• Advances in environmental research
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• v.7 no.1
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• pp.29-37
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• 2018

A simple mathematical model for predicting fixed bed adsorption dynamics is described. The model is characterized by a linear adsorption isotherm and a linear driving force expression for mass transfer. Its analytic solution can be approximated with an algebraic equation in closed form which is easily evaluated by spreadsheet computation. To demonstrate one application of the fixed bed model, a previously published adsorption system is used as a case study in this work. The adsorption system examined here describes chromium breakthrough in a fixed bed adsorber packed with imidazole functionalized adsorbent particles and is characterized by a nonlinear adsorption isotherm. However, the equilibrium behavior of the fixed bed adsorber is in essence governed by a linear adsorption isotherm due to the use of a low influent chromium concentration. It is shown that chromium breakthrough is predicted reasonably well by the fixed bed model. The model's parameters can be easily extracted from independent batch experiments. The proposed modeling approach is very simple and rapid, and only Excel is used for computation.

• Proceedings of the Membrane Society of Korea Conference
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• 1998.10a
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• pp.39-42
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• 1998

1. 서론 : 막을 경계로 접촉한 두 상(phase)간의 물질전달에 의해 물질을 효과적으로 분리해내는 막접촉기(membrane contactor) 방식은 추출이나 흡수에 적용되고 있다. 이것은 고전적인 충전탑이 갖는 접촉면적의 한계, 불안정한 유체유동의 단점을 가급적 극복할 수 있다는 측면에 있다. 막접촉방식의 하나인 막 흡수법의 경우, 흡수제(absorbent)를 정지시킨 contained(혹은, supported) liquid membrane 방식에서 인공폐의 원리를 기초로 독립적으로 분리시킨 흡수와 탈착모듈간의 계속 순환시키는 circulatory membrane absorber방식이 제안되었다.(생략)

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.25 no.11
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• pp.624-630
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• 2013

A truck refrigeration system using phase change material (PCM) is expected to have a lower noise level, reduced energy cost, and much lower local greenhouse gas emission. Recently, a forced convection type PCM refrigeration module has been developed. As the operation time increases, the PCM around the air inlet melts, because of a large temperature difference between the PCM and air. Therefore, the latent heat transfer area decreases and the heat transfer rate of the module decreases even though there is a lot of PCM which does not melt around the air outlet. A computational fluid dynamic modeling of the PCM refrigeration module was developed and validated by the experiment. Using the CFD, the design parameters, such as the mass flow rate of the air and roughness of the slab, were investigated to improve the heat transfer inhomogeneity. As a result, the adoption of partial roughness on the slabs improved the heat transfer inhomogeneity and reduced a fan power.

• Advances in environmental research
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• v.12 no.1
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• pp.17-40
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• 2023

This article presents studies of the adsorption process in a continuous system of fluoride solutions at a concentration of 30 mg/L using a bone char packed in fixed-bed columns, as well as regeneration studies in the same system using HNO₃, HCl and NaOH at 0.01, 0.1 and 1 M. The Thomas Model, Artificial Neural Networks (ANNs), Numerical Integration and Mass Transfer Zone were used for the modeling of asyemmetrical breakthrough curves obtained from the fluoride adsorption on bone char. The maximum adsorption capacity of the breakthrough curves was estimated, and various design parameters of the columns were obtained for the different operating conditions. Results showed that an improvement in the modeling capabilities of the Thomas model can be obtained using ANNs. Moreover, ANNs are useful for determining reasonable and accurate design parameters of packed-bed adsorption columns. This modeling approach can be useful for the process system engineering of dynamic adsorption systems involved in the field of water treatment and purification. It is important to highlight that the obtained results indicate that, when using HCl or HNO₃ at a concentration of 0.1 M, a large number of adsorption-desorption cycles are obtained and, therefore, the highest values of adsorption capacity, which leads to a reduction in operation costs.

• Applied Chemistry for Engineering
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• v.8 no.3
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• pp.416-424
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• 1997

Mass transfer mechanism and concentration profiles in the axial direction at each phase were analyzed and simulated by a theoretical modeling on a liquid-liquid static contactor using highly packed fiber bundle. The concentrations at the end of the fiber extractor calculated at several operational conditions were compared with experimental results. The fiber extractor could be completely predicted by a plug flow model without axial dispersion. A parameter used in the model equations, $k_a{\sigma}$ called the product of mass transfer coefficient and mass transfer area per unit length of the fiber extractor in the axial direction, which was determined by a curve-fitting, was confirmed to be a unique characteristic value of the fiber extractor, and was about 0.0327cm2/sec.

