• Title/Summary/Keyword: Material separation

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NUCLIDE SEPARATION MODELING THROUGH REVERSE OSMOSIS MEMBRANES IN RADIOACTIVE LIQUID WASTE

  • LEE, BYUNG-SIK
    • Nuclear Engineering and Technology
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    • v.47 no.7
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    • pp.859-866
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    • 2015
  • The aim of this work is to investigate the transport mechanism of radioactive nuclides through the reverse osmosis (RO) membrane and to estimate its effectiveness for nuclide separation from radioactive liquid waste. An analytical model is developed to simulate the RO separation, and a series of experiments are set up to confirm its estimated separation behavior. The model is based on the extended Nernst-Plank equation, which handles the convective flux, diffusive flux, and electromigration flux under electroneutrality and zero electric current conditions. The distribution coefficient which arises due to ion interactions with the membrane material and the electric potential jump at the membrane interface are included as boundary conditions in solving the equation. A high Peclet approximation is adopted to simplify the calculation, but the effect of concentration polarization is included for a more accurate prediction of separation. Cobalt and cesium are specifically selected for the experiments in order to check the separation mechanism from liquid waste composed of various radioactive nuclides and nonradioactive substances, and the results are compared with the estimated cobalt and cesium rejections of the RO membrane using the model. Experimental and calculated results are shown to be in excellent agreement. The proposed model will be very useful for the prediction of separation behavior of various radioactive nuclides by the RO membrane.

Effects of Operating Variables on Separation Rate and Separation Efficiency in Ash Separator for Solid Fuel Chemical Looping Combustor (고체연료 매체순환연소기를 위한 회재분리기에서 분리속도 및 분리효율에 미치는 조업변수들의 영향)

  • RYU, HOJUNG;LEE, DONGHO;YOON, JOOYOUNG;JANG, MYOUNGSOO;BAE, DALHEE;PARK, JAEHYEON;BAEK, JEOMIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.2
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    • pp.211-219
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    • 2016
  • To develop an ash separator for the solid fuel chemical looping combustion system, effects of operating variables such as solid injection nozzle velocity, diameter of solid injection nozzle, gap between solid injection line and vent line, vent line inside diameter, and solid intake height on solid separation rate and solid separation efficiency were measured and discussed using heavy and coarse particle and light and fine particles mixture as bed material in an acrylic fluidized bed apparatus. The solid separation rate increased as the solid injection nozzle velocity and the diameter of solid injection nozzle increased. However, the solid separation rate decreased as the gap between solid injection line and vent line, the vent line inside diameter, and the solid intake height increased. The solid separation efficiency was in inverse proportion to the solid separation rate. In this study, we could get high solid separation rate up to 2.39 kg/hr with 91.6% of solid separation efficiency.

Triboelectrostatic Separation System for Separation of PVC and PS Materials Using Fluidized Bed Tribocharger

  • Lee, Jae-Keun;Shin, Jin-Hyouk;Hwang, Yoo-Jin
    • Journal of Mechanical Science and Technology
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    • v.16 no.10
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    • pp.1336-1345
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    • 2002
  • A triboelectrostatic separation system using a fluidized bed tribocharger for the removal of PVC material in the mixture of PVC/PS plastics is designed and evaluated as a function of electric field strength, air flow rate, and the mixing ratio of two-component mixed plastics. It consists of a fluidized-bed tribocharger, a separation chamber, a collection chamber and a controller. PVC and PS particles can be imparted negative and positive surface charges, respectively, due to the difference in the work function values of plastics suspended in the fluidized-bed tribocharger, and can be separated by passing them through an external electric field. Experimental results show that separation efficiency is strongly dependent on the electric Deld strength and particle mixing ratio. In the optimum conditions of 150 Ipm air flow rate and 2.6 kV/cm electric field strength a highly concentrated PVC (99.1%) can be recovered with a yield of more than 99.2% from the mixture of PVC and PS materials for a single stage of processing.

Reducing Separation Force for Projection Stereolithography based on Constrained Surface Technique (규제액면기법의 전사방식 광조형 시스템을 위한 이형력 감소)

  • Kim, Hye Jung;Ha, Young Myoung;Park, In Baek;Kim, Min Sub;Jo, Kwang Ho;Lee, Seok Hee
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.9
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    • pp.1001-1006
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    • 2013
  • Projection-based stereolithography is divided into constrained-surface and free-surface type according to controlling liquid layer. The constrained-surface type has a uniform layer thickness due to the use of a projection window, which covers the pattern generator such as liquid crystal display. However, the adhered resin on the projection window causes trouble and requires great separation force when the cured layer is separated from the window. To minimize the separation force, we developed a system to measure the separation force. The influence of material covering the pattern generator and the resin temperature is investigated in the system. Several structures according to the resin temperature and the velocity of z-axis elevation are compared. As a result, the fabrication condition to minimize the separation force reduces the process time.

