• Title/Summary/Keyword: Mass transfer zone

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A Study on Cleaning Process for Benzene Recovery in Activated Carbon Bed (활성탄을 충전한 흡착탑에서 벤젠 회수를 위한 세정공정의 연구)

  • Kang, Sung-Won;Min, Byong-Hoon;Suh, Sung-Sup
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.2
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    • pp.108-116
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    • 2002
  • Experimental Study was carried out for benzene desorption by purge gas or evacuation in an activated carbon bed. As purge gas flow rate increased, desorption rate increased due to the higher interstitial linear gas velocity. For various purge gas flow rates, desoption curves almost got together if they were plotted against dimensionless time. At a higher flow rate, mass transfer zone became narrower. Temperature drop in the bed was more fast and severe at higher flow rates and higher outer temperature. It was found out that desorption was almost completed when the temperature in the drop of the bed returned to the initial temperature before temperature drop. Desorption by vacuum purge was completed in shorter time than desorption by purge gas. Countercurrent purge was more effective than cocurrent purge.

Decrease in the Thickness of Capillary Fringe Induced by Surface Active Chemicals in the Groundwater (계면활성물질의 지하수적용에 의한 모관수대 두께의 감소)

  • Kim, Heonki;Shin, Seungyup;Yang, Haewon
    • Journal of Soil and Groundwater Environment
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    • v.17 no.6
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    • pp.52-58
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    • 2012
  • Capillary fringe divides the groundwater and the vadose zone controlling the diffusive mass transfer of contaminants and gases. The thickness of capillary fringe is of great importance for the rate of contaminant mass transfer across the capillary fringe. Application of surface active chemicals including surfactants and alcohol-based products into the subsurface environment changes the surface tension of the aqueous phase, which in turn, affects the thickness of the capillary fringe. In this study, a bench-scale model was used to assess the quantitative relationship between the surface tension and the thickness of the capillary fringe. An anionic surfactant (Sodium dodecylbenzene sulfonate, SDBS) and an aqueous solution of ethanol were used to control the surface tension of the groundwater. It was found that the thickness of the capillary fringe is directly proportional to the surface tension. The air entry pressures measured by the Tempe Pressure Cell at different surface tensions using SDBS (200 mg/L) and ethanol (20%, v/v) solutions were in good agreement with the thicknesses of the capillary fringe measured by the model. A simple method to correct the conventional Brooks-Corey model for estimating the air entry pressure was also presented.

Visual Demonstration of Simulated Moving Bed (Simulated Moving Bed Chromatography의 시각적 설명)

  • Oh, Nan Suk;Lee, Chong-Ho;Kim, Jin Il;Koo, Yoon-Mo
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.360-365
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    • 2005
  • SMB (simulated moving bed) is a continuous chromatographic process by shifting periodically port position. Binary of mixture, Blue dextran and Orange G, was separated by SMB. These components have unique color individually, that is, Blue dextran is blue and Orange G is orange. It is easy to understand SMB process by observing the shift of color changes in SMB. These components was not adsorbed to stationary phase and isolated by difference of size exclusion factor. Mass transfer coefficient was determined by single pulse test under several flow rate conditions. Operation condition was obtained by standing wave theory and optimized for high purities in extract and raffinate streams. Experiment was performed in open loop 4 zone (2-2-2-2) SMB. There are several advantages in open loop SMB, where extract is product for high purity. It is also easy to control flow rate and monitor experimental state during operation. Experimental, extract and raffinate history is well fitted with simulation results, however, column concentration profile is a little different from simulation results. Purities were 99.5% for extract and 98.9% for raffinate and extract and raffinate yields were obtained as 98.9% and 99.4% respectively.

A numerical study of the influence of rock mass classes boundary on tunnel stability (암반 등급 경계가 터널 안정성에 미치는 영향에 관한 수치해석적 연구)

  • Kim, Gyeomyeon;Jung, Chanmook;Lee, Yongjun
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.21 no.6
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    • pp.825-835
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    • 2019
  • When the tunnel is designed, the ground is classified into several grades and the corresponding support system is applied according to the support pattern table. However, a simple pattern application based on rock grade does not take into account the longitudinal stress transitions occurring at rock grade boundaries. In this study, three-dimensional numerical analysis was performed to estimate the stress change in the longitudinal rock grade change of NATM tunnel, and the influence zone of load transfer was investigated using the influence line and trend line. As a result, the downward change of rock grade in the direction of tunnel excavation occurs in the range of 0.35~0.7D from low-strength rock to high-strength rock around the grade change boundary. It is necessary to apply a downward pattern of about 1.0D to the safety direction in consideration of the influence range of 0.35D to 0.7D.

