• Title/Summary/Keyword: Material Decomposition

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Encapsulation of Semiconductor Gas Sensors with Gas Barrier Films for USN Application

  • Lee, Hyung-Kun;Yang, Woo Seok;Choi, Nak-Jin;Moon, Seung Eon
    • ETRI Journal
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    • v.34 no.5
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    • pp.713-718
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    • 2012
  • Sensor nodes in ubiquitous sensor networks require autonomous replacement of deteriorated gas sensors with reserved sensors, which has led us to develop an encapsulation technique to avoid poisoning the reserved sensors and an autonomous activation technique to replace a deteriorated sensor with a reserved sensor. Encapsulations of $In_2O_3$ nanoparticles with poly(ethylene-co-vinyl alcohol) (EVOH) or polyvinylidene difluoride (PVDF) as gas barrier layers are reported. The EVOH or PVDF films are used for an encapsulation of $In_2O_3$ as a sensing material and are effective in blocking $In_2O_3$ from contacting formaldehyde (HCHO) gas. The activation process of $In_2O_3$ by removing the EVOH through heating is effective. However, the thermal decomposition of the PVDF affects the property of the $In_2O_3$ in terms of the gas reactivity. The response of the sensor to HCHO gas after removing the EVOH is 26%, which is not significantly different with the response of 28% in a reference sample that was not treated at all. We believe that the selection of gas barrier materials for the encapsulation and activation of $In_2O_3$ should be considered because of the ill effect the byproduct of thermal decomposition has on the sensing materials and other thermal properties of the barrier materials.

The influence of the way of fat recovery from fleshing scrap on the acid value and fatty acid composition (플레싱 스크랩으로부터 유지 회수 방법이 산가 및 지방산 조성에 미치는 영향)

  • Shin, Soo-Beom;Min, Byung-Wook;Yang, Seung-Hun;Park, Min-Seok;Yang, Yung-Kon;Baik, Doo-Hyun;Kim, Hae-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.4
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    • pp.347-353
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    • 2007
  • Fleshing scrap is a kind of wastes produced during leather making process and used in the test of manufacturing biodiesel. The early step of manufacturing biodiesel is fat recovery from fleshing scrap. Hence, we investigated the influence of the way of fat recovery on the fatty acid composition. We used three different recovery ways, that is chemical method by protein decomposition with acid/fat recovering, physical method by protein denaturalization with heat and vacuum/fat pressing, and biodiesel method by protein decomposition/fat recovering. The biological method yielded the best results in terms of appearance transparency. It was most effective to lower acid value. Also the recovered fat by biological method would be favorable methyl-ester reaction raw material for biodiesel because it contains more than 5% of oleic acid among unsaturated fatty acid.

Enviroment-Friendly Synthesis of Nanocrystalline Nickel Oxide and Its Antibacterial Properties (폐과일껍질을 이용한 친환경 NiO 나노분말 합성 및 향균특성 연구)

  • Yuvakkumar, R.;Song, Jae Sook;Hong, Sun Ig
    • Korean Journal of Materials Research
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    • v.28 no.1
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    • pp.24-31
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    • 2018
  • This study reports an environment-friendly synthetic strategy to process nickel oxide nanocrystals. A mesoporous nickel oxide nanostructure was synthesized using an environmentally benign biomimetic method. We used a natural rambutan peel waste resource as a raw material to ligate nickel ions to form nickel-ellagate complexes. The direct decomposition of the obtained complexes at $700^{\circ}C$, $900^{\circ}C$ and $1100^{\circ}C$ in a static air atmosphere resulted in mesoporous nickel oxide nanostructures. The formation of columnar mesoporous NiO with a concentric stacked doughnuts architecture was purely dependent on the suitable direct decomposition temperature at $1100^{\circ}C$ when the synthesis was carried out. The prepared NiO nanocrystals were coated on cotton fabric and their antibacterial activity was also analyzed. The NiO nanoparticle-treated cotton fabric exhibited good antibacterial and wash durability performance.

