• Title/Summary/Keyword: Material of organic solar cell

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Photovoltaic Effects in Organic Semiconductor $CuPc/C_{60}$ depending on Cathodes ($CuPc/C_{60}$ 구조 유기 반도체에서의 음전극의 종류에 따른 광기전 효과 연구)

  • Oh, Hyun-Seok;Jang, Kyung-Wook;Lee, Sung-Ill;Lee, Joon-Ung;Kim, Tae-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.181-184
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    • 2004
  • Organic semiconductors have attracted considerable attention due to their interesting physical properties followed by various technological applications in the area of electronics and opto-electronics. It has been a long time since organic solar cells were expected as a low-cost high-energy conversion device. Although practical use of them has not been achieved, technological progress continues. Morphology of the materials, organic/inorganic interface, metal cathodes, molecular packing and structural properties of the donor and acceptor layers are essential for photovoltaic response. We have fabricated solar-cell devices based on copper-phthalocyanine(CuPc) as a donor(D) and fullerene($C_{60}$) as an electron acceptor(A) with doped charge transport layers, and BCP as an exciton blocking layer(EBL). We have measured photovoltaic characteristics of the solar-cell devices using the xenon lamp as a light source.

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Wet-Chemically Prepared NiO Layers as Hole Transport Layer in the Inverted Organic Solar Cell

  • Lim, Dong-Chan;Kim, Young-Tae;Shim, Won-Hyun;Jang, A-Young;Lim, Jae-Hong;Kim, Yang-Do;Jeong, Yong-Soo;Kim, Young-Dok;Lee, Kyu-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.1067-1070
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    • 2011
  • We have demonstrated that solution-based fabrication of NiO films as HTL can be used for the construction of IOSCs. Type of solvent of NiO-solution, and annealing procedure of the active layers were optimized for obtaining a PCE of 3% of IOSC. The photovoltaic performance of NiO-based device is comparable to that of the same type of solar cell using PEDT:PSS instead of NiO. These solution-based processes can be a promising method for a mass production OSCs under ambient condition.

Perspective of Hybridization Technology for Next-Generation Solar Cells (차세대 태양전지 하이브리드 기술의 전망)

  • Lee, Jae-Kwan;Lee, Jae-Joon
    • Journal of the Korean Electrochemical Society
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    • v.13 no.1
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    • pp.1-9
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    • 2010
  • We are presenting an overview of a R&D trend on dye-sensitized solar cells and organic polymer solar cells, which are classified into a next-generation solar cell, and the perspective on their hybridization technology. When considering the competition with inorganic material-base solar cells, especially, these next-generation solar cells need a new hybridization technology, even though it is still at the initial stage. The fusion and hybridization of them will be not only attractive in a new application, but also promising to expect significant progresses in the near future for successful R&D.

Ion Migration in Organic Metal Halide Perovskites (유기 금속 할라이드 페로브스카이트에서 이온 이동)

  • Oh, Ilwhan
    • Journal of the Korean Electrochemical Society
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    • v.21 no.2
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    • pp.21-27
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    • 2018
  • In this review, recent researches on ion transport phenomena in organic metal halide perovskite materials, which have been popular all over the world, are summarized. Although different results have been reported depending on the perovskite material composition and applied voltage, iodide seems to migrate under actual solar cell operating conditions, and occasionally methylammonium migration is observed. Perovskite is a so-called mixed conductor in which electrons and ions move simultaneously at room temperature, which greatly influences the hysteresis of the perovskite solar cell current-voltage curve and the performance degradation due to long-term operation.

Properties of the Exciton Blocking Layer with BCP in Organic Photovoltaic cell (BCP를 엑시톤 억제층으로 사용한 유기 광기전력 소자의 특성)

  • Oh, Hyun-Seok;Lee, Joon-Ung;Lee, Won-Jae;Kim, Tae-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.273-274
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    • 2005
  • Photovoltaic effects in organic solar cell were studied in a cell configuration of ITO/PEDOT:PSS/CuPc(20nm)/$C_{60}$(40nm)/BCP/Al(150nm) at room temperature. Here, the BCP layer works as an exciton blocking layer. The exciton blocking layer must transport electrons from the acceptor layer to the metal cathode with minimal increase in the total cell series resistance and should absorb damage during cathode deposition. Therefore, a proper thickness of the exciton blocking layer is required for an optimized photovoltaic cell. Several thicknesses of BCP were made between $C_{60}$ and Al. And we obtained characteristic parameters such as short-circuit current, open-circuit voltage, and power conversion efficiency of the device under the illumination of AM 1.5.

