• Korean Chemical Engineering Research
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• v.61 no.2
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• pp.226-233
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• 2023

To create an environmentally sustainable fuel with a low sulfur concentration, requires alternative sulfur removal methods. During the course of this study, a high surface gamma alumina-supported ZnO nanocatalyst with a ZnO/-Al₂O₃ ratio of 12% was developed and tested for its ability to improve the activity of the oxidative desulfurization (ODS) process for the desulfurization of kerosene fuel. Scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) were used to characterize the produced nanocatalyst. In a digital batch baffled reactor (20~80 min), the effectiveness of the synthesized nanocatalyst was tested at different initial concentrations of dibenzothiophene (DBT) of 300~600 ppm, oxidation temperatures (25~70 ℃), and oxidation periods (0.5, 1, and 2 hours). The baffles included in the digital baffled batch reactor resist the swirling of the reaction mixture, thus facilitating mixing. The ODS procedure yielded the maximum DBT conversion (95.5%) at 70 ℃ with an 80-minute reaction time and an initial DBT level of 600 ppm. The most precise values of kinetic variables were subsequently determined using a mathematical modelling procedure for the ODS procedure. The average absolute error of the simulation findings was less than 5%, demonstrating a good degree of agreement with the experimental results acquired from all runs. The optimization of the operating conditions revealed that 99.1% of the DBT can be removed in 140 minutes.

• Structural Engineering and Mechanics
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• v.88 no.5
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• pp.451-462
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• 2023

Lumped Damage Mechanics (LDM) is a theory proposed in the late eighties, which assumes that structural collapse may be analyzed as a two-phase phenomenon. In the first (pre-localization) stage, energy dissipation is a continuous process and it may be modelled by means of the classic versions of the theory of plasticity or Continuum Damage Mechanics (CDM). The second, post-localization, phase can be modelled assuming that energy dissipation is lumped in zones of zero volume: inelastic hinges, hinge lines or localization surfaces. This paper proposes a new LDM formulation for cracking in concrete structures in tension. It also describes its numerical implementation in conventional finite element programs. The results of three numerical simulations of experimental tests reported in the literature are presented. They correspond to plain and fiber-reinforced concrete specimens. A fourth simulation describes also the experimental results of a new test using the digital image correlation technique. These numerical simulations are also compared with the ones obtained using conventional Cohesive Fracture Mechanics (CFM). It is then shown that LDM conserves the advantages of both, CDM and CFM, while overcoming their drawbacks.

• Computers and Concrete
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• v.15 no.1
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• pp.127-140
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• 2015

The process of chloride ingress in saturated concrete was presented by a previous study that used a mathematical model for the same as that concrete. This model is to be studied chloride ion diffusion which is considered as a chemical phenomenon and is to be represented the chloride diffusion process to be a nonlinear partial differential equation (PDE). In this paper, this nonlinear PDE is solved by the Kirchhoff transformation to render into a linear PDE. This linear PDE associated with initial and boundary conditions is also solved by the Laplace transformation to obtain an analytical solution. To verify the serviceability and reliability of this proposed method, the practical application should be supplied. The input parameters were cited from the previous study. The free chloride concentration profiles obtained by the analytical solution of mathematical model for saturated concretes after 24 and 120 hrs of exposure were compared with the previous study. The predicted results obtained from proposed method have a tendency with experimental results obtained by the previous study and trend toward numerical results approximated by finite difference technique.

• Computers and Concrete
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• v.4 no.1
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• pp.1-18
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• 2007

Over the past decades, an enormous amount of effort has been expended in laboratory and field studies on concrete durability estimation. The results of this research are still either widely scattered in the journal literature or mentioned briefly in the standard textbooks. Moreover, the theoretical approaches of deterioration mechanisms with a predictive character are limited to some complicated mathematical models not widespread in practice. A significant step forward could be the development of appropriate software for computer-based estimation of concrete service life, including reliable mathematical models and adequate experimental data. In the present work, the basis for the development of a computer estimation of the concrete service life is presented. After the definition of concrete mix design and structure characteristics, as well as the consideration regarding the environmental conditions where the structure will be found, the concrete service life can be reliably predicted using fundamental mathematical models that simulate the deterioration mechanisms. The prediction is focused on the basic deterioration phenomena of reinforced concrete, such as carbonation and chloride penetration, that initiate the reinforcing bars corrosion. Aspects on concrete strength and the production cost are also considered. Field observations and data collection from existing structures are compared with predictions of service life using the above model. A first attempt to develop a database of service lives of different types of reinforced concrete structure exposed to varying environments is finally included.