A Study on Gas-Liquid Contact in a Perforated Plate-Type $SO_2$ Absorber at Flooding Conditions

  • Han, Seung-Ho;Soowoo Kwon;Sangwon Jung;Jaehyuk Junk;Yang, Chang-Ryung;Carl Weilert
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.E
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    • pp.17-28
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    • 1999
  • Gas-liquid contact tests above a perforated-plate were conducted with air and water at flooding gas-flow conditions in order to study two-phase flow characteristics in a limestone-gypsum SO2 absorber. Gas layers were in the form of air pockets and confined to the limited areas around each duct pipe, while the remaining tary area were in the wet condition. The liquid above the tray was always in the flooded and even fluidized conditions at gas flows over the range studied, although vigorous bubbly or churn-turbulent two-phase regime was only observed in the immediate vicinity of the gas hole exit at low gas loads. The froth zone was extremely active to provide intimate contact between gas and liquid so that the necessary mass transfer operation can take place, which is the primary purpose of high-performance SO2 absorbers. Howefer, the absorber $\Delta$P was 250mmH2O for the initial water level at 150mm, which is an important issue to be resolved for economical operation of the SO2 absorber. It was seen in the liquid level-and gas flow-transient tests that changes in the absorber liquid inventory were much more pronounced for intimate gas-liquid contact than changes in the gas flow. Based on the 4- and 8-duct pipe test results, grouping the duct pipes near the center of the test tray seemed to promote better recirulation of liquid from gas-liquid contact zone back to the reaction tank so that the absorbed SO2 can be neutralized.

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Simulation study of DAF flotation basin using CFD (전산유체해석기법을 이용한 용존공기부상공정의 유동해석)

  • Park, Byungsung;Woo, Sungwoo;Park, Sungwon;Min, Jinhee;Lee, Woonyoung;You, Sunam;Jun, Gabjin
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.2
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    • pp.261-272
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    • 2013
  • Algae boom (Red tide) in south coastal area of Korea has been appeared several times during a decade. If algae boom appears in the desalination plant, media filter and UF filter are clogged quickly, and the plant should be shutdown. In general, Algae can be removed from water by flotation better than by sedimentation, because of the low density of algal cell. The purpose of this study conducts the CFD simulation of DAF flotation basin to apply the design of the dissolved air flotation with ball filter in the Test Bed for SWRO desalination plant. In this study, Eulerian-Eulerian multiphase model was applied to simulate the behavior of air bubbles and seawater. Density difference model and gravity were used. But de-sludge process and mass transfer between air bubbles and seawater were ignored. Main parameter is hydraulic loading rate which is varied from 20 m/hr to 27.5 m/hr. Geometry of flotation basin were changed to improve the DAF performance. According to the result of this study, the increase of hydraulic loading rate causes that the flow in the separation basin is widely affected and the concentration of air is increased. The flow pattern in the contact zone of flotation basin is greatly affected by the location of nozzle header. When the nozzle header was installed not the bottom of the contact zone but the above, the opportunity of contact between influent and recycle flow was increased.

Adsorption Characteristics of $CH_4/CO_2$ Mixed Gases on Activated Carbon Fibers (활성탄소섬유상에서 CH4/CO2 혼합가스의 흡착 특성)

  • Moon, Seung-Hyun;Shim, Jae-Woon
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.5
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    • pp.655-662
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    • 2004
  • An adsorption process to recover the pure $CH_4\;and\;CO_2$ from its mixture was examined. In this study, activated carbon fibers were used as a selective adsorbent. The activated carbon fibers has 78~94% micropore volume and 10.5~20.3${\AA}$ narrow pore size, and showed high adsorption rate and the good selectivity for $CO_2$ under the ambient pressure. The ACF with high surface area showed short mass transfer zone and long breakthrough time and, its adsorption capacity depended on the microporosity. Compared with single component adsorption, the amount adsorbed $CO_2$ on ACF increased by the roll-up of $CH_4$ in mixed gases. The adsorption selectivity increased as now rate and $CO_2$ concentration of mixed gases increased, showing 5.2 selectivity for 75% $CO_2$ concentration.

