호
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• pp.480-485
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• 2020

Onsager 이론으로 확장된 Maxwell-Wagner 분극 모델을 이용하여 전도성 입자로 제조된 전기유변(Electrorheological, ER) 액체의 전기유변 현상에 대한 전산 모사를 수행하였다. 확장된 Maxwell-Wagner 분극 모델을 이용한 전산 모사는 전도성 입자로 제조된 전기유변 액체의 특성인 비제곱 전기유변 현상(Δτ∝Eⁿ, n≈1.5)을 확인하였다. 전단 흐름에서 전단응력이 정상상태에 도달하는 시점은 전기장 하에서 생성된 사슬 모양 구조가 전단 흐름에 의해 깨짐과 재생성이 정상상태에 도달하는 지점으로 나타났다. 또한, 전단 속도의 증가에 따라 전단응력이 최솟값을 보이는 전도성 입자를 기반으로 한 전기유변 액체의 현상도 관찰하였으며, 이것은 입자의 사슬 모양 구조가 무작위 배열로 바뀌는 순간에 발생하는 것임을 관찰하였다. 입자의 부피 분율 ϕ가 증가에 따라 전단응력은 증가하다가 일정해지는 경향도 관찰하였다.

• Transactions on Electrical and Electronic Materials
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• 제8권3호
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• pp.139-142
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• 2007

Organic field-effect transistor (FET) based on a copper Phthalocyanine (CuPc) material as an active layer and a $SiO_2$ as a gate insulator were fabricated and analyzed. We measured the typical FET characteristics of CuPc in air. The electrical characteristics of the CuPc FET device were analyzed by a Maxwell-Wagner model. The Maxwell-Wagner model employed in analyzing double-layer dielectric system was helpful to explain the C-V and I-V characteristics of the FET device. In order to further clarity the channel formation of the CuPc FET, optical second harmonic generation (SHG) measurement was also employed. Interestingly, SHG modulation was not observed for the CuPc FET. This result indicates that the accumulation of charge from bulk CuPc makes a significant contribution.

• Korean Chemical Engineering Research
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• 제60권4호
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• pp.613-619
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• 2022

전도성 입자로 제조된 전기유변(Electrorheological) 유체에서 입자 크기 및 서로 다른 크기의 입자들의 혼합이 전기유변 현상에 어떤 영향을 미치는지 살펴보기 위해 Onsager 이론으로 확장된 Maxwell-Wagner 분극 모델을 이용하여 전산 모사를 수행하였다. 전산 모사 결과 입자의 부피 분율이 같은 경우 단일한 크기의 입자로 구성된 균일한 전기유변 유체의 동적 항복응력은 입자 크기에 무관하였고, 크기가 서로 다른 입자들로 혼합된 비균일 전기유변 유체의 동적 항복응력은 균일한 전기유변 유체에 비해 감소하였다. 입자 부피 분율이 같은 경우 ${\dot{\gamma}}^*$≧0.01인 범위에서 큰 입자로 구성된 균일한 전기유변 유체가 작은 입자로 구성된 균일한 전기유변 유체보다 전단응력이 큰 것으로 나타났으며, ${\dot{\gamma}}^*$≧1인 경우에는 전기유변 유체는 큰 입자의 비율이 증가할수록 전단응력이 증가함을 보였다. 모든 입자 크기 및 조성에 대해 전도성 입자로 제조된 전기유변 유체의 특성인 비제곱 전기유변 현상(∆_𝛕 ∝ Eⁿ, n ≈ 1.55)도 예측하였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.70-71
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• 2007

Analyzing pentacene field effect transistors (FETs) with Au source and drain electrodes as Maxwell-Wagner effect elements, electron and hole injection from the Au electrodes into the FET channel were examined using current-voltage (I-V), capacitance-voltage (C-V) and optical second harmonic generation (SHG) measurements. Based on these results, a mechanism of the hole and electron injection into pentacene from the Au electrodes and subsequently recombination mechanism with light-emitting in the pentacene layer are discussed, with taking into account the presence of trapped charges.