• Korean Chemical Engineering Research
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• v.46 no.3
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• pp.521-528
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• 2008

The micro-porous asymmetric PVDF hollow fiber membranes for gas-liquid contactor were prepared by the dry-jet wet phase inversion process and the characteristics of hollow fiber membranes were evaluated by the gas permeation method and scanning electron microscope. The chemical absorbent for removal of $SO_2$ gas was sodium hydroxide at bench scale hollow fiber membrane contactor. The experiments were performed in a counter-current mode of operation with gas in the shell side and liquid in the fiber lumen of the module to examine the effect of various operating variables such as concentration of absorbent, gas flow rate, L/G ratio and concentration of inlet $SO_2$ gas on the $SO_2$ removal efficiency using PVDF hollow fiber membrane contactor. Membrane mass transfer coefficient($k_m$) was calculated by mathematical modeling. The volumetric overall mass transfer coefficient increased with increasing the concentration of absorbent and L/G ratio. The increase of the absorbent concentration and L/G ratio not only provides more sufficient alkalinity but also decreases liquid phase resistance. The volumetric overall mass transfer coefficient increased with increasing gas flow rate due to decreasing the gas phase resistance.

• Nuclear Engineering and Technology
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• v.54 no.9
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• pp.3310-3316
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• 2022

Owing to the rising concerns about the safety of nuclear power plants (NPP), it is essential to study the venturi scrubber in detail, which is a key component of the filtered containment venting system (FCVS). FCVS alleviates the pressurein containment byfiltering and venting out the contaminated air. Themain objective of this research was to perform a CFD investigation of different configurations of a circular, non-submerged, self-priming venturi scrubber to estimate and improve the performance in the removal of elemental iodine from the air. For benchmarking, a mass transfer model which is based on two-film theory was selected and validated by experimental data where an alkaline solution was considered as the scrubbing solution. This mass transfer model was modified and implemented on a unique formation of two self-priming venturi scrubbers in series. Euler-Euler method was used for two-phase modeling and the realizable K-ε model was used for capturing the turbulence. The obtained results showed a remarkable improvement in the removal of radioactive iodine from the air using a series combination of venturi scrubbers. The removal efficiency was improved at every single data point.

• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.5
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• pp.952-961
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• 1989

The purpose of this study is to investigate the behavior of operational and design factors on the performance characteristics of a horizontal fin-tube heat exchanger under phase change conditions for refrigerant. The flow and heat transfer in the heat exchanger are simulated numerically taking into account the variations of heat transfer coefficients, thermodynamic and flow properties of refrigerant, and the axial heat conduction in the tube wall. As the results of this study, it was found that the annular flow model was more reasonable physically than the homogeneous one for the two phase flow of refrigerant and axial heat conduction of tube wall did not have a great influence on the analysis. The effects of refrigerant pressure, mass flow rate of air, diameter of tube and the number of fins per unit length of tube were also discussed.

• Journal of Energy Engineering
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• v.12 no.2
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• pp.93-100
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• 2003

An estimation methodology of the mass and energy (M/E) release due to the main steam line break (MSLB) has been developed with the RETRAN-3D code. In the case of equipment qualification (EQ), the over-estimated temperature would exceed the design limits of some cables or valves. In order to have a more flexible EQ profiles from the MSLB M/E release, the methodology with the best-estimated code was used. The major conditions affecting the MSLB M/E were found to be the initial SG level, heat transfer between primary and secondary sides, power level, operable protection system, main or auxiliary feedwater availability, and break conditions. The RETRAN-3D models were developed for the Kori unit 1 (KRN-1) which is typical two loop Westinghouse (WH) designed plant. Particularly, a detailed model of the steam generators was developed to estimate a more realistic two-phase heat transfer effect of the steam flow. After the modeling, the methodology has been developed through the sensitivity analyses. The M/E release data generated from the analyses have been used as the input to the inside containment pressure and temperature (P/T) analysis. According to the results at the point of view containment P/T, the Kori unit 1 can have more margin of 5∼15 ㎪ in pressure and 8∼15$^{\circ}C$ in temperature.

• Proceedings of the Korean Society for Rock Mechanics Conference
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• 2000.09a
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• pp.211-222
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• 2000

The design values of rock socketed pile related with properties of rock mass are not clearly established. However, the drilled shafts socketed in rock are widely used as the foundation of large scaled structure. In this study, the characteristics of behavior of rock socketed pile is researched, and the properties of interface between pile and rock considering soil-structure interaction are evaluated for numerical modeling of rock socketed pile based on the previous researches. Based on the properties of interface and rock mass, the behaviors of rock socketed piles are numerically modeled and compared with field measurement. To verify the numerical analysis, a micro pile socketed in rock is modeled and the results of numerical analysis are compared with field measurement. The numerical results show a good agreement with field measured data, especially in terms of load transfer characteristics.