• Transactions on Electrical and Electronic Materials
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• v.15 no.6
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• pp.305-308
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• 2014

Organosilyl-modified and star-shaped poly (${\varepsilon}$-caprolactone) (m-PCL) was prepared, and added to polymethylsilsesquioxane (PMSSQ), to make composites. The end groups of m-PCL are chemically similar to PMSSQ, and m-PCL mixed well with PMSSQ in the composite. Porous PMSSQ film was made by further calcination of the composite film at elevated temperature. m-PCL-templated PMSSQ and the as-prepared porous PMSSQ were structurally, optically, and thermally characterized in thin films. The chemical binding of m-PCL and PMSSQ effectively suppressed the phase separation of PMSSQ and m-PCL during the curing process. After calcination at elevated temperature, there remained many pores in the PMSSQ matrix. The refractive indices of the resulting porous PMSSQ thin films decreased with increase of the film porosities, depending on the initial m-PCL loadings.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.21 no.5
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• pp.474-480
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• 2008

In order to make full color cholesteric displays, color filter-less R, G, B sub-pixel structured cholesteric LC cells have been studied. To make R, G, B colors, UV induced pitch variant chiral dopant was added to cholesteric LC mixtures. The concentration of the photo-sensitive chiral dopant was adjusted so that the initial state showed blue color and the color was changed from blue to green and red with increase of UV irradiation to the cholesteric cells. To prevent the mixing of R, G, B reflective sub-pixel liquid crystals, separation walls were formed using negative photo resister in boundary area between sub-pixels, Through the optimization of the material concentrations and UV irradiation condition, vivid R, G, B colors were achieved.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.433-434
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• 2006

Monosized germanium micro particles are prepared by a newly developed Pulsated Orifice Ejection Method. The obtained particles are categorized into two kinds of the microstructures as refined and coarse ones. The morphological difference is estimated to be determined by the undercooling level during nucleation. Actually, the increase in the temperature of the melt was effective in coarsening the microstructure, because the temperature of the melt intensely relates to the undercooling level. The transition temperature of coarse and refined microstructures is found to be 1300-1350K. Furthermore, a triggered nucleation could improve the crystallinity of the particles in the short separation.

• Transactions of the Korean Society of Automotive Engineers
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• v.14 no.5
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• pp.130-137
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• 2006

A transient finite element simulation is developed for the two-dimensional thermoelastic contact problem of a stationary functionally graded material between sliding layers, with frictional heat generation. Thermoelastic instability in functionally graded materials is investigated. The critical speed of functionally graded material coating disk is larger than that of the conventional steel disk. The effect of the nonhomogeneity parameter in functionally graded material is also investigated. The results show that functionally gradient materials restrain the growth of perturbation and delay the contact separation.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07b
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• pp.1162-1165
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• 2004

In oil-filled enuipment such as transformers, partial discharge or local overheating will precede a final shutdown. Accompanied with such problems is a decomposition of insulating material into gases, which are dissolved into the transformer oil. The gases dissolved in oil can be separated with some membranes based on the differences in permeability of membranes to different gases. This paper discuss the permeability characteristics of several membranes for separation hydrogen gas in oil. With result of this paper, it may become possible to detect fault-related gases from transformer oil and predict incipient failures in the future.

• Journal of the Semiconductor & Display Technology
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• v.21 no.3
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• pp.92-97
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• 2022

Plastics are classified into 7 types such as PET (PETE), HDPE, PVC, LDPE, PP, PS, and Other for separation and recycling. Recently, large corporations advocating ESG management are replacing them with bioplastics. Incineration and landfill of disposal of plastic waste are responsible for air pollution and destruction of the ecosystem. Because it is not easy to accurately classify plastic materials with the naked eye, automated system-based screening studies using various sensor technologies and AI-based software technologies have been conducted. In this paper, NIR scanning devices considering the NIR wavelength characteristics that appear differently for each plastic material and a system that can identify the type of plastic by learning the NIR spectrum data collected through it. The accuracy of plastic material identification was evaluated through a decision tree-based SVM model for multiclass classification on NIR spectral datasets for 8 types of plastic samples including biodegradable plastic.