• 한국전기전자재료학회논문지
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• 제26권7호
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• pp.515-521
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• 2013

Magnetoelectric(ME) bulk composites with PZT-PNN-PZN/$Fe_2O_4$ were prepared by using a conventional ceramic methods and investigated on the ME voltage vs frequency of ac magnetic fields. We made the electric equivalent circuits by using the Maxwell-Wagner model and simulated the frequency dependence of ME voltage in low frequency region. ME devices were described by a series of two equivalent circuits of piezoelectric and magnetic, which have the relaxation time ${\tau}$ due to the interaction between ME device and load resistor. Equivalent circuit of piezoelectric material is independent of frequency. However ferrite magnetic materials have Debye absorption and dipolar dispersion, whose equivalent circuit is a function of frequency. Therefore we suggest the resistance in the equivalent circuit is proportion to $1+{\omega}^2{\tau}^2$ and the capacitance is in inverse proportion to $1+{\omega}^2{\tau}^2$ in the magnetic materials.

• E2M - 전기 전자와 첨단 소재
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• 제11권10호
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• pp.24-31
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• 1998

Interfacial effect in polymetric composites have been studied extensively. This report deals mainly with the effects of interfacial space charge and interface structure. A model for the dynamic process of interfacial space charge accumulation is proposed. The new model might interpret some interface phenomena which is difficult to be explained in terms of traditional Maxwell-Wagner theory. An interface structure is also presented, by which the importance of surface treatment of glass Fiber for improving the properties of FRP could be well understood.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2007년도 추계학술대회논문집
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• pp.73-76
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• 2007

Electro-Active paper (EAPap) is a new smart material that has a potential to be used in biomimetic actuator and sensor. It is made by cellulose that is abundant material in nature. EAPap is fascinating with its biodegradability, lightweight, large displacement, high mechanical strength and low actuation voltage. Actuating mechanism of EAPap is known to be the combined effects of ion migration and piezoelectricity. However, the electromechanical actuation mechanisms are not yet to be established. This paper presents the modeling of the actuation behavior of water infused cellulose samples and their composite dielectric constants calculated by Maxwell-Wagner theory. Electro-mechanical forces were calculated using Maxwell stress tensor method. Bending deflection was evaluated from simple beam model and compared with experimental observation, which result good correlation with each other.

• 한국소음진동공학회논문집
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• 제17권12호
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• pp.1179-1183
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• 2007

Electro-Active paper(EAPap) is a new smart material that has a potential to be used in biomimetic actuator and sensor. It is made by cellulose that is abundant material in nature. EAPap is fascinating with its biodegradability, lightweight, large displacement, high mechanical strength and low actuation voltage. Actuating mechanism of EAPap is known to be the combined effects of ion migration and piezoelectricity. However, the electromechanical actuation mechanisms are not yet to be established. This paper presents the modeling of the actuation behavior of water infused cellulose samples and their composite dielectric constants calculated by Maxwell-Wagner theory. Electro-mechanical forces were calculated using Maxwell stress tensor method. Bending deflection was evaluated from simple beam model and compared with experimental observation, and which result in good correlation with each other.

• Transactions on Electrical and Electronic Materials
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• 제9권4호
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• pp.151-155
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• 2008

Using pentacene field effect transistors (FETs) with Au source and drain electrodes, electron injection from the Au electrodes into the pentacene was investigated. The capacitance-voltage (C-V) and optical second harmonic generation (SHG) measurements were employed. Electron injection from the Au electrodes was suggested by the hysteresis behavior with the C-V characteristics and slowly decaying SHG signal under DC biasing, A mechanism of hole-injection assisted by trapped electrons is proposed. To confirm electron injection process, light-emitting behavior under the application of AC applied voltage was observed.