The Characteristics of Atrazine Decomposition by Photo-chemical Oxidation Process (광화학적 산화처리에 의한 Atrazine 분해 특성)

  • Choi, Hyun-Jin;Park, Jong-Il;Lee, Tae-Jin
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.8
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    • pp.829-836
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    • 2005
  • In this study, the characteristics of atrazine decompositon with photo-chemical oxidation process was investigated by the oxidation products analysis. The main products of the process were OIET(2-hydroxy-4-ethylamino-6-isopropylamino s-triazine), OIAT(2-hydroxy-4-amino-6-isopropylamino s-triazine) and OAAT(2-hydroxy-4,6-diamino-s-triazine), resulting i n dechlorination or hydroxylation as the main mechanism of the photo-chemical oxidation process. Through the material balance analysis of TOC and chloride ion in the aqueous solution, it was concluded that mineralization of the atrazine was not occurred but the dechlorination of atrazine had been completed.

Performance Evaluation of a Micro Thruster Utilizing Hydrogen Peroxide Decomposition (과산화수소 분해반응을 이용한 초소형 추력기 성능평가)

  • Lee, Jeong-Sub;An, Sung-Yong;Kwon, Se-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.04a
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    • pp.102-105
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    • 2007
  • The performance evaluation of the micro thruster utilizing hydrogen peroxide decomposition is described. The catalyst bed was made of porous ceramic material($Isolite^{(R)}$) with large surface to mass ratio. 14%wt platinum was loaded on the catalyst support as a catalyst. Hydrogen peroxide with 85% concentration was used as a monopropellant. The length of the catalyst bed and the feed pressure of the hydrogen peroxide were taken as the parameters for the experiment. All experiments were carried out under cold start condition for 30 seconds. The $c^*$ efficiency was evaluated for each test case using measured pressure data. For the catalyst support length of 30 mm and feed pressure at 5.51 bar, satisfactory $c^*$ efficiency beyond 95% was observed.

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Synthesis and Structures of Two Lanthanide Complexes Containing a Mixed Ligand System: [Ln(Phen)2(L)3(HL)]·H2O [Ln = La, Ce: Phen = Phenanthroline: HL = Salicylic Acid]

  • Iravani, Effat;Nami, Navabeh;Nabizadeh, Fatemeh;Bayani, Elham;Neumuller, Bernhard
    • Bulletin of the Korean Chemical Society
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    • v.34 no.11
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    • pp.3420-3424
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    • 2013
  • The reaction of $LnCl_3{\cdot}7H_2O$ [Ln = La (1), Ce (2)] with salicylic acid (HL) and 1,10-phenanthroline (Phen) at $20^{\circ}C$ in $H_2O$/ethanol gave after work-up and recrystallization two novel lanthanide complexes with general formula $[Ln(Phen)_2(L)_3(HL)]{\cdot}H_2O$. Compounds 1 and 2 were characterized by IR and UV-Vis spectroscopy, TGA, CHN as well as by X-ray analysis. According to these results, compounds 1 and 2 are isostructural and contain $Ln^{3+}$ ions with coordination number nine. Complexes 1 and 2 consist of two Phen, one neutral HL and three L anions (two L anions act as monodentate ligands and the third one is chelating to $Ln^{3+}$). Thermal decomposition led to primary loss of the Phen molecules. Then HL molecules and finally L moieties left the material to give $Ln_2O_3$.

Effect of Corynebacterium glutamicum on Livestock Material Burial Treatment

  • Kim, Bit-Na;Cho, Ho-Seong;Cha, Yougin;Park, Joon-Kyu;Kim, Geonha;Kim, Yang-Hoon;Min, Jiho
    • Journal of Microbiology and Biotechnology
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    • v.26 no.8
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    • pp.1404-1408
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    • 2016
  • In recent years, foot-and-mouth disease has occurred in all parts of the world. The animals with the disease are buried in the ground; therefore, their concentration could affect ground or groundwater. Moreover, the complete degradation of carcasses is not a certainty, and their disposal is important to prevent humans, livestock, and the environment from being affected with the disease. The treatment of Corynebacterium glutamicum is a feasible method to reduce the risk of carcass decomposition affecting humans or the environment. Therefore, this study aimed to investigate the effect of C. glutamicum on the soil environment with a carcass. The composition of amino acids in the soil treated with C. glutamicum was generally higher than those in the untreated soil. Moreover, the plant root in the soil samples treated with C. glutamicum had 84.0% amino acids relative to the standard value and was similar to that of the control. The results of this study suggest the possibility to reduce the toxicity of a grave land containing animals with this disease.