Numerical Analysis of Switching Arcs with the Ablation of PTFE Nozzles (PTFE 노즐로부터 발생하는 용삭가스를 고려한 스위칭 아크 해석)

  • Lee, Won-Ho;Kim, Hong-Kyu;Lee, Jong-Chul
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1536-1537
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    • 2011
  • The high-voltage circuit breaker plays an important role in the electrical system because there has been a need for suitable switching devices capable of initiating and interrupting the flow of the electric fault current. It continues as the contacts recede from each other and as the newly created gap is bridged by a plasma. The arc plasma happens inside the insulation nozzle of SF6 self-blast interrupter which is newly developed as the next-generation switching principle. The ablation of PTFE nozzle is caused by this high temperature medium, the PTFE vapor from the nozzle surfaces flows toward the outlets and the pressure chamber. The vapor makes the pressure of the chamber increased by heat and mass transfer from the arcing zone. Because the rate of ablation depends on the magnitude of applied current, it decreases when the current goes to zero. The compressed gas inside the chamber flows reversely toward the arc plasma during this moment. According to this principle, the arc can be cooled down and the fault current can be interrupted successfully. In this study, we calculate arc plasmas and thermal-flow characteristics caused by fault current interruption inside a SF6 self-blast interrupter, and to investigate the effect of PTFE ablation on the whole arcing history.

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Adsorption of volatile organic compounds using activated carbon fiber filter in the automobiles

  • Moon, Hyung Suk;Kim, In Soo;Kang, Sin Jae;Ryu, Seung Kon
    • Carbon letters
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    • v.15 no.3
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    • pp.203-209
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    • 2014
  • The adsorption of volatile organic compounds (VOCs) was carried out using an activated carbon fiber (ACF) filter in an automobile. The adsorption capacities of formaldehyde, toluene, and benzene on an ACF filter were far better than those of a polypropylene (PP) mat filter and combined (PP+activated carbon) mat filter by batch adsorption in a gas bag. In a continuous flow of air containing toluene vapor through an ACF packed bed, the breakpoint time was very long, the length of the unused bed was short, and sharp "S" -type breakthrough curve was plotted soon after breakpoint, showing a narrow mass transfer zone of toluene on the ACF. The adsorption amount of toluene on the ACF filter was proportional to the specific surface area of the ACF; however, the development of mesopores 2-5 nm in size on the ACF was very effective with regard to the adsorption of toluene. The ACF air clarifier filter is strongly recommended to remove VOCs in newly produced automobiles.

Cell-intrinsic signals that regulate adult neurogenesis in vivo: insights from inducible approaches

  • Johnson, Madeleine A.;Ables, Jessica L.;Eisch, Amelia J.
    • BMB Reports
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    • v.42 no.5
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    • pp.245-259
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    • 2009
  • The process by which adult neural stem cells generate new and functionally integrated neurons in the adult mammalian brain has been intensely studied, but much more remains to be discovered. It is known that neural progenitors progress through distinct stages to become mature neurons, and this progression is tightly controlled by cell-cell interactions and signals in the neurogenic niche. However, less is known about the cell-intrinsic signaling required for proper progression through stages of adult neurogenesis. Techniques have recently been developed to manipulate genes specifically in adult neural stem cells and progenitors in vivo, such as the use of inducible transgenic mice and viral-mediated gene transduction. A critical mass of publications utilizing these techniques has been reached, making it timely to review which molecules are now known to play a cell-intrinsic role in regulating adult neurogenesis in vivo. By drawing attention to these isolated molecules (e.g. Notch), we hope to stimulate a broad effort to understand the complex and compelling cascades of intrinsic signaling molecules important to adult neurogenesis. Understanding this process opens the possibility of understanding brain functions subserved by neurogenesis, such as memory, and also of harnessing neural stem cells for repair of the diseased and injured brain.