• Title/Summary/Keyword: Maximum optical absorption

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A Study on the Reversibility Scalar Phenomena in Amorphous Chalcogenides (비정질 칼코게나이드에서 광유기 스칼라 현상의 가역성에 관한 연구)

  • 박수호;정진만;이현용;정홍배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.31-34
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    • 1997
  • A reversible scalar phenomena in amorphous As$_{40}$ Ge$_{10}$ Se$_{15}$ S$_{35}$ have been investigated by blue-pass-filtered Hg lamp and He-Ne laser. Annealing causes the shift of the absorption edge to shelter wavelengths approximately 0.17ev, also illumination moves it to longer wavelengths about 0.05 ~ 0.07eV and it increases the refractive index maximum 0.3. Therefore the thermalbleaching(TB) and photodarkening(PD) effects have been understood by the results related to optical absorption characteristics. TB could be estimated as increasing the stabilization of amorphous chalcogenide films since absorption slope of extended regions(U) was not changed by annealing. On the other hand, PD could be understood as due to the enhancement of disorder since the slope of Urbach’s tail(1/F) around an absorption edge were decreased by illumination.ion.n.

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Electrical Relaxation in Silica Glasses and Nonlinearity in Electrical Conductivity (실리카 유리의 전기이완 특성과 비선형적 전기전도도)

  • 신동욱
    • Journal of the Korean Ceramic Society
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    • v.36 no.9
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    • pp.923-929
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    • 1999
  • The cause of optical nonlinearity induced in thermally poled silica glass is believed to be the space charge polarization. Since the second order optical nonlinearity (electro-optic effect) can be used in optical switches the optical nonlinearity in silica glass has drawn a large attention. Space charge polarization occurs when an ionic conducting material is subjected to dc electric field by the blocking electrode. Thermal poling performed to induce the optical nonlinearity in silica glass is basically identical to the process generating space charge polarization. As a first step to understand the mechanism of space charge polarization in silica glass hence the induced optical nonlinearity the absorption currents as functions of time were measured for various types of silica glasses and analyzed by the theory of space charge polarization. It was found that the electrical relaxation exhibited a step by the space charge polarization in the relatively long time range and dielectric loss peak showed a maximum at a specific temperature which is depending on type of silica glass. It was turned out that this relaxation might be a cause of nonlinearity in electrical conductivity of silica glass.

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Spectroscopic properties of Er3+/Yb3+ co-doped fluorophosphate glasses for NIR luminescence and optical temperature sensor applications

  • Linganna, K.;Agawane, G.L.;In, Jung-Hwan;Park, June;Choi, Ju H.
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.236-243
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    • 2018
  • A series of $Er^{3+}/Yb^{3+}$ co-doped fluorophosphate glasses with varying $YbF_3$ concentration were prepared by a high temperature melt quenching technique. Absorption and emission cross-sections were determined by using the McCumber theory. The larger emission cross-section ($9.86{\times}10^{-21}cm^2$) and longer fluorescence lifetime (12.37 ms) were obtained for the $^4I_{13/2}{\rightarrow}^4I_{15/2}$ transition of ABS3Er4Yb glass. The sensitivity and temperature of the maximum sensitivity were evaluated by the fluorescence intensity ratio method from the measured upconversion spectra. The results were discussed and compared to the other reported glasses.

The Properties of the Absorption Spectra in Tinted Material of Lens and Color Lens (렌즈 염색제와 칼라 렌즈의 광흡수 특성)

  • Kim, Yong-Geun;Park, Sang-An
    • Journal of Korean Ophthalmic Optics Society
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    • v.4 no.2
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    • pp.65-71
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    • 1999
  • The optical absorption spectrum was measured of the tinted powder, tinted solution and tinted lens in the visible regions. The tinted powder was very different with color of tinted lens that the optical absorptions was so higher, composed of the thick-gray color. The optical absorptions of tinted solution were just a little appeared by the energy split of a transition metal ion, so constructed with each color space. The optical absorptions of the tinted lens were appeared with the energy split peaks to a transition metal ion, so its were affected by the color constructions. The optical absorption peaks of each lens were depend on the tinted time. Blue color lens had a lot of absorption in the short wavelength regions than 500nm, and had a little appeared in the high wavelength regions than 500nm. In case of a yellow color, the optical absorptions were appeared quite contrary to the blue color, so these colors had the opponent-colors each other. In case of green color, the optical absorptions had a high in the both edges, had a low in the middle regions. In the pink color, by the optical absorptions form of quite contrary to the green color it, these colors had the opponent-colors each other. In the brown color, the optical absorptions had a maximum values in the short wavelength regions, and it gradually decreased goes by the long wavelength regions.