Sintering Characteristics of Zircon Nanopowders Fabricated by High Energy Milling Process (고 에너지 밀링 공정으로 제조된 지르콘 나노분말의 소결특성에 관한 연구)

  • Lee, Ju Seong;Kang, Jong Bong
    • Korean Journal of Materials Research
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    • v.26 no.2
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    • pp.95-99
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    • 2016
  • In this study, 5 um sized $ZrSiO_4$ was ground to 1.9 um, 0.3 um, and 0.1 um sized powders by wet high energy milling process, and the sintering characteristics were observed. Pure $ZrSiO_4$ itself can-not be sintered to these levels of theoretical density, but it was possible to sinter $ZrSiO_4$ powder of nano-scale size of, -0.1 um to the theoretical density and to lower the sintering temperature for full density. Also, the decomposition of $ZrSiO_4$ with a size in the micron range resulted in the formation of monoclinic $ZrO_2$; however, in the nano sized range, the decomposition resulted in the tetragonal phase of $ZrO_2$. So, it was possible to improve the sintering characteristics of nano-sized $ZrSiO_4$ powders.

The Effect of Calcium on Microstructure of AZ61 Magnesium Alloy during Annealing Heat Treatment (AZ61 마그네슘 합금의 어닐링 중 Ca의 첨가에 따른미세조직 변화에 미치는 영향)

  • Kim, Kibeom;Jeon, Joonho;Kim, Kwonhoo
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.2
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    • pp.53-59
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    • 2021
  • Due to high specific strength and low density, AZ series magnesium alloys have been receiving high interest as a lightweight material. However, their industrial application is limited due to the phenomenon that the strength decreases at elevated temperature by the occurrence of softening effect because of the Mg17Al12 phase decomposition. To solve this problem, many research were conducted to increase the high-temperature strength by forming a thermal stable second-phase component by adding new elements to the AZ magnesium. Especially, adding Ca to AZ magnesium has been reported that Ca forms the new second-phase. However, studies about the analysis of decomposition or precipitation temperature, formation composition, and components to understand the formation behavior of these precipitated phases are still insufficient. Therefore, the effect of Ca addition to AZ61 on the phase change and microstructure of the alloy during annealing was investigated. As a result of analysis of the initial and heat-treated specimen, AZ61 formed α-Mg matrix and precipitated phase of Mg17Al12, and AZX611 formed one more type of precipitated phase, Al2Ca. Also, Al2Ca was thermal stable at high temperatures. And after annealing, the laves phase was decomposed to under 10 ㎛ size and distributed in matrix.

Application of $TiO_2$-Coated Construction Materials for Nicotine Photo-decomposition (니코틴 광분해를 위한 산화티타늄 코팅 건축자재 활용)

  • Jo, Wan-Kuen;Chun, Hee-Dong
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.3
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    • pp.316-322
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    • 2006
  • The current study evaluated the technical feasibility of the application of $TiO_2$ photocatalysis for the removal of nocotine which has well known as a representative material of environmental tobacco smoke(ETS). Four different preliminary experiments were performed for the evaluation of nicotine removal using photocatalyst-coated construction materials. The photocatalytic removal of nicotine was investigated for five parameters: dry condition of coating tiles, type of coating sol, number of coatings, relative humidity(RH), and input concentrations. Prior to performing the parameter tests, adsorption of nicotine onto the current experimental system was surveyed. All the variables tested in the present study exhibited to influence the photocatalytic decomposition of Nicotine. A dry condition of high temperature and short dry period presented higher photocatalytic oxidation(PCO) efficiency compared to that of low temperature and long dry period. ST-KO3 sol showed higher decomposition efficiency than E-T Sol. The PCO efficiency increased as the number of coating increased. High humidity and low input concentrations exhibited higher PCO efficiency. Consequently, it is noted that the five parameters tested in the present study should be considered for the application of photocatalyst-coated construction materials in cleaning nicotine in ETS.