• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.34 no.1
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• pp.8-13
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• 2024

Objectives: To evaluate the levels of exposure to organic compounds during aircraft disinfection and seat cover replacement operations. Methods: According to the working schedule, organic compounds were collected using activated carbon tubes and then analyzed by GC/FID and GC/MSD. Results: In the disinfection task, the main substances listed in the material safety data sheet (MSDS) of the disinfectant were not detected. However, 1-bromopropane, which had been used in the previous task of replacing seat covers, was detected at a level of 2.37 ppm at the measurement time. During seat cover replacement, bonding workers were exposed to 2.48 ppm on an eight-hour time-weighted average, and seat cover replacement workers were exposed to 0.22 ppm. Conclusions: It is necessary to ensure the reliability of MSDS. A work environment management system is necessary when different companies alternate working in the same place.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.15 no.6
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• pp.209-215
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• 2015

Following the semiconductor industry's growing, various types of toxic gases and caustic chemicals, HF(Hydrofluoric acid), HCI (Hydochloric acid), $H_2O_2$ (Hydrogen peroxide), $H_2SO_4$ (Sulfuric acid), and Piranha, were using on the semiconductor manufacturing process. Therefore many gas leakage accidents that produce huge losses of lives were caused by the processes. This research deeply considers two basic solutions that the necessity of MSDS education on university for reducing damage of lives and protecting life from chemical leak accidents such as a HF accident in Gumi, Korea and the use of GHS, REACH and the comprehension of propriety about using MSDS for keeping safety from conflagrations by released poison chemical materials.

• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.376-382
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• 2008

There are many accidents such as fire and explosion in laboratories that have caused a great loss to lives and property in spite of the effort to the enhancement of laboratory safety level for years. Development of laboratory safety management system is a necessary to improve safety level because the accidents of similar types have periodically occurred in laboratories. The laboratory safety management system may reduce many accidents and a serious loss in laboratory. In this study, we summarized major items for a risk management and safety improvement based on the analysis results of various accidents in the laboratories. And then the laboratory safety management system was developed containing a laboratory safety management manual, a laboratory management system, a education management system, a MSDS (material safety data sheet) management system and a laboratory safety audit system. It may have a potential application for the laboratory safety management in the chemical laboratories.

• Fire Science and Engineering
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• v.21 no.3
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• pp.56-60
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• 2007

The usage of MSDS (Material Safety Data Sheet) is increased world widely for the implementation of GHS and REACH. In order to know the accuracy of the data in MSDS the flash point of n-Decanol was measured by using a Tag closed tester, a Seta-flash closed tester, a Pensky-Martens closed tester and a Cleveland open tester in Japan and Korea, respectively. The test results of flash points of n-Decanol purchased different manufacturer were compared to the data of the references and MSDS. The flash points determined in Japan were similar to those in Korea but have shown much difference from those in MSDS and literatures. It is suggested that the results of flash points determined in this research have validity and manufacturers should be more careful when they make MSDS as well as for the classification of GHS and REACH.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.25 no.1
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• pp.45-57
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• 2015

Objectives: This study aims to compare the physicochemical characteristics, toxicological data with Occupational Exposure Limits (OELs) of chemicals under the Occupational Safety and Health Act(OSHA) regulated by the Ministry of Employment and Labor of Korea. Methods: Information on chemicals which have OELs on physicochemical characteristics and toxicological data was collected using Material Safety Data Sheet(MSDS) from Korea Occupational Safety and Health Agency(KOSHA) and the Korea Information System for Chemical Safety Management(KISChem) in 2014. Statistical analyses including correlation and simple regression were performed to compare the OELs with chemical characteristics including molecular weight, boiling point, odor threshold, vapor pressure, vapor density, solubility and octanol-water partition coefficient(OWPC) and toxicological data such as median lethal dose($LD_{50}$) and median lethal concentration($LC_{50}$). Results: A total of 656 chemicals have OELs under OSHA in Korea. The numbers of chemicals which have eight-hour time weighted average(TWA) and short term exposure limits(STEL) are 618 and 190, respectively. TWA was significantly correlated with boiling point and STEL was only correlated with vapor pressure among physicochemical characteristics. Solubility and OWPC between "skin" and "no skin" substances which indicate skin penetration were not significantly different. Both $LD_{50}$ and $LC_{50}$ were correlated with TWA, while the $LC_{50}$ was not with STEL. As health indicators, health rating and Emergency Response Planning Guidelines(ERPG) rating as recommended by the National Fire Protection Association(NFPA) and American Industrial Hygiene Association(AIHA) were associated with OELs and reflect the chemical hazards. Conclusions: We found relationships between OEL and chemical information including physicochemical characteristics and toxicological data. The study has an important meaning for understanding present regulatory OELs.

• Fire Science and Engineering
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• v.31 no.3
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• pp.25-30
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• 2017

Because of the vertical combustion characteristics of combustible substances, accurate substance safety information for their safe use, handling and transportation is essential. The flash point, fire point, explosion limits and autoignition temperature (AIT) are important safety parameters which need special attention in chemical plants and laboratories that handle dangerous materials. In this study, tert-butylbenzene which is widely used as an intermediate material in the chemical industry was selected. For the reliability of the flammable properties of tert-butylbenzene, this study was investigated the explosion limits of tert-butylbenzene in the reference data. The flash points, fire points and AITs by the ignition delay time for tert-butylbenzene were experimented. The lower flash points of tert-butylbenzene by using the Setaflash and Pensky-Martens closed-cup testers measured $39^{\circ}C$ and $44^{\circ}C$, respectively. The flash points of tert-butylbenzene by using the Tag and Cleveland open cup testers are measured $51^{\circ}C$ and $54^{\circ}C$. And the fire points of tert-butylbenzene by the Tag and Cleveland open cup testers were $54^{\circ}C$ and $58^{\circ}C$ respectively. The AIT of tert-butylbenzene measured by the ASTM 659E tester was measured as $450^{\circ}C$. The lower explosion limit of $39^{\circ}C$ which measured by the Setaflash flash point tester was calculated to be 0.68 vol%.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.27 no.4
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• pp.423-432
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• 2017