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Synthesis of a Novel Near-Infrared Fluorescent Dye: Applications for Fluorescence Imaging in Living Cells and Animals

  • Chen, Tongbin;Lai, Yijun;Huang, Suisheng
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.2937-2941
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    • 2013
  • Fluorescence imaging is considered as one of the most powerful techniques for monitoring biomolecule activities in living systems. Near-infrared (NIR) light is advantageous for minimum photodamage, deep tissue penetration, and minimum background autofluorescence interference. Herein, we have developed a new NIR fluorescent dye, namely, RB-1, based on the Rhodamine B scaffold. RB-1 exhibits excellent photophysical properties including large absorption extinction coefficients, high fluorescence quantum yields, and high photostability. In particular, RB-1 displays both absorption and emission in the NIR region of the "biological window" (650-900 nm) for imaging in biological samples. RB-1 shows absorption maximum at 614 nm (500-725 nm) and emission maximum at 712 nm (650-825 nm) in ethanol, which is superior to those of traditional rhodamine B in the selected spectral region. Furthermore, applications of RB-1 for fluorescence imaging in living cells and small animals were investigated using confocal fluorescence microscopy and in vivo imaging system with a high signal-to-noise ratio (SNR = 10.1).

Synthesis and Exploitation in Solar Cells of Hydrothermally Grown ZnO Nanorods Covered by ZnS Quantum Dots

  • Mehrabian, Masood;Afarideh, Hossein;Mirabbaszadeh, Kavoos;Lianshan, Li;Zhiyong, Tang
    • Journal of the Optical Society of Korea
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    • v.18 no.4
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    • pp.307-316
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    • 2014
  • Improved power conversion efficiency of hybrid solar cells with ITO/ZnO seed layer/ZnO NRs/ZnS QDs/P3HT/PCBM/Ag structure was obtained by optimizing the growth period of ZnO nanorods (NRs). ZnO NRs were grown using a hydrothermal method on ZnO seed layers, while ZnS quantum dots (QDs) (average thickness about 24 nm) were fabricated on the ZnO NRs by the successive ionic layer adsorption and reaction (SILAR) technique. Morphology, crystalline structure and optical absorption of layers were analyzed by a scanning electron microscope (SEM), X-ray diffraction (XRD) and UV-Visible absorption spectra, respectively. The XRD results implied that ZnS QDs were in the cubic phase (sphalerite). Other experimental results showed that the maximum power conversion efficiency of 4.09% was obtained for a device based on ZnO NR10 under an illumination of one Sun (AM 1.5G, $100mW/cm^2$).

Simulation and Optimization of Nonperiodic Plasmonic Nano-Particles

  • Akhlaghi, Majid;Emami, Farzin;Sadeghi, Mokhtar Sha;Yazdanypoor, Mohammad
    • Journal of the Optical Society of Korea
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    • v.18 no.1
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    • pp.82-88
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    • 2014
  • A binary-coupled dipole approximation (BCDA) is described for designing metal nanoparticles with nonperiodic structures in one, two, and three dimensions. This method can be used to simulate the variation of near- and far-field properties through the interactions of metal nanoparticles. An advantage of this method is in its combination with the binary particle swarm optimization (BPSO) algorithm to find the best array of nanoparticles from all possible arrays. The BPSO algorithm has been used to design an array of plasmonic nanospheres to achieve maximum absorption, scattering, and extinction coefficient spectra. In BPSO, a swarm consists of a matrix with binary entries controlling the presence ('1') or the absence ('0') of nanospheres in the array. This approach is useful in optical applications such as solar cells, biosensors, and plasmonic nanoantennae, and optical cloaking.