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Properties in Organic Photovoltaic Cell Depending on the Exciton Blocking Layer Thickness (엑시톤 억제층 두께에 따른 유기 광기전력 소자의 특성)

  • Oh, Hyun-Seok;Lee, Joon-Ung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.12
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    • pp.1148-1151
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    • 2005
  • Photovoltaic effects in organic solar cell were studied in a cell configuration of ITO/PEDOT:PSS/CuPc(20 nm)/$C_{60}$(40 nm)/BCP/Al(150 nm) at room temperature. Here, the BCP layer works as an exciton blocking layer. The exciton blocking layer must transport electrons from the acceptor layer to the metal cathode with minimal increase in the total cell series resistance and should absorb damage during cathode deposition. Therefore, a proper thickness of the exciton blocking layer is required for an optimized photovoltaic cell. Several thicknesses of BCP were made between $C_{60}$ and Al. And we obtained characteristic parameters such as short-circuit current, open-circuit voltage, and power conversion efficiency of the device under the illumination of AM 1.5.

Properties of Photovoltaic Cell using ZnPc/C60 Double Layer Devices

  • Lee, Ho-Sik;Seo, Dae-Shik;Lee, Won-Jae;Jang, Kyung-Uk;Kim, Tae-Wan;Lee, Sung-Il
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.3
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    • pp.124-127
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    • 2005
  • It has been a long time since organic solar cells were expected as a low-cost energy-conversion device. Although practical use of them has not been achieved, technological progress continues. Morphology of the materials, organic/inorganic interface, metal cathodes, molecular packing and structural properties of the donor and acceptor layers are essential for photovoltaic response. We have fabricated solar cell devices based on zinc-phthalocyanine(ZnPc) as donor(D) and fullerene$(C_60)$ as electron acceptor(A) with doped charge transport layers, and BCP and $Alq_3$ as an exciton blocking layer(EBL). We have measured the photovoltaic characteristics of the solar cell devices using the Xe lamp as a light source. We were use of $Alq_3$ layer leads to external power conversion efficiency was $2.65\%$ at illumination intensity $100\;mW/cm^2$. Also we confirmed the optimum thickness ratio of the DA hetero-junction is about 1:2.

Photovoltaic Properties of Organic Photovoltaic cell (유기물을 이용한 Photovoltaic cell의 광기전력 특성)

  • Kim, S.K.;Lee, H.D.;Chung, D.H.;Oh, H.S.;Hong, J.I.;Park, J.W.;Kim, T.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.04a
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    • pp.123-126
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    • 2003
  • Recently, there is a growing concern on the photovoltaic effects using organic materials. This is a phenomena which converts the solar energy into the electrical one. We have fabricated a device structure of $ITO/PEDOT:PSS/CuPc/C_{60}/BCP/AI$. The PEDOT:PSS layer is made by spin coating, and the other organic layers are made by thermal vapor deposition. By measuring the current-voltage characteristics with an illumination of light, we have obtained value of Voc=0.38V, Jsc=$0.5mA/cm^{2}$. And a fill factor and efficiency are about 0.314 and 0.083%, respectively. A 500W xenon lamp(ORIEL) is used for a light source, and the light intensity illuminated into the device was about 10mW.

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Synthesis, Characterization and Determination of HOMO-LUMO of the Substituted 1,3,5-Triazine Molecule for the Applications of Organic Electronics

  • Pakkath, Rajeesh;Reddy, Eeda Koti;Kuriakose, Sheena;Saritha, C;Sajith, Ayyiliath M;Karuvalam, Ranjith Pakkath;Haridas, Karickal Raman
    • Journal of the Korean Chemical Society
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    • v.63 no.5
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    • pp.352-359
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    • 2019
  • The most important parameter of organic molecules for energy harvesting application focuses mainly on their band gap (HOMO-LUMO). In this report, we synthesized differently substituted 1,3,5-triazine based organic molecule which on future processing can be used in organic electronics like solar cells and OLED's. The energy gap of the synthesized novel analogue was calculated using cyclic voltammetry, UV-Visible spectroscopy and compared with density functional theory (DFT) studies.

Characterization of Ag/TiO2 Nanoparticles Synthesis (Ag/TiO2미세입자 합성물의 특성 분석)

  • Kyungho Kang;Yonggi Jo;Sun-Geum Kim
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.2
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    • pp.202-207
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    • 2024
  • This study examines a manufacturing process for the photoelectrode material of dye-sensitized solar cell (DSSC) intending to increase efficiency through the surface plasmon resonance phenomenon of nanoparticles with a composite structure made of Ag and TiO2. This invention involves the use of Ag and TiO2 nanoparticles in the solar cell. These nanoparticles cause surface plasmon resonance, which amplifies and scatters incident solar energy, enhancing the dye's rate of light absorption. It also makes it possible to absorb energy in wavelength ranges that were previously difficult to do, which increases efficiency. Centrifugal separation and heat synthesis are used to create the composite metal structures, and certain combinations are used to decide the particle morphologies. To increase the efficiency of organic solar cells and DSSC, the Ag/TiO2 composite structure is therefore quite likely to be used.