Objectives: This study was conducted to evaluate asbestos handling history of workers at automobile manufacturing plants in Korea. Methods: National regulations on asbestos and Korea Occupational Safety and Health Agency(KOSHA) database on the information of asbestos containing products were reviewed. We investigated asbestos related materials from one automobile manufacturing plant. Material safety data sheets(MSDS) collected in 2010, work environment monitoring results reported from 2000 to 2013, trade union reports and asbestos survey reports were reviewed. We also interviewed workers with long career and did walk-through survey. Results: The Ministry of Labor in Korea has permitted asbestos manufacturing since 1990. In 1997, the use of crocidolite and amosite asbestos were banned. In 2007, the Korean government announced a total ban on the manufacturing, importation and use of all kinds of asbestos, which took full effect in 2009. A total of 174 asbestos products information from KOSHA database was analyzed. Extruded cement panel for building, special brake for crane farm machinery, gasket, joint sheet and thermal insulator were produced until 2007. From automobile manufacturing plant survey, we confirmed that asbestos containing materials(ACM) such as gasket, heating induction materials have been used until 2011. Asbestos containing building materials(ACBM) such as bamlites, slate and ceiling tex were reported at 122 asbestos dismantling projects in 2014. Conclusion: Although the use of all kinds of asbestos were banned from 2009, ACMs and ACBMs installed before 2009 were still found at automobile manufacturing plant until 2011 and 2014 respectively. In particular, asbestos slates should be managed because most of slates had not been removed until 2014.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.33 no.3
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• pp.365-374
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• 2023

Objectives: After the MSDS submission and non-disclosure review system was introduced in January 2021, there were compliance difficulties in the field. Accordingly, for the establishment of the MSDS system, the government intends to investigate what has been improved and what urgently needs to be improved in the future, and to suggest detailed improvement plans. Methods: The background and problems of urgent difficulties in the field handling chemicals were investigated, and realistic improvement plans were derived through review of other laws related to the MSDS system and overseas cases. Results: In order to guarantee the safety of the public while at the same time promoting corporate R&D, it is necessary to alleviate the non-disclosure screening system for chemical substances for R&D, and to improve the irrationality of failing to implement the non-disclosure screening system due to information on unclassified substances being circulated. For this reason, it seems necessary to ease the requirement to submit all ingredients. In addition, it is necessary to strengthen punishment to raise awareness so that health problems do not occur due to the harmfulness and danger of hidden substances among workers who handle chemical substances and downstream users due to false descriptions in MSDS. Conclusions: All members of our society, including chemical manufacturers/importers and handling companies, academia, civil society, and the government, each subject of chemicals, should take an interest in the entire process from production to disposal of chemicals and work together to prevent harm to the public.

• International Journal of Aeronautical and Space Sciences
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• v.18 no.2
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• pp.215-221
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• 2017

An electromagnetic (EM) wave absorber reduces the possibility of radar detection by minimizing the radar cross section (RCS) of structures. In this study, a radar absorbing structure (RAS) was applied to the leading edge of a blended wing body aircraft to reduce RCS in X-band (8.2~12.4GHz) radar. The RAS was composed of a periodic pattern resistive sheet with conductive lossy material and glass-fiber/epoxy composite as a spacer. The applied RAS is a multifunctional composite structure which has both electromagnetic (EM) wave absorbing ability and load-bearing ability. A two dimensional unit absorber was designed first in a flat-plate shape, and then the fabricated leading edge structure incorporating the above RAS was investigated, using simulated and free-space measured reflection loss data from the flat-plate absorber. The leading edge was implemented on the aircraft, and its RCS was measured with respect to various azimuth angles in both polarizations (VV and HH). The RCS reduction effect of the RAS was evaluated in comparison with a leading edge of carbon fabric reinforced plastics (CFRP). The designed leading edge structure was examined through static structural analysis for various aircraft load cases to check structural integrity in terms of margin of safety. The mechanical and structural characteristics of CFRP, RAS and CFRP with RAM structures were also discussed in terms of their weight.

• Journal of Yeungnam Medical Science
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• v.36 no.1
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• pp.20-25
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• 2019

Background: The aim of this study was to evaluate the awareness of occupational hazards and personal protective equipment use among dental hygienists (DHs). Methods: A total of 271 self-administered questionnaires were obtained from 280 DHs working at dental hospitals or clinics in Daegu and Gyeongsangbuk-do, Korea. Results: The occupational hazards included work involving dust (94.1%), volatile substances (86.0%), noise (97.0%), and light-curing units (96.7%). The proportion of dental hygiene tasks that participants perceived as harmful were 42.4%, 51.7%, 9.2%, and 31.4% in the same order as above. The proportion of participants who used dust-proof masks during work involving dust was 1.1%. Those who wore gas-proof masks and gloves for work using volatile substances were 0.7% and 31.2%, respectively. Participants who used goggles for work involving light-curing units were 31.0%. None of the participants used ear plugs for work involving noise. A total of 22.9% of the participants recognized the Material Safety Data Sheet, while 79.7% had never been educated about harmful work environments. Conclusion: When compared to exposure status and perception of occupational hazards, the level of protective equipment use was very low. Extra measures to increase DHs' use of personal protective equipment are necessary.