• Archives of Metallurgy and Materials
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• v.66 no.3
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• pp.745-750
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• 2021

A novel process to recover lithium and manganese oxides from a cathode material (LiMn₂O₄) of spent lithium-ion battery was attempted using thermal reaction with hydrogen gas at elevated temperatures. A hydrogen gas as a reducing agent was used with LiMn₂O₄ powder and it was found that separation of Li₂O and MnO was taken place at 1050℃. The powder after thermal process was washed away with distilled water and only lithium was dissolved in the water and manganese oxide powder left behind. It was noted that manganese oxide powder was found to be 98.20 wt.% and the lithium content in the solution was 1,928 ppm, respectively.

• Journal of Hydrogen and New Energy
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• v.16 no.3
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• pp.244-252
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• 2005

It is very interesting and important in the academic point of view and in practical use the hydrogen-induced phase separation(HIPS) which appears during hydrogen heat treatment. Since hydrogen can be removed very fast by pumping it out the hydrogen-induced new lattice phase which can not be obtained without hydrogen can be preserved as meta-stable state. In this study it has been investigated whether the HIPS appear in Pd-Al, Pd-Co, Pd-Cr, Pd-Ti, Pd-V and Pd-Zr alloys and discussed thermodynamic representation of the HIPS. The Pd alloys were arc-melted under argon atmosphere and remelted 4 or 5 times for homogenization. The alloys were annealed at 600$^{\circ}C$ under vacuum for 24 hrs and then subjected to pressure-composition isotherm measurements at 100$^{\circ}C$. The hydrogen heat treatment(HHT) of samples was carried out at 600$^{\circ}C$ under hydrogen pressure of 70 bar for 6 days and PC isotherms at 100$^{\circ}C$ were measured. By comparing the PC isotherms measured before and after HHT, occurrence of phase separation was determined. The experimental results showed that the HIPS appeared only in Pd-0.05Co alloy. For Pd-Co alloys with various composition the PC isotherms were measured. By adopting Park-Flanagan model for ternary thermodynamics the Gibbs free energy change for Pd-Co-H solid solution was calculated and subsequently with this the HIPS in Pd-Co alloy was explained fairly.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.2
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• pp.234-238
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• 2008

Coarse pore filter could be an alternative of membrane for solid-liquid separation in an activated sludge reactor because of inexpensive cost of the filter material and high flux at low filtration pressure. However such filter module has much less specific filtration area compared to the membrane. Therefore a certain effort is required to increase the specific filtration area in the module design of such coarse pore filter for solid-liquid separation in an activated sludge reactor. In this study, tubular type coarse pore filter was designed at various diameter and configuration. The filtration performance was investigated to separate solid in the activated sludge reactor for domestic wastewater treatment. Tubular type coarse pore filter module could be successfully applicable to solid separation in the activated sludge reactor. The design parameters were the tube diameter of 10mm and vertical installation. Smaller diameter of the tube caused faster increase of the filtration pressure because of the hydraulic head loss in the tube channel.

• Environmental Analysis Health and Toxicology
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• v.29
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• pp.18.1-18.9
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• 2014

Objectives The purpose of this study was to determine a separation method for each arsenic metabolite in urine by using a high performance liquid chromatography (HPLC)-inductively coupled plasma-mass spectrometer (ICP-MS). Methods Separation of the arsenic metabolites was conducted in urine by using a polymeric anion-exchange (Hamilton PRP X-100, $4.6mm{\times}150mm$, $5{\mu}m$) column on Agilent Technologies 1260 Infinity LC system coupled to Agilent Technologies 7700 series ICP/MS equipment using argon as the plasma gas. Results All five important arsenic metabolites in urine were separated within 16 minutes in the order of arsenobetaine, arsenite, dimethylarsinate, monomethylarsonate and arsenate with detection limits ranging from 0.15 to $0.27{\mu}g/L$ ($40{\mu}L$ injection). We used G-EQUAS No. 52, the German external quality assessment scheme and standard reference material 2669, National Institute of Standard and Technology, to validate our analyses. Conclusions The method for separation of arsenic metabolites in urine was established by using HPLC-ICP-MS. This method contributes to the evaluation of arsenic exposure, health effect assessment and other bio-monitoring studies for arsenic exposure in South Korea.