Triboelectrostatic Separation of PVC Materials from Mixed Plastics for Waste Plastic Recycling

  • Lee, Jae-Keun;Shin, Jin-Hyouk;Ku, Jae-Hyun;Kim, Doo-Hyun;Cho, Jae-Min;Hwang, Yu-Jin
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.597-601
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    • 2001
  • Waste plastics amount is more than 3.5 million tons and 30% of industrial waste in 1998, Korea but recycling rate of industrial waste plastics is quite low because the material separation technology from the mixed waste plastic powders is not commercially available so far. This study covers the triboelectrostatic separation of polyvinylchloride (PVC) materials collection chambers and controllers. PVC and PET powders can be imparted negative and positive surface charges, respectively, due to the difference of triboelectric charging series between particles and particles in the fluidized bed tribocharger, and can be separated by passing them through an external electric field. The extract content and yield of PVC separation from the mixed PVC and PET plastic powders are 90.0% and 98.2%, respectively. The electrostatic separation system using the fluidized bed tribocharger shows the potential to be an effective method for removing PVC materials from other mixed plastics.

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Residence Time Distribution in the Chromatographic Column: Applications in the Separation Engineering of DNA

  • Park, Young G.
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.2
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    • pp.117-125
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    • 2003
  • Experimental and theoretical works were performed for the separation of large polyelectrolyte, such as DNA, in a column packed with gel particles under the influence of an electric field. Since DNA quickly orient in the field direction through the pores, this paper presents how intraparticle convection affects the residence time distribution of DNAs in the column. The concept is further illustrated with examples from solid -liquid systems, for example, from chromatography Showing how the column efficiency is improved by the use of a n electric field. Dimensionless transient mass balance equations were derived, taking into consideration both diffusion and electrophoretic convection. The separation criteria are theoretically studied using two different Peclet numbers in the fluid and solid phases. These criteria were experimentally verified using two different DNAs via electrophoretic mobility measurements. which showed how the separation position of the DNAs varies in the column in relation to the Peg/Pef values of an individual DNA. The residence time distribution was solved by an operator theory and the characteristic method to yield the column response.

Hydrogen Separation by Compact-type Silica Membrane Process (컴팩트 타입 실리카막 공정을 이용한 수소 분리)

  • Moon, Jong-Ho;Bae, Ji-Han;Lee, Sang-Jin;Chung, Jong-Tae;Lee, Chang-Ha
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.336-339
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    • 2006
  • With the steady depletion off fossil fuel reserves, hydrogen based energy sources become increasingly attractive. Therefore hydrogen production or separation technologies, such as Bas separation membrane based on adsorption technology, have received enormous attention in the industrial and academic fields. In this study, the transport mechanisms of the MTES (methyltriethoxysilane) templating silica/a-alumina composite membrane were evaluated by using unary, binary and quaternary hydrogen gas mixtures permeation experiments at unsteady- and steady-states. Since the permeation flux in the MTES membrane, through the experimental and theoretical study, was affected by molecular sieving effects as well as surface diffusion properties, the kinetic and equilibrium separation should be considered simultaneously in the membrane according to molecular properties. In order to depict the transient multi-component permeation on the templating silica membrane, the GMS (generalized Maxwell-Stefan) and DGM (dust Bas model) were adapted to unsteady-state material balance

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Magnetic separation of Fe contaminated Al-Si cutting chip scraps and evaluation of solidification characteristics (Fe성분이 혼입된 Al-Si 절삭칩 스크랩의 자력선별 및 응고특성 평가)

  • Kim, Bong-Hwan;Kim, Jun-Kyeom;Lee, Sang-Mok
    • Journal of Korea Foundry Society
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    • v.29 no.1
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    • pp.38-44
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    • 2009
  • Magnetic separation of Fe contaminated Al-Si cutting chip scraps was performed for the recyclability assessment. It was also aimed to investigate the casting and solidification characteristics of the cutting chip scraps. The magnetically separated cutting chip scraps were adequately treated for the casting procedure and test specimens were made into a stepped mold inducing different cooling rates. The test specimens were evaluated by the combined analysis of ICP, Spectroscopy, OM-image analyzer, SEM/EDS, etc. Solidification characteristics of cutting chip scraps were examined as functions of Fe content and cooling rate. It is concluded that the magnetic separation process can be utilized to recycle the Fe contaminated Al-Si cutting chip scraps in the high cooling rate foundry process.

The Interpretation of Separation Mechanism of Ridge-Cut Explosive Bolt Using Software Simulation Program

  • Lee, Y. J.;Kim, D. J.
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.532-543
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    • 2004
  • The present work have been developed the interpretation processor including the behavior of material failure and the separation phenomena under transient dynamic loading (the operation of explosive bolt) using AUTODYN V4.3, SoildWork 2003 and TrueGrid V2.1 programs. It has been demonstrated that the interpretation in ridge-cut explosive bolt under dynamic loading condition should be necessary to the appropriate failure model and the basic stress of bolt failure is the principal stress. The use of this interpretation processor developing the present work could be extensively helped to design the shape and the amount of explosives in the explosive bolt having a complex geometry. It is also proved that the interpretation processor approach is an accurate and effective analysis technique to evaluate the separation mechanism in explosive bolts.

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