• Clean Technology
• /
• v.6 no.2
• /
• pp.129-137
• /
• 2000

A methanol synthesis process via reverse-water-gas-shift and methanol formation reactions has been analyzed using the notion of exergy. The analysis has been based on the simulation results with the aid of real operating data. Driving and material exergy losses have been defined and quantified, respectively. Locations and the reason of major exergy losses have been pinpointed and improvement strategies have been suggested. It had been noted that the exergy analysis can provide a sound scientific base for adopting the concept of industrial ecology and developing loss prevention schemes.

• Clean Technology
• /
• v.12 no.2
• /
• pp.95-100
• /
• 2006

Fractionation and hydrodealkylation (HDA) units, subparts of BTX plant, were thermodynamically analyzed using the notion of exergy. Exergy values were calculated as the sum of physical and chemical exergies due to the existence of chemical reactions. The analysis was based on the simulation results with the aid of real operating data. Driving and material exergy losses were separately defined and quantified. Locations and the reason of major exergy losses were identified and improvement strategies were suggested. It was noted that the exergy analysis could provide a sound base for adopting the concept of industrial ecology and developing loss prevention schemes.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.12 no.6
• /
• pp.550-560
• /
• 2000

In order to minimize compression power and analyze the cause of exergy loss for a dry ice production cycle with 3-stage compression, the variation of compression power was investigated and the exergy analysis was peformed for the cycle. In this cycle, $CO_2$, is used both as a refrigerant and as a raw material for dry ice. The behavior of compression power and irreversibility in the cycle were examined as a function of intermediate pressure. From this result, the conditions for the minimum compression power were obtained in terms of the first stage or the third stage pressure. In addition, the irreversibilities for the cycle were investigated with respect to the efficiency of compressor. Result shows that the optimum pressure is not consistent with the conventional pressure obtained from the equal-pressure-ratio assumption. This is mainly due to the change in mass flow rate of the intermediate stage compressor by the flash gas evaporation from the flash drums. Most important is that the present exergy analysis enabled us to find bad performance components for the cycle and informed us of methods to improve the cycle performance.