Two-Dimensional Arrays of Gold Nanoparticles for Plasmonic Nanosensor

  • Sim, Brandon;Monjaraz, Fernando;Lee, Yong-Joong;Park, So-Yeun
    • Korean Journal of Materials Research
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    • v.21 no.10
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    • pp.525-531
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    • 2011
  • Two dimensional (2D) arrays of noble metal nanoparticles are widely used in the sensing of nanoscale biological and chemical events. Research in this area has sparked considerable interest in many fields owing to the novel optical properties, e.g., the localized surface plasmon resonance, of these metallic nanoarrays. In this paper, we report successes in fabricating 2D arrays of gold nano-islands using nanosphere lithography. The reproducibility and the effectiveness of the nano-patterning method are tested by means of spin coating and capillary force deposition. We found that the capillary force deposition method was more effective for nanospheres with diameters greater than 600 nm, whereas the spin coating method works better for nanospheres with diameters less than 600 nm. The optimal deposition parameters for both methods were reported, showing about 80% reproducibility. In addition, we characterize gold nano-island arrays both geometrically with AFM as well as optically with UV-VIS spectrometry. The AFM images revealed that the obtained nano-arrays formed a hexagonal pattern of truncated tetrahedron nano-islands. The experimental and theoretical values of the geometric parameters were compared. The 2D gold nano-arrays showed strong LSPR in the absorption spectra. As the nano-islands increased in size, the LSPR absorption bands became red-shifted. Linear dependence of the plasmon absorption maximum on the size of the gold nano-islands was identified through the increment in the plasmon absorption maximum rate for a one nanometer increase in the characteristic length of the nano-islands. We found that the 2D gold nano-arrays showed nearly seven-fold higher sensitivity of the absorption spectrum to the size of the nano-islands as compared to colloidal gold nano-particles.

Investigation of Absorption Cross-Section Effects on the Formaldehyde Column Density Retrieval from Direct Sun Measurement (태양 직달광 관측 자료로부터 포름알데히드 연직 농도 산출 시 흡수단면적이 미치는 영향 연구)

  • Gyeong Park;Jeonghyeon Park;Hanlim Lee
    • Korean Journal of Remote Sensing
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    • v.39 no.5_1
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    • pp.551-561
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    • 2023
  • In this study, we investigated the effects of the spectral fitting window and absorption cross-section on the retrieval of the formaldehyde (HCHO) slant column density (SCD) from the direct-sun measurement of pandora spectrometer system using differential optical absorption spectroscopy (DOAS). Pandora Level 1 data observed at Yonsei University in Seoul from October 12 to 31, 2022 were used. The HCHO column density was retrieved under eight ranges including the spectral fitting window used in the Second Cabauw Intercomparison campaign for Nitrogen Dioxide measuring Instruments (CINDI-2) and seven types of absorption cross-section composition. The spectral fitting window was selected from 336.5 to 359.0 nm with minimum residual and HCHO SCD error. When the nitrogen dioxide (NO2) absorption cross-section at 220 K was added to the cross-section composition used in the CINDI-2 campaign among seven types, the residual and HCHO SCD error were the smallest and the HCHO column density wasstably retrieved. The average HCHO SCD with the highest retrieval accuracy and the values retrieved under other conditions differed from a minimum of 4% to a maximum of 40%.

Laser-induced Damage to Polysilicon Microbridge Component

  • Zhou, Bing;He, Xuan;Li, Bingxuan;Liu, Hexiong;Peng, Kaifei
    • Current Optics and Photonics
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    • v.3 no.6
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    • pp.502-509
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    • 2019
  • Based on the typical pixel structure and parameters of a polysilicon uncooled bolometer, the absorption rate of a polysilicon microbridge infrared detector for 10.6 ㎛ laser energy was calculated through the optical admittance method, and the thermal coupling model of a polysilicon microbridge component irradiated by far infrared laser was established based on theoretical formulas. Then a numerical simulation study was carried out by means of finite element analysis for the actual working environment. It was found that the maximum temperature and maximum stress of the microbridge component are approximately exponentially changing with the laser power of the irradiation respectively and that they increase monotonically. The highest temperature zone of the model is gradually spread by the two corners of the bridge surface that are not connected to the bridge legs, and the maximum stress acts on both sides of the junction of the microbridge legs and the substrate. The mechanism of laser-induced hard damage to polysilicon detectors is the melting damage caused by high temperature. This paper lays the foundation for the subsequent study of the interference mechanism of the laser on working state polysilicon detectors.