• Communications of the Korean Mathematical Society
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• v.28 no.4
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• pp.783-797
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• 2013

Recently, Liu et al. [Bilateral generating functions for the Chan-Chyan-Srivastava polynomials and the generalized Lauricella function, Integral Transform Spec. Funct. 23 (2012), no. 7, 539-549] investigated, in several interesting papers, some various families of bilateral generating functions involving the Chan-Chyan-Srivastava polynomials. The aim of this present paper is to obtain some bilateral generating functions involving the Chan-Chyan-Sriavastava polynomials and three general classes of multivariable polynomials introduced earlier by Srivastava in [A contour integral involving Fox's H-function, Indian J. Math. 14 (1972), 1-6], [A multilinear generating function for the Konhauser sets of biorthogonal polynomials suggested by the Laguerre polynomials, Pacific J. Math. 117 (1985), 183-191] and by Kaano$\breve{g}$lu and $\ddot{O}$zarslan in [Two-sided generating functions for certain class of r-variable polynomials, Mathematical and Computer Modelling 54 (2011), 625-631]. Special cases involving the (Srivastava-Daoust) generalized Lauricella functions are also given.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.5 no.4
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• pp.323-338
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• 2007

For the assessment of the performance and safety of a deep underground radioactive repository system, the thermal, hydraulic, mechanical, and chemical behaviors and their coupling should be studied. In order to analyze the THMC coupling behavior more effectively, which requires complex mathematical models and modelling techniques, DECOVALEX international cooperation project was launched in 1992. Since its beginning, four major stages of the project were successfully completed and THMC modelling techniques for various conditions could be developed. In this study, the current status and major achievements from the project were reviewed and possible benefits of the participation to the project were discussed.

• Interaction and multiscale mechanics
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• v.1 no.1
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• pp.33-51
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• 2008

This paper investigates the modelling of coupled soil-structure interaction problems by domain decomposition techniques. It is assumed that the soil-structure system is physically partitioned into soil and structure subdomains, which are independently modelled. Coupling of the separately modelled partitioned subdomains is undertaken with various algorithms based on the sequential iterative Dirichlet-Neumann sub-structuring method, which ensures compatibility and equilibrium at the interface boundaries of the subdomains. A number of mathematical and computational characteristics of the coupling algorithms, including the convergence conditions and choice of algorithmic parameters leading to enhanced convergence of the iterative method, are discussed. Based on the presented coupling algorithms a simulation environment, utilizing discipline-oriented solvers for nonlinear structural and geotechnical analysis, is developed which is used here to demonstrate the performance characteristics and benefits of various algorithms. Finally, the developed tool is used in a case study involving nonlinear soil-structure interaction analysis between a plane frame and soil subjected to ground excavation. This study highlights the relative performance of the various considered coupling algorithms in modelling real soil-structure interaction problems, in which nonlinearity arises in both the structure and the soil, and leads to important conclusions regarding their adequacy for such problems as well as the prospects for further enhancements.

• Journal of Welding and Joining
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• v.21 no.2
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• pp.102-110
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• 2003

A visual sensor consisted of polygonal mirror, laser, and CCD camera was proposed to measure the distance to the weld joint for recognizing the joint shape. To scan the laser beam of the sensor onto an object, 8-facet polygonal mirror was used as the rotating mirror. By locating the laser and the camera at axi-symmetrical positions around the mirror, the synchronized-scan condition could be satisfied even when the mirror was set to rotate through one direction continuously, which could remove the inertia effect of the conventional oscillating-mirror methods. The mathematical modelling of the proposed sensor with the optical triangulation method made it possible to derive the relation between the position of an image on the camera and the one of a laser light on the object. Through the geometrical simulation of the proposed sensor with the principal of reflection and virtual image, the optical path of a laser light could be predicted. The position and direction of the CCD camera were determined based on the Scheimpflug's condition to fit the focus of any image reflected from an object within the field of view. The results of modelling and simulation revealed that the proposed visual sensor could be used to recognize the weld joint and its vicinity located within the range of the field of view and the resolution. (Received February 19, 2003)

• Proceedings of the Korean Geotechical Society Conference
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• 2005.03a
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• pp.71-80
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• 2005

More than 100 bridges have been annually collapsed or seriously damaged by scouring in Korea. It is extremely hard to understand the complicated scour mechanism and estimate the scour depth with accuracy in fields, however since scouring is a very complex manifestation of sediment transport unable to describe with a simple mathematical tool. In order to obtain the reasonable solution to bridge scouring, therefore, the interdisciplinary co-operation is strongly recommended. In this study the special task force team for the scour problems around Incheon 2nd bridge piers is made, in which all kinds of scour oriented researches such as oceangraphic survey, hydraulic model test, numerical simulation, scour rate test, real-time scour monitoring, etc will be carried out. This paper provides this interdisciplinary procedure in details.

• Journal of the Korean Institute of Telematics and Electronics A
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• v.32A no.1
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• pp.14-25
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• 1995

The main contribution of this paper can be summarized in two items as follws. Firstly, a modelling of mobile communication channel with Rayleigh fading characteristics is presented. Actual signal environments can be approximated as being real measurements by a proper mathematical representation of fluctuation of channel parameters due to Doppler effect, that is determined by the relative speed between transmitter and receiver, and noises, that vary at each sampling time. Secondly, an alternative procedure of synthesizing an adaptive equalizers is presented for recovering original signals that have been corrupted through the modelled channel. In order to compute the optimal tap coefficients for a high speed data(512 k symbol/sec) on a real-time basis, the CGM that guarantees fast and stable convergency is adopted during the training period of each frame. The coefficients obtained by the CGM are used as initial values for the LMS algorithm to trace the optimal coefficients during the data period that vary at each sampling time due to the mobility and noise at the receiver. Using the modelling presented in this paper, distributions of received signal power in various signal environments are demonstrated. The performance of the eqalizer proposed in this paper is shown as a function of BER under the various signal circumstances of